Abstract
In this article, Cr(OH)3 nanoparticle-modified cellulose nanocrystal (CNC) as a novel hybrid nanocomposite (Cr(OH)3-NPs-CNC) was prepared by a simple procedure and used as a sorbent for adsorptive removal of methylene blue (MB) and malachite green (MG) from aqueous solution. Different kinetic models were tested, and the pseudo-second-order kinetic model was found more suitable for the MB and MG adsorption processes. The BET and Langmuir models were more suitable for the adsorption processes of MB and MG. Thermodynamic studies suggested that the adsorption of MB and MG onto Cr(OH)3-NPs-CNC nanocomposite was a spontaneous and endothermic process. The maximum adsorption capacities for MB and MG were reached 106 and 104 mg/g, respectively, which were almost two times higher than unmodified CNC. The chemical stability and leaching tests of the Cr(OH)3-NPs-CNC hybrid nanocomposite showed that only small amounts of chromium were leached into the solution.
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Abbas M, Kaddour S, Trari M (2014) Kinetic and equilibrium studies of cobalt adsorption on apricot stone activated carbon. J Ind Eng Chem 20:745–751
Alves LCH (2015) Cellulose solutions: dissolution, regeneration, solution structure and molecular interactions, Universidade de Coimbra
Anastopoulos I, Kyzas GZ (2014) Agricultural peels for dye adsorption: a review of recent literature. J Mol Liq 200:381–389
Anirudhan T, Deepa J (2015) Synthesis and characterization of multi-carboxyl-functionalized nanocellulose/nanobentonite composite for the adsorption of uranium (VI) from aqueous solutions: kinetic and equilibrium profiles. Chem Eng J (Lausanne) 273:390–400
Anirudhan T, Shainy F (2015) Effective removal of mercury (II) ions from chlor-alkali industrial wastewater using 2-mercaptobenzamide modified itaconic acid-grafted-magnetite nanocellulose composite. J Colloid Interface Sci 456:22–31
Azmat R, Saeed A (2014) Catalytic degradation of methylene blue by nanostructured CrO (OH) prepared by hydrothermal method. Eur Chem Bull 3:417–421
Bennett J, Creamer N, Deplanche K, Macaskie L, Shannon I, Wood J (2010) Palladium supported on bacterial biomass as a novel heterogeneous catalyst: a comparison of Pd/Al 2 O 3 and bio-Pd in the hydrogenation of 2-pentyne. Chem Eng Sci 65:282–290
Boyer TH, Singer PC (2007) Stoichiometry of removal of natural organic matter by ion exchange. Environ Sci Technol 42:608–613
Capadona JR, Shanmuganathan K, Trittschuh S, Seidel S, Rowan SJ, Weder C (2009) Polymer nanocomposites with nanowhiskers isolated from microcrystalline cellulose. Biomacromolecules 10:712–716
Crini G, Peindy HN, Gimbert F, Robert C (2007) Removal of CI basic green 4 (malachite green) from aqueous solutions by adsorption using cyclodextrin-based adsorbent: kinetic and equilibrium studies. Sep Purif Technol 53:97–110
Cui L, Guo X, Wei Q, Wang Y, Gao L, Yan L, Yan T, Du B (2015) Removal of mercury and methylene blue from aqueous solution by xanthate functionalized magnetic graphene oxide: sorption kinetic and uptake mechanism. J Colloid Interface Sci 439:112–120
Dodd MC, Rentsch D, Singer HP, Kohler H-PE, Uv G (2010) Transformation of β-lactam antibacterial agents during aqueous ozonation: reaction pathways and quantitative bioassay of biologically-active oxidation products. Environ Sci Technol 44:5940–5948
Doğan M, Alkan M, Demirbaş Ö, Özdemir Y, Özmetin C (2006) Adsorption kinetics of maxilon blue GRL onto sepiolite from aqueous solutions. Chem Eng J (Lausanne) 124:89–101
Dubinin M (1960) The potential theory of adsorption of gases and vapors for adsorbents with energetically nonuniform surfaces. Chem Rev (Washington, DC, US) 60:235–241
Dubinin M (1965) Modern state of the theory of volume filling of micropore adsorbents during adsorption of gases and steams on carbon adsorbents. Zh Fiz Khim 39:1305–1317
Edition F (2011) Guidelines for drinking-water quality. WHO Chron 38:104–108
Elazzouzi-Hafraoui S, Nishiyama Y, Putaux J-L, Heux L, Dubreuil F, Rochas C (2007) The shape and size distribution of crystalline nanoparticles prepared by acid hydrolysis of native cellulose. Biomacromolecules 9:57–65
Essandoh M, Kunwar B, Pittman CU, Mohan D, Mlsna T (2015) Sorptive removal of salicylic acid and ibuprofen from aqueous solutions using pine wood fast pyrolysis biochar. Chem Eng J (Lausanne) 265:219–227
Ferrero F (2007) Dye removal by low cost adsorbents: hazelnut shells in comparison with wood sawdust. J Hazard Mater 142:144–152
Fu J, Chen Z, Wang M, Liu S, Zhang J, Zhang J, Han R, Xu Q (2015) Adsorption of methylene blue by a high-efficiency adsorbent (polydopamine microspheres): kinetics, isotherm, thermodynamics and mechanism analysis. Chem Eng J (Lausanne) 259:53–61
Ghaedi M, Ansari A, Sahraei R (2013) ZnS: cu nanoparticles loaded on activated carbon as novel adsorbent for kinetic, thermodynamic and isotherm studies of reactive orange 12 and direct yellow 12 adsorption. Spectrochim Acta A 114:687–694
Gupta VK, Tyagi I, Agarwal S, Sadegh H, Shahryari-ghoshekandi R, Yari M, Yousefi-nejat O (2015) Experimental study of surfaces of hydrogel polymers HEMA, HEMA–EEMA–MA, and PVA as adsorbent for removal of azo dyes from liquid phase. J Mol Liq 206:129–136
Hamed MM, Ahmed I, Metwally S (2014) Adsorptive removal of methylene blue as organic pollutant by marble dust as eco-friendly sorbent. J Ind Eng Chem 20:2370–2377
He X, Male KB, Nesterenko PN, Brabazon D, Paull B, Luong JH (2013) Adsorption and desorption of methylene blue on porous carbon monoliths and nanocrystalline cellulose. ACS Appl Mater Interfaces 5:8796–8804
Ho Y-S, McKay G (1998) Sorption of dye from aqueous solution by peat. Chem Eng J (Lausanne) 70:115–124
Hokkanen S, Repo E, Sillanpää M (2013) Removal of heavy metals from aqueous solutions by succinic anhydride modified mercerized nanocellulose. Chem Eng J (Lausanne) 223:40–47
Hou A, Zhou M, Wang X (2009) Modifying cellulose with the emulsion of the triazine derivative containing the tertiary amino group to improve the reactivity with reactive dyes. J Dispers Sci Technol 30:643–648
Ioelovich M (2012) Study of cellulose interaction with concentrated solutions of sulfuric acid. ISRN Chem Eng 2012
Johar N, Ahmad I, Dufresne A (2012) Extraction, preparation and characterization of cellulose fibres and nanocrystals from rice husk. Ind Crop Prod 37:93–99
Jonoobi M, Harun J, Mathew AP, Hussein MZB, Oksman K (2010) Preparation of cellulose nanofibers with hydrophobic surface characteristics. Cellulose 17:299–307
Kargarzadeh H, Ahmad I, Abdullah I, Dufresne A, Zainudin SY, Sheltami RM (2012) Effects of hydrolysis conditions on the morphology, crystallinity, and thermal stability of cellulose nanocrystals extracted from kenaf bast fibers. Cellulose 19:855–866
Kargarzadeh H, Sheltami RM, Ahmad I, Abdullah I, Dufresne A (2015) Cellulose nanocrystal: a promising toughening agent for unsaturated polyester nanocomposite. Polymer 56:346–357
Kemp KC, Seema H, Saleh M, Le NH, Mahesh K, Chandra V, Kim KS (2013) Environmental applications using graphene composites: water remediation and gas adsorption. Nano 5:3149–3171
Kiefer E, Sigg L, Schosseler P (1997) Chemical and spectroscopic characterization of algae surfaces. Environ Sci Technol 31:759–764
Koh YK, Chiu TY, Boobis AR, Scrimshaw MD, Bagnall JP, Soares A, Pollard S, Cartmell E, Lester JN (2009) Influence of operating parameters on the biodegradation of steroid estrogens and nonylphenolic compounds during biological wastewater treatment processes. Environ Sci Technol 43:6646–6654
Kumari S, Chauhan GS (2014) New cellulose–lysine Schiff-Base-based sensor–adsorbent for mercury ions. ACS Appl Mater Interfaces 6:5908–5917
Li Y, Du Q, Liu T, Sun J, Wang Y, Wu S, Wang Z, Xia Y, Xia L (2013) Methylene blue adsorption on graphene oxide/calcium alginate composites. Carbohydr Polym 95:501–507
Li C, Zhong H, Wang S, Xue J, Zhang Z (2015) Removal of basic dye (methylene blue) from aqueous solution using zeolite synthesized from electrolytic manganese residue. J Ind Eng Chem 23:344–352
Liu DY, Sui G, Bhattacharyya D (2014) Synthesis and characterisation of nanocellulose-based polyaniline conducting films. Compos Sci Technol 99:31–36
Liu P, Borrell PF, Božič M, Kokol V, Oksman K, Mathew AP (2015) Nanocelluloses and their phosphorylated derivatives for selective adsorption of Ag+, Cu 2+ and Fe 3+ from industrial effluents. J Hazard Mater 294:177–185
Majumder S, Naskar B, Ghosh S, Lee C-H, Chang C-H, Moulik SP, Panda AK (2014) Synthesis and characterization of surfactant stabilized nanocolloidal dispersion of silver chloride in aqueous medium. Colloids Surf A Physicochem Eng Asp 443:156–163
Masomboon N, Ratanatamskul C, Lu M-C (2009) Chemical oxidation of 2, 6-dimethylaniline in the Fenton process. Environ Sci Technol 43:8629–8634
McNaught AD, Wilkinson A (1997) Compendium of chemical terminology. IUPAC recommendations
Moghaddam SS, Moghaddam MA, Arami M (2010) Coagulation/flocculation process for dye removal using sludge from water treatment plant: optimization through response surface methodology. J Hazard Mater 175:651–657
Moradi O, Gupta VK, Agarwal S, Tyagi I, Asif M, Makhlouf ASH, Sadegh H, Shahryari-ghoshekandi R (2015) Characteristics and electrical conductivity of graphene and graphene oxide for adsorption of cationic dyes from liquids: kinetic and thermodynamic study. J Ind Eng Chem 28:294–301
Mukherjee I, Dinda G, Ghosh S, Moulik SP (2012) Synthesis, characterization, and applications of microheterogeneous-templated CdS nanodispersions. J Nanopart Res 14:1–14
Nekouei F, Nekouei S (2017a) Comparative study of photocatalytic activities of Zn5(OH)8 Cl2· H2O and ZnO nanostructures in ciprofloxacin degradation: response surface methodology and kinetic studies. Sci Total Environ 601:508–517
Nekouei F, Nekouei S (2017b) Comparative evaluation of BiOCl–NPls–AC composite performance for methylene blue dye removal from solution in the presence/absence of UV irradiation: kinetic and isotherm studies. J Alloys Compd 701:950–966
Nekouei F, Nekouei S, Tyagi I, Gupta VK (2015) Kinetic, thermodynamic and isotherm studies for acid blue 129 removal from liquids using copper oxide nanoparticle-modified activated carbon as a novel adsorbent. J Mol Liq 201:124–133
Nekouei F, Kargarzadeh H, Nekouei S, Keshtpour F, Makhlouf ASH (2016a) Efficient method for determination of methylene blue dye in water samples based on a combined dispersive solid phase and cloud point extraction using Cu(OH)2 nanoflakes: central composite design optimization. Anal Bioanal Chem 1–14
Nekouei F, Kargarzadeh H, Nekouei S, Keshtpour F, Makhlouf ASH (2016b) Novel, facile, and fast technique for synthesis of AgCl nanorods loaded on activated carbon for removal of methylene blue dye. Process Saf Environ Prot 103:212–226
Nekouei F, Kargarzadeh H, Nekouei S, Tyagi I, Agarwal S, Gupta VK (2016c) Preparation of nickel hydroxide nanoplates modified activated carbon for malachite green removal from solutions: kinetic, thermodynamic, isotherm and antibacterial studies. Process Saf Environ Prot 102:85–97
Nekouei F, Noorizadeh H, Nekouei S, Asif M, Tyagi I, Agarwal S, Gupta VK (2016d) Removal of malachite green from aqueous solutions by cuprous iodide–cupric oxide nano-composite loaded on activated carbon as a new sorbent for solid phase extraction: isotherm, kinetics and thermodynamic studies. J Mol Liq 213:360–368
Nekouei S, Nekouei F, Canselier JP (2016e): Solid-phase extraction for simultaneous separation and preconcentration of Fe (III) and Zn (II) traces using three chelatants and Ramelak bark-derived activated carbon as a new bio-sorbent. Sep Sci Technol
Nekouei S, Nekouei F, Tyagi I, Agarwal S, Gupta VK (2016f) Mixed cloud point/solid phase extraction of lead (II) and cadmium (II) in water samples using modified-ZnO nanopowders. Process Saf Environ Prot 99:175–185
Nekouei S, Nekouei F, Ulusoy Hİ, Noorizadeh H (2016g) Simultaneous application of cloud point and solid-phase extraction for determination of Fe (III) and Cu (II) ions by using SnO2 nanopowder in micellar medium. Desalin Water Treat 57:12653–12662
Ouaissa YA, Chabani M, Amrane A, Bensmaili A (2014) Removal of tetracycline by electrocoagulation: kinetic and isotherm modeling through adsorption. J Environ Chem Eng 2:177–184
Peng Y, Gardner DJ, Han Y (2012) Drying cellulose nanofibrils: in search of a suitable method. Cellulose 19:91–102
Radushkevich L (1949) Potential theory of sorption and structure of carbons. Zh Fiz Khim 23:1410–1420
Rathod M, Haldar S, Basha S (2015) Nanocrystalline cellulose for removal of tetracycline hydrochloride from water via biosorption: equilibrium, kinetic and thermodynamic studies. Ecol Eng 84:240–249
Salleh MAM, Mahmoud DK, Karim WAWA, Idris A (2011) Cationic and anionic dye adsorption by agricultural solid wastes: a comprehensive review. Desalination 280:1–13
Sangpour P, Hashemi F, Moshfegh AZ (2010) Photoenhanced degradation of methylene blue on cosputtered M: TiO2 (M= Au, Ag, Cu) nanocomposite systems: a comparative study. J Phys Chem C 114:13955–13961
Schröfel A, Kratošová G, Šafařík I, Šafaříková M, Raška I, Shor LM (2014) Applications of biosynthesized metallic nanoparticles—a review. Acta Biomater 10:4023–4042
Siqueira G, Bras J, Dufresne A (2009) New process of chemical grafting of cellulose nanoparticles with a long chain isocyanate. Langmuir 26:402–411
Tempkin M, Pyzhev V (1940) Kinetics of ammonia synthesis on promoted iron catalyst. Acta Phys Chim USSR 12:327
Ten E, Bahr DF, Li B, Jiang L, Wolcott MP (2012) Effects of cellulose nanowhiskers on mechanical, dielectric, and rheological properties of poly (3-hydroxybutyrate-co-3-hydroxyvalerate)/cellulose nanowhisker composites. Ind Eng Chem Res 51:2941–2951
Uber F (1985) Die adsorption in losungen. Z Phys Chem 57:387–470
Vithanage M, Mayakaduwa S, Herath I, Ok YS, Mohan D (2016) Kinetics, thermodynamics and mechanistic studies of carbofuran removal using biochars from tea waste and rice husks. Chemosphere 150:781–789
Wu J, Wang J, Li H, Du Y, Huang K, Liu B (2013) Designed synthesis of hematite-based nanosorbents for dye removal. J Mater Chem A 1:9837–9847
Wu Z, Zhong H, Yuan X, Wang H, Wang L, Chen X, Zeng G, Wu Y (2014) Adsorptive removal of methylene blue by rhamnolipid-functionalized graphene oxide from wastewater. Water Res 67:330–344
Yang S-T, Chen S, Chang Y, Cao A, Liu Y, Wang H (2011) Removal of methylene blue from aqueous solution by graphene oxide. J Colloid Interface Sci 359:24–29
Yang Y, Xie Y, Pang L, Li M, Song X, Wen J, Zhao H (2013) Preparation of reduced graphene oxide/poly (acrylamide) nanocomposite and its adsorption of Pb (II) and methylene blue. Langmuir 29:10727–10736
Zykova A, Safonov V, Virva O, Luk'yanchenko V, Walkowich J, Rogowska R, Yakovin S (2008) Surface parameters modification by multilayer coatings deposition for biomedical applications, Journal of Physics: Conference Series. IOP Publishing, pp. 012029
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Nekouei, F., Nekouei, S., Keshtpour, F. et al. Cr(OH)3-NPs-CNC hybrid nanocomposite: a sorbent for adsorptive removal of methylene blue and malachite green from solutions. Environ Sci Pollut Res 24, 25291–25308 (2017). https://doi.org/10.1007/s11356-017-0111-2
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DOI: https://doi.org/10.1007/s11356-017-0111-2