Skip to main content
Erschienen in: The International Journal of Life Cycle Assessment 5/2013

01.06.2013 | LCA OF CHEMICALS

Ethylene based on woody biomass—what are environmental key issues of a possible future Swedish production on industrial scale

verfasst von: Christin Liptow, Anne-Marie Tillman, Matty Janssen, Ola Wallberg, Glenn A. Taylor

Erschienen in: The International Journal of Life Cycle Assessment | Ausgabe 5/2013

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Purpose

In order to reduce its environmental impact, the chemical industry no longer produces base chemicals such as ethylene, solely from fossil, but also from biomass-based feedstocks. However, a biomass option suitable for one region might not be as suitable for another region due to, e.g., long transport and the related environmental. Therefore, local biomass alternatives and the environmental impact related to the production of chemicals from these alternatives need to be investigated. This study assesses the environmental impact of producing ethylene from Swedish wood ethanol.

Methods

The study was conducted following the methodology of life cycle assessment. The life cycle was assessed using a cradle-to-gate perspective for the production of 50,000 tonnes ethylene/year for the impact categories global warming, acidification (ACP), photochemical ozone creation, and eutrophication (EP).

Results and discussion

The production of enzymes used during the life cycle had a significant effect on all investigated impacts. However, reduced consumption of enzyme product, which could possibly be realized considering the rapid development of enzymes, lowered the overall environmental impact of the ethylene. Another approach could be to use alternative hydrolyzing agents. However, little information on their environmental impact is available. An additional key contributor, with regard to ACP, EP, and POCP, was the ethanol production. Therefore, further improvements with regard to the process’ design may have beneficial effects on its environmental impact.

Conclusions

The study assessed the environmental impact of wood ethylene and pointed to several directions for improvements, such as improved enzyme production and reduced consumption of enzyme products. Moreover, the analysis showed that further investigations into other process options and increase of ethylene production from biomass are worth continued research.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Fußnoten
1
Wood needed to produce 50,000 tonnes ethylene is ∼4.5 × 105 tonnes (dry matter content 50 %) (unallocated).
 
2
One filter paper unit for cellulase enzymes according to Ferreira et al. (2009) is “the amount of enzyme that releases 1 micromole glucose per minute during hydrolysis reaction” and can be used to describe the activity of the enzyme. The enzyme product assessed in this study, however, does not only contain the enzyme but also some formulation materials. For this reason 1 g of enzyme product does not necessarily equal 1 g of enzyme rather it may vary for different products and product generations. The stated FPU dosage was, therefore, only used to calculate the enzyme product consumption for the current scenarios, since only data for current FPU/g enzyme product were available. For the future consumption scenarios, however, simplified estimates of possible future enzyme product consumptions were made, without the intention to project.
 
3
This high purity is not necessary for the production of ethylene. However, the model was set up to simulate production of biofuels, which require this high concentration.
 
Literatur
Zurück zum Zitat Aden A, Ruth M, Ibsen K, Jechura J, Neeves K, Sheehan J, Wallace B (2002) Montague L, Slayton A, Lukas J (Harris Group, Seattle, Washington). Lignocellulosic biomass to ethanol process design and economics utilizing co-current dilute acid hydrolysis and enzymatic hydrolysis for corn stover. NREL/TP-510-32438, National Renewable Energy Lab Aden A, Ruth M, Ibsen K, Jechura J, Neeves K, Sheehan J, Wallace B (2002) Montague L, Slayton A, Lukas J (Harris Group, Seattle, Washington). Lignocellulosic biomass to ethanol process design and economics utilizing co-current dilute acid hydrolysis and enzymatic hydrolysis for corn stover. NREL/TP-510-32438, National Renewable Energy Lab
Zurück zum Zitat Andersson B-I (1996) Miljö- och energidatabas för träindustrin - etapp I (Environmental and energy data for the forestry industry—stage I) Rapport P 9601006. Trätek - Institutet för Träteknisk Forskning, Stockholm Andersson B-I (1996) Miljö- och energidatabas för träindustrin - etapp I (Environmental and energy data for the forestry industry—stage I) Rapport P 9601006. Trätek - Institutet för Träteknisk Forskning, Stockholm
Zurück zum Zitat Bals B, Wedding C, Balan V, Sendich E, Dale B (2011) Evaluating the impact of ammonia fiber expansion (AFEX) pretreatment conditions on the cost of ethanol production. Biores Technol 102(2):1277–1283CrossRef Bals B, Wedding C, Balan V, Sendich E, Dale B (2011) Evaluating the impact of ammonia fiber expansion (AFEX) pretreatment conditions on the cost of ethanol production. Biores Technol 102(2):1277–1283CrossRef
Zurück zum Zitat Barrocas HV, Lacerda A (2007) Process for the production of ethylene from ethyl alcohol. Brazil Patent Barrocas HV, Lacerda A (2007) Process for the production of ethylene from ethyl alcohol. Brazil Patent
Zurück zum Zitat Barta Z, Kovacs K, Reczey K, Zacchi G (2010a) Process design and economics of on-site cellulase production on various carbon sources in a softwood-based ethanol plant. Enzyme Res. doi:10.4061/2010/734182 Barta Z, Kovacs K, Reczey K, Zacchi G (2010a) Process design and economics of on-site cellulase production on various carbon sources in a softwood-based ethanol plant. Enzyme Res. doi:10.​4061/​2010/​734182
Zurück zum Zitat Barta Z, Reczey K, Zacchi G (2010b) Techno-economic evaluation of stillage treatment with anaerobic digestion in a softwood-to-ethanol process. Biotechnol Biofuels 3(1):1–11CrossRef Barta Z, Reczey K, Zacchi G (2010b) Techno-economic evaluation of stillage treatment with anaerobic digestion in a softwood-to-ethanol process. Biotechnol Biofuels 3(1):1–11CrossRef
Zurück zum Zitat Berg S, Lindholm EL (2005) Energy use and environmental impacts of forest operations in Sweden. J Clean Prod 13(1):33–42CrossRef Berg S, Lindholm EL (2005) Energy use and environmental impacts of forest operations in Sweden. J Clean Prod 13(1):33–42CrossRef
Zurück zum Zitat Börjesson P, Tufvesson L, Lantz M (2010) Life cycle assessment of biofuels in Sweden Report no 70 Börjesson P, Tufvesson L, Lantz M (2010) Life cycle assessment of biofuels in Sweden Report no 70
Zurück zum Zitat Ferreira SMP, Duarte AP, Queiroz JA, Domingues FC (2009) Influence of buffer systems on Trichoderma reesei Rut C-30 morphology and cellulase production. Electron J Biotechnol 12(3):8–9 Ferreira SMP, Duarte AP, Queiroz JA, Domingues FC (2009) Influence of buffer systems on Trichoderma reesei Rut C-30 morphology and cellulase production. Electron J Biotechnol 12(3):8–9
Zurück zum Zitat Galbe M, Zacchi G (2007) Pretreatment of lignocellulosic materials for efficient bioethanol production. Adv Biochem Eng Biotechnol 108:41–65 Galbe M, Zacchi G (2007) Pretreatment of lignocellulosic materials for efficient bioethanol production. Adv Biochem Eng Biotechnol 108:41–65
Zurück zum Zitat Galbe M, Sassner P, Wingren A, Zacchi G (2007) Process engineering economics of bioethanol production. In: Springer-Verlag (ed) Galbe M, Sassner P, Wingren A, Zacchi G (2007) Process engineering economics of bioethanol production. In: Springer-Verlag (ed)
Zurück zum Zitat Gao Y, Skutsch M, Drigo R, Pacheco P, Masera O (2011) Assessing deforestation from biofuels: methodological challenges. Appl Geogr 31(2):508–518CrossRef Gao Y, Skutsch M, Drigo R, Pacheco P, Masera O (2011) Assessing deforestation from biofuels: methodological challenges. Appl Geogr 31(2):508–518CrossRef
Zurück zum Zitat González-García S, Berg S, Feijoo G, Moreira MT (2009) Environmental impacts of forest production and supply of pulpwood: Spanish and Swedish case studies. Int J Life Cycle Assess 14(4):340–353CrossRef González-García S, Berg S, Feijoo G, Moreira MT (2009) Environmental impacts of forest production and supply of pulpwood: Spanish and Swedish case studies. Int J Life Cycle Assess 14(4):340–353CrossRef
Zurück zum Zitat González-García S, Mola-Yudego B, Murphy RJ (2012) Life cycle assessment of potential energy uses for short rotation willow biomass in Sweden. Int J Life Cycle Assess. doi:10.1007/s11367-012-0536-2 González-García S, Mola-Yudego B, Murphy RJ (2012) Life cycle assessment of potential energy uses for short rotation willow biomass in Sweden. Int J Life Cycle Assess. doi:10.​1007/​s11367-012-0536-2
Zurück zum Zitat Gottschlich N (2004) Nachhaltigkeitsbewertung eines biologisch abbaubaren Kunststoffes unter gleichzeitiger Erarbeitung von Maßnahmenkatalogen. Fachhochschule Lippe und Höxter, Höxter Gottschlich N (2004) Nachhaltigkeitsbewertung eines biologisch abbaubaren Kunststoffes unter gleichzeitiger Erarbeitung von Maßnahmenkatalogen. Fachhochschule Lippe und Höxter, Höxter
Zurück zum Zitat Huang R, Su R, Qi W, He Z (2011) Bioconversion of lignocellulose into bioethanol: process intensification and mechanism research. Bioenergy Res 4(4):225–245CrossRef Huang R, Su R, Qi W, He Z (2011) Bioconversion of lignocellulose into bioethanol: process intensification and mechanism research. Bioenergy Res 4(4):225–245CrossRef
Zurück zum Zitat International Energy Agency (2008) Energy policies of IEA countries Sweden 2008 Review International Energy Agency (2008) Energy policies of IEA countries Sweden 2008 Review
Zurück zum Zitat International Energy Agency (IEA) (2011) World key energy statistics International Energy Agency (IEA) (2011) World key energy statistics
Zurück zum Zitat ISO (2006) International Organization for Standardization: ISO 14040:2006 Environmental management—Life cycle assessment—Principles and framework. ISO, Geneva, Switzerland ISO (2006) International Organization for Standardization: ISO 14040:2006 Environmental management—Life cycle assessment—Principles and framework. ISO, Geneva, Switzerland
Zurück zum Zitat Jeihanipour A (2011) Waste textiles bioprocessing to ethanol and biogas. Chalmers University of Technology, Göteborg Jeihanipour A (2011) Waste textiles bioprocessing to ethanol and biogas. Chalmers University of Technology, Göteborg
Zurück zum Zitat Kochar N, Merims R, Padia A (1981) Ethylene from ethanol. CEP (June):66–71 Kochar N, Merims R, Padia A (1981) Ethylene from ethanol. CEP (June):66–71
Zurück zum Zitat Lapola DM, Schaldach R, Alcamo J, Bondeau A, Koch J, Koelking C, Priess JA (2010) Indirect land-use changes can overcome carbon savings from biofuels in Brazil. Proc Natl Acad Sci 107(8):3388–3393CrossRef Lapola DM, Schaldach R, Alcamo J, Bondeau A, Koch J, Koelking C, Priess JA (2010) Indirect land-use changes can overcome carbon savings from biofuels in Brazil. Proc Natl Acad Sci 107(8):3388–3393CrossRef
Zurück zum Zitat Lehtikangas P (1999) Lagringshandbok för trädbränslen slu. Sveriges lantbruksuniversitet, Uppsala Lehtikangas P (1999) Lagringshandbok för trädbränslen slu. Sveriges lantbruksuniversitet, Uppsala
Zurück zum Zitat Lindholm EL (2006) Energy use in Swedish forestry and its environmental impact. SLU (Sveriges lantbruksuniversitet), Uppsala Lindholm EL (2006) Energy use in Swedish forestry and its environmental impact. SLU (Sveriges lantbruksuniversitet), Uppsala
Zurück zum Zitat Liptow C, Tillman AM (2009) Comparative life cycle assessment of polyethylene based on sugarcane and crude oil; internal report. Chalmers University of Technology, Göteborg Liptow C, Tillman AM (2009) Comparative life cycle assessment of polyethylene based on sugarcane and crude oil; internal report. Chalmers University of Technology, Göteborg
Zurück zum Zitat Liptow C, Tillman A-M (2012) A comparative LCA study of polyethylene based on sugarcane and crude oil. JIE 16(3):420–435 Liptow C, Tillman A-M (2012) A comparative LCA study of polyethylene based on sugarcane and crude oil. JIE 16(3):420–435
Zurück zum Zitat Liu QP, Hou XD, Li N, Zong MH (2012) Ionic liquids from renewable biomaterials: synthesis, characterization and application in the pretreatment of biomass. Green Chem 14(2):304–307CrossRef Liu QP, Hou XD, Li N, Zong MH (2012) Ionic liquids from renewable biomaterials: synthesis, characterization and application in the pretreatment of biomass. Green Chem 14(2):304–307CrossRef
Zurück zum Zitat MacLean HL, Spatari S (2009) The contribution of enzymes and process chemicals to the life cycle of ethanol. Environ Res Lett 4:014001CrossRef MacLean HL, Spatari S (2009) The contribution of enzymes and process chemicals to the life cycle of ethanol. Environ Res Lett 4:014001CrossRef
Zurück zum Zitat Naturvårdsverket Swedish EPA (2010) Sågverk Fakta om branschen och dess miljöpåverkan branschfakta utgåva 1, April 2010 (Sawmill—facts from the industry and its environmental impact) branschfakta utgåva 1, April 2010. Naturvårdsverket, Stockholm Naturvårdsverket Swedish EPA (2010) Sågverk Fakta om branschen och dess miljöpåverkan branschfakta utgåva 1, April 2010 (Sawmill—facts from the industry and its environmental impact) branschfakta utgåva 1, April 2010. Naturvårdsverket, Stockholm
Zurück zum Zitat Naumann K (2011) Abschlussworkshop Monitoring zur Wirkung nationaler und internationaler gesetzlicher Rahmenbedingungen auf die Marktentwicklung im Biokraftstoffsektor Deutsches Biomasse Forschungs Zentrum Naumann K (2011) Abschlussworkshop Monitoring zur Wirkung nationaler und internationaler gesetzlicher Rahmenbedingungen auf die Marktentwicklung im Biokraftstoffsektor Deutsches Biomasse Forschungs Zentrum
Zurück zum Zitat Nordfjell T, Nilsson P, Henningsson M, Wästerlund I (2008) Unutilized biomass resources in Swedish young dense forests. Paper presented at the World Bioenergy Nordfjell T, Nilsson P, Henningsson M, Wästerlund I (2008) Unutilized biomass resources in Swedish young dense forests. Paper presented at the World Bioenergy
Zurück zum Zitat PRé Consultants SimaPro 7.2. Amersfoort, The Netherlands, accessed April 6, 2011 PRé Consultants SimaPro 7.2. Amersfoort, The Netherlands, accessed April 6, 2011
Zurück zum Zitat Sassner P, Galbe M, Zacchi G (2008) Techno-economic evaluation of bioethanol production from three different lignocellulosic materials. Biomass Bioenergy 32(5):422–430CrossRef Sassner P, Galbe M, Zacchi G (2008) Techno-economic evaluation of bioethanol production from three different lignocellulosic materials. Biomass Bioenergy 32(5):422–430CrossRef
Zurück zum Zitat Skogsstyrelsen (2010) Swedish Statistical yearbook of forestry 2010. Skogsstyrelsen Skogsstyrelsen (2010) Swedish Statistical yearbook of forestry 2010. Skogsstyrelsen
Zurück zum Zitat Slade R, Bauen A, Shah N (2009) The greenhouse gas emissions performance of cellulosic ethanol supply chains in Europe. Biotechnol Biofuels 2(15):1–19 Slade R, Bauen A, Shah N (2009) The greenhouse gas emissions performance of cellulosic ethanol supply chains in Europe. Biotechnol Biofuels 2(15):1–19
Zurück zum Zitat Swedish Forest Industries Federation (2010) The Swedish forest industries: facts and figures 2009. Swedish Forest Industries Federation, Stockholm, Sweden Swedish Forest Industries Federation (2010) The Swedish forest industries: facts and figures 2009. Swedish Forest Industries Federation, Stockholm, Sweden
Zurück zum Zitat Tillman A-M (2000) Significance of decision-making for LCA methodology. Environ Impact Assess Rev 20(1):113–123CrossRef Tillman A-M (2000) Significance of decision-making for LCA methodology. Environ Impact Assess Rev 20(1):113–123CrossRef
Zurück zum Zitat Uihlein A, Schebek L (2009) Environmental impacts of a lignocellulose feedstock biorefinery system: An assessment. Biomass Bioenergy 33(5):793–802CrossRef Uihlein A, Schebek L (2009) Environmental impacts of a lignocellulose feedstock biorefinery system: An assessment. Biomass Bioenergy 33(5):793–802CrossRef
Zurück zum Zitat Verardi A, De Bari I, Ricca E, Calabro V (2011) Hydrolysis of lignocellulosic biomass: current status of processes and technologies and future perspectives. Bioethanol, pp 95–122 Verardi A, De Bari I, Ricca E, Calabro V (2011) Hydrolysis of lignocellulosic biomass: current status of processes and technologies and future perspectives. Bioethanol, pp 95–122
Zurück zum Zitat Wesolowski D (2005) The sustainability of ethanol fuel in the United States Wesolowski D (2005) The sustainability of ethanol fuel in the United States
Zurück zum Zitat Zhao X, Cheng K, Liu D (2009) Organosolv pretreatment of lignocellulosic biomass for enzymatic hydrolysis. Appl Microbiol Biotechnol 82(5):815–827CrossRef Zhao X, Cheng K, Liu D (2009) Organosolv pretreatment of lignocellulosic biomass for enzymatic hydrolysis. Appl Microbiol Biotechnol 82(5):815–827CrossRef
Metadaten
Titel
Ethylene based on woody biomass—what are environmental key issues of a possible future Swedish production on industrial scale
verfasst von
Christin Liptow
Anne-Marie Tillman
Matty Janssen
Ola Wallberg
Glenn A. Taylor
Publikationsdatum
01.06.2013
Verlag
Springer Berlin Heidelberg
Erschienen in
The International Journal of Life Cycle Assessment / Ausgabe 5/2013
Print ISSN: 0948-3349
Elektronische ISSN: 1614-7502
DOI
https://doi.org/10.1007/s11367-013-0564-6

Weitere Artikel der Ausgabe 5/2013

The International Journal of Life Cycle Assessment 5/2013 Zur Ausgabe