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Comparative Analysis of Temperature-dependent Raman Spectra of GaN and GaN/Mg Films

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Abstract

The Raman spectra of unintentionally doped gallium nitride (GaN) and Mg-doped GaN films were investigated and compared at room temperature and low temperature. The differences of E2 and A1(LO) mode in two samples are discussed. Stress relaxation is observed in Mg-doped GaN, and it is suggested that Mg-induced misfit dislocation and electron–phonon interaction are the possible origins. A peak at 247 cm−1 is observed in both the Raman spectra of GaN and Mg-doped GaN. Temperature-dependent Raman scattering experiment of Mg-doped GaN shows the frequency and intensity changes of this peak with temperature. This peak is attributed to the defect-induced vibrational mode.

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References

  1. Ramsteiner M., Menniger J., Brandt O. et al., Shallow donors in GaN studied by electronic Raman scattering in resonance with yellow luminescence transitions, Appl. Phys. Lett., 1996, 69: 1276–1278

    Article  ADS  Google Scholar 

  2. Siegle H., Loa I., Thurian P. et al., Comment on “Shallow donors in GaN studied by electronic Raman scattering in resonance with yellow luminescence transitions ”, Appl. Phys. Lett., 1997, 70: 909

    Article  ADS  Google Scholar 

  3. Jiang D.-S., Ramsteiner M., Ploog K.-H. et al., Defect-induced Raman scattering in resonance with yellow luminescence transitions in hexagonal GaN on a sapphire substrate, Appl. Phys. Lett., 1998, 72: 365–367

    ADS  Google Scholar 

  4. Siegle H., Kaschner A., Hoffmann A. et al., Raman scattering from defects in GaN: the question of vibrational or electronic scattering mechanism, Phys. Rev., B, 1998, 58: 13619–13626

    Article  ADS  Google Scholar 

  5. Kaczmarczyk G., Kaschner A., Hoffmann A. et al., Impurity-induced modes of Mg, As, and C in hexagonal and cubic GaN, Phys. Rev., B, 2000, 61: 5353–5357

    Article  ADS  Google Scholar 

  6. Kozawa T., Kachi T., Kano H. et al., Raman scattering from LO phonon-plasmon coupled modes in gallium nitride, J. Appl. Phys., 1994, 75: 1098–1101

    Article  ADS  Google Scholar 

  7. Perlin P., Jauberthie-Carillon C., Itie J.-P. et al., Raman scattering and x-ray-absorption spectroscopy in gallium nitride under high pressure, Phys. Rev., B, 1992, 45: 83–89

    ADS  Google Scholar 

  8. Harima H., Properties of GaN and related compounds studied by means of Raman scattering, J. Phys.: Condens. Matter., 2002, 14: R967–R993

    Article  ADS  Google Scholar 

  9. Popovici G., Xu G.-Y., Botchkarev A. et al., Raman scattering and photoluminescence of Mg-doped GaN films grown by molecular beam epitaxy, J. Appl. Phys., 1997, 82: 4020–4023

    Article  ADS  Google Scholar 

  10. Xu B., Yu Q.-X., Wu Q.-H. et al., Effects of strain and Mg-dopant on the photoluminescence spectra in P-type GaN, Acta Phys. Sin., 2004, 53: 204–209 (in Chinese)

    Google Scholar 

  11. Lee I.-H., Choi I.-H., Lee C.-R. et al., Stress relaxation in Si-doped GaN studied by Raman spectroscopy, J. Appl. Phys., 1998, 83: 5787–5791

    ADS  Google Scholar 

  12. Ruvimov S., Liliental-Weber Z., Suski T. et al., Effect of Si doping on the dislocation structure of GaN grown on the A-face of sapphire, Appl. Phys. Lett., 1996, 69: 990–992

    ADS  Google Scholar 

  13. Cardona M. and Güntherodt G., Light Scattering in Solids IV, Berlin Heidelberg New York: Springer, 1984, 127–145

    Google Scholar 

  14. Pophristic M., Long F.-H., Schurman M. et al., Raman microscopy of lateral epitaxial overgrowth of GaN on sapphire, Appl. Phys. Lett., 1999, 74: 3519–3521

    Article  ADS  Google Scholar 

  15. Yu. Davydov V., Kitaev Yu E., Goncharuk I.-N. et al., Phonon dispersion and Raman scattering in hexagonal GaN and AlN, Phys. Rev., B, 1998, 58: 12899–12907

    ADS  Google Scholar 

  16. Harima H., Inoue T., Nakashima S. et al., Electronic properties in P-type GaN studied by Raman scattering, Appl. Phys. Lett., 1998, 73: 2000–2002

    Article  ADS  Google Scholar 

  17. Chaldyshev V.-V., Pollak F.-H., Pophristic M. et al., Micro-Raman investigation of the N-dopant distribution in lateral epitaxial overgrown GaN/sapphire (0001), J. Electron. Mater., 2002, 31: 631–634

    Google Scholar 

  18. Florescu D.-I., Asnin V.-M., Pollak F.-H. et al., High spatial resolution thermal conductivity and Raman spectroscopy investigation of hydride vapor phase epitaxy grown N–GaN/sapphire (0001): doping dependence, J. Appl. Phys., 2000, 73: 3295–3299

    ADS  Google Scholar 

  19. Kasic A., Schubert M., Saito Y. et al., Effective electron mass and phonon modes in N-type hexagonal InN, Phys. Rev., B, 2002, 65: 115206

    ADS  Google Scholar 

  20. Limmer W., Ritter W., Sauer R. et al., Raman scattering in ion-implanted GaN, Appl. Phys. Lett., 1998, 72: 2589–2591

    Article  ADS  Google Scholar 

  21. Kaschner A., Siegle H., Kaczmarozyk G. et al., Local vibrational modes in Mg-doped GaN grown by molecular beam epitary, Appl. Phys. Lett., 1999, 74: 3281–3283

    ADS  Google Scholar 

  22. Harima H., Inoue T., Nakashima S. et al., Local vibrational modes as a probe of activation process in P-type GaN, Appl. Phys. Lett., 1999, 75: 1383–1385

    Article  ADS  Google Scholar 

  23. Kaschner A., Kaczmarczyk G., Hoffmann A. et al., Defect complexes in highly Mg-doped GaN studied by Raman spectroscopy, Phys. Stat. Sol., B, 1999, 216: 551–555

    Article  Google Scholar 

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Correspondence to Wang Rui-min.

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Translated from Chinese Journal of Semiconductors, 2005, 26(4) (in Chinese)

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Wang, Rm., Chen, Gd., Lin, J.Y. et al. Comparative Analysis of Temperature-dependent Raman Spectra of GaN and GaN/Mg Films. Front. Phys. China 1, 112–116 (2006). https://doi.org/10.1007/s11467-005-0007-3

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