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Nanotribological behaviors of in situ nanoparticles doped molecular deposition films

  • Articles / Mechanical Engineering
  • Published:
Chinese Science Bulletin

Abstract

The molecular deposition films of poly (diallyl dimethylammonium chloride) (PDDA) and poly (acrylicacid) (PAA) with Cu2+ on quartz and glass substrates were prepared in laboratory first, then different bilayers films were dipped into fresh Na2S aqueous solution. As a result, CuS nanoparticles were fabricated in multilayer molecular deposition films in situ. The structure and nanotribological properties of the composite films were analyzed by ultraviolet-visible (UV-visible) spectroscopy, XPS and atomic force microscope (AFM). It was found that the CuS nanoparticles were homogeneously distributed throughout the whole film. And these films had a much smaller friction force than their substrates and higher antiwear life than pristine PDDA/PAA molecular deposition films. The fluctuation and variation trend of the topography, hardness, and friction with the AFM indentation length were also investigated.

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References

  1. Decher G, Hong J D, Schmitt J. Buildup of ultrathin multilayer films by a self-assembly process: III Consecutively alternating adsorption of anionic and cationic polylectrolytes on charged surface. Thin Solid Films, 1992, 210–211: 831–835

    Article  Google Scholar 

  2. Decher G. Layered nanoarchitectures via directed assembly of anionic and cationic molecules. Comprehensive Supramole Chem, 1996, 9: 507–528

    Google Scholar 

  3. Wang D G, Feng D P, Lan H Q. The preparation and application of molecular deposition films (in Chinese). Mater Mech Engin, 2003, 27: 1–3

    Google Scholar 

  4. Hu X L, Zhang C H, Luo J B, et al. Formation and tribology properties of polyfluoroalkylmethacrylate film on the magnetic head surface. Chinese Sci Bull, 2005, 50: 2385–2390

    Article  Google Scholar 

  5. Zhang S W, Lan H Q. Developments in tribological research on ultrathin films. Trib Inter, 2002, 35: 321–327

    Article  Google Scholar 

  6. Wang Q B, Gao M L, Zhang S W. Nanofriction properties of molecular deposition films. Sci China Ser B: Chem, 2000, 43: 137–142

    Article  Google Scholar 

  7. Wang Q B, Gao M L, Zhang S W. Tribological application of molecular deposition (MD) films. Mater Sci Engin C, 1999, 10: 127–129

    Article  Google Scholar 

  8. Kang X H, Wang B, Zhu L, et al. Synthesis and tribological property study of oleic acid-modified copper sulfide nanoparticles. Wear, 2008, 265: 150–154

    Article  Google Scholar 

  9. Yang G H, Zhang X T, Xun J, et al. Investigation of tribological properties of composite C60-LB films. Chinese Sci Bull, 2006, 51: 1811–1817

    Article  Google Scholar 

  10. Zhang S W, Feng D P, Wang D G. Tribological behaviors of composite molecular deposition films. Triby Inter, 2005, 38: 959–965

    Article  Google Scholar 

  11. Dante S, Hou Z, Risbud S, et al. Nucleation of iron oxy-hydroxide nanoparticles by layer-by-layer polyionic assemblies, Langmuir, 1999, 15: 2176–2182

    Article  Google Scholar 

  12. Joly S, Kane R, Radzilowdki L, et al. Multilayer nanoreactors for metallic and semiconducting particles, Langmuir, 2000, 16: 1354–1359

    Article  Google Scholar 

  13. Caykara T, Inam R. Determination of the competitive adsorption of heavy metal ions on poly(N-vinyl-2-pyrrolidone/acrylic acid) hydrogels by differential pulse polarography. J Appl Poly Sci, 2003, 89: 2013–2018

    Article  Google Scholar 

  14. Peng C S, Song S X, Gu Q B. Scanning Probe Microscopy Principles and Applications (in Chinese). Beijing: Chemical Industry Press, 2007. 53–77

    Google Scholar 

  15. Yang L, Luo Y F, Jia X R, et al. Microtribological property of self-assembly multilayer films based on PAMAM dendrimers (in Chinese). Acta Polymerica Sin, 2004, 5: 780–784

    Google Scholar 

  16. Arrighi V, McEwen I J, Qian H, et al. The glass transition and interfacial layer in styrene-butadiene rubber containing silica nanofiller. Polymer, 2003, 44: 6259–6266

    Article  Google Scholar 

Download references

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Correspondence to DeGuo Wang.

Additional information

Supported by the National Natural Science Foundation of China (Grant No. 50575151), National Basic Research Program of China (Grant No. 2007CB607604), and Opening Fund of the State Key Laboratory of Tribology at Tsinghua University (Grant No. SKLT05-02)

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Guo, Y., Wang, D. & Zhang, S. Nanotribological behaviors of in situ nanoparticles doped molecular deposition films. Chin. Sci. Bull. 54, 4571–4576 (2009). https://doi.org/10.1007/s11434-009-0574-8

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  • DOI: https://doi.org/10.1007/s11434-009-0574-8

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