Skip to main content
Log in

Definition and sturcture characteristics of pores in mylonitized organic-rich shales

  • Research Paper
  • Published:
Science China Earth Sciences Aims and scope Submit manuscript

Abstract

Gas shales with a high gas content were drilled in the Lower Cambrian Lujiaping Formation in the northeastern Sichuan Basin, close to the Chengkou Fault in the Dabashan arc-like thrust fold belt. The equivalent vitrinite reflectance values of organic matters are over 4.0% Ro. The pore structures of the shales were investigated based on microscopy, field emission scanning electron microscopy (FESEM) observations, and low temperature N2 adsorption analysis. The study suggests that cleavages, comprising clay minerals mixed up with organic matter and other insoluble residues, were developed in the rock layers. The clay minerals are directionally arranged, displaying a mylonitized texture. Abundant nanometer-size organic matter and clay mineral particles are well mixed in the cleavage domains, which developed the mylonitized pore system that consists of nanometer-size intergranular pore spaces, aggregate pore spaces in clay mineral flakes and pore network. This mylonitized pore system has high specific surface area, high methane adsorption capacity, and high capillary pressure, which collectively contributes to the preservation of shale gas in such a complex tectonic area. The discovery of the mylonitized pore structure in organic-rich shales may reveal a new mechanism of shale gas enrichment in complex tectonic areas with over-mature organic matter in the northeastern part of Sichuan Basin.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • Ambrose R J, Hartman R C, Dias-Campos M, et al. 2010. New pore-scale considerations for shale gas in place calculations. SPE Unconventional Gas Conference. SPE Paper 131772: 17

    Google Scholar 

  • Beliveau D. 1993. Honey, I Shrunk the Pores. J Can Petrol Technol, 32: 15–17

    Article  Google Scholar 

  • Boyer C, Keischnick J, Lewis R E, et al. 2006. Producing gas from its source. Oilfield Rev, 18: 36–49

    Google Scholar 

  • Chalmers G R L, Bustin R M. 2008. Lower Cretaceous gas shales in northeastern British Columbia, Part I: Geological controls on methane sorption capacity. Bull Can Petrol Geol, 56: 1–21

    Article  Google Scholar 

  • Curtis J B. 2002. Fractured shale-gas systems. AAPG Bull, 86: 1921–1938

    Google Scholar 

  • Curtis M E, Sondergeld C H, Ambrose R J, et al. 2012. Microstructural investigation of gas shales in two and three dimensions using nanometer-scale resolution imaging. AAPG Bull, 96: 665–677

    Article  Google Scholar 

  • Dong C B. 1996. The structural analysis of the shear fold in Hongyanbei Area, Yun County, Hubei Province (in Chinese). J Chengdu Inst Technol, 23: 88–95

    Google Scholar 

  • Hao F., Zou H., Lu Y. 2013. Mechanisms of shale gas storage: Implications for shale gas exploration in China. AAPG Bull, 97: 1325–1346

    Article  Google Scholar 

  • Himeno S, Tomita T, Suzuki K, et al. 2007. Characterization and selectivity for methane and carbon dioxide adsorption on the all-silica DD3R zeolite. Microporous Mesoporous Mater, 98: 62–69

    Article  Google Scholar 

  • Hou Q L, Li H J, Fan J J, et al. 2012. Structure and coalbed methane occurrence in tectonically deformed coals. Sci China Earth Sci, 55: 1755–1763

    Article  Google Scholar 

  • Ju Y W, Jiang B, Hou Q L, et al. 2005. Relationship between nanoscale deformation of coal structure and metamorphic-deformed environments (in Chinese). Chin Sci Bull, 17: 1884–1892

    Google Scholar 

  • Ju Y W. Structures and Physical Properties of Tectonic Coal (in Chinese). 2005. Xuzhou: China University of Mining and Technology Press. 102–115

    Google Scholar 

  • Murata K, Mitsuoka K, Hirai T, et al. 2000. Structural determinants of water permeation through aquaporin-1. Nature, 407: 599–605

    Article  Google Scholar 

  • Han H, Li D H, Ma Y, et al. 2012. The origin of marine shale gas in the northeastern Sichuan Basin, China: Implications from chemical composition and stable carbon isotope of desorbed gas (in Chinese). Acta Petrol Sin, 5: 453–459

    Google Scholar 

  • Jarvie D. 2004. Evaluation of Hydrocarbon Generation and Storage in Barnett Shale, Fort Worth Basin, Texas: The University of Texas at Austin. Bureau of Economic Geology/PTTC. 93–94

    Google Scholar 

  • Li H, Ogawa Y. 2001. Pore structure of sheared coals and related coalbed methane. Environ Geol, 40: 1455–1461

    Article  Google Scholar 

  • Li H, Ogawa Y, Shimada S. 2003. Mechanism of methane flow through sheared coals and its role on methane recovery. Fuel, 82: 1271–1279

    Article  Google Scholar 

  • Loucks R G, Reed R M, Ruppel S C, et al. 2009. Morphology, genesis, and distribution of nanometer-scale pores in siliceous mudstones of the Mississippian Barnett Shale. J Sediment Res, 79: 848–861

    Article  Google Scholar 

  • Loucks R G, Reed R M, Ruppel S C, et al. 2012. Spectrum of pore types and networks in mudrocks and a descriptive classification for matrix-related mudrock pores. AAPG Bull, 96: 1071–1098

    Article  Google Scholar 

  • Ma L, Chen H J, Gan K W, et al. 2004. Tectonics and Marine Petroleum Geology in South China (in Chinese). Beijing: Geological Publishing House. 1–283

    Google Scholar 

  • Milliken K L, Rudnicki M, Awwiller D N, et al. 2013. Organic matter-hosted pore system, Marcellus Formation (Devonian), Pennsylvania. AAPG Bull, 97: 177–200

    Article  Google Scholar 

  • Ross D J K, Bustin R M. 2009. The importance of shale composition and pore structure upon gas storage potential of shale gas reservoirs. Mar Petrol Geol, 26: 916–927

    Article  Google Scholar 

  • Schieber J. 2010. Common themes in the formation and preservation of intrinsic porosity in shales and mudstones: Illustrated with examples from across the Phanerozoic. SPE Unconventional Gas Conference. SPE Paper 132379: 10

    Google Scholar 

  • Slatt M S, O’Brien N R. 2011. Pore types in the Barnett and Woodford gas shales: Contribution to understanding gas storage and migration pathways in fine-grained rocks. AAPG Bull, 95: 2017–2030

    Article  Google Scholar 

  • Song B. 2010. Pressure transient analysis and production analysis for New Albany ahale gas wells. Master’s Thesis. Texas: Texas A&M University

    Google Scholar 

  • Sondergeld, C H, Ambrose R J, Rai C S, et al. 2010. Microstructural studies of gas shales. SPE Unconventional Gas Conference. SPE Paper 131771: 17

    Google Scholar 

  • Wang F P, Reed R M. 2009. Pore Networks and Fluid Flow in Gas Shales. SPE Annual Technical Conference Exhibition. SPE Paper 124253: 3

    Google Scholar 

  • Wang P Q. 2001. The study for quantitative analysis of water on clays and their hydration mechanism (in Chinese). Doctoral Dissertation. Chengdu: Southwest Petroleum University. 10–144

    Google Scholar 

  • Wei G Y, Zhang C J. 1995. Petrology Introductory Tutorial (in Chinese). Beijing: Geological Publishing House. 155–171

    Google Scholar 

  • Zhang G W, Zhang B R, Yuan X C, et al. 2001. Qinling Orogenic Belt and Continental Dynamics (in Chinese). Beijing: Science Press. 117–321

    Google Scholar 

  • Zhang H F, Fang C L, Gao X Z, et al. 1999. Petroleum Geology (in Chinese). Beijing: Petroleum Industry Press. 120–124

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to NingNing Zhong.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ma, Y., Zhong, N., Han, H. et al. Definition and sturcture characteristics of pores in mylonitized organic-rich shales. Sci. China Earth Sci. 57, 3027–3034 (2014). https://doi.org/10.1007/s11430-014-4968-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11430-014-4968-3

Keywords

Navigation