Skip to main content
SpringerLink
Log in

Study of electrochemical performances of multi-doped spinel Li1.1Mn1.85Co0.075Ni0.075O4 at 4.3 and 5 V

  • Original Paper
  • Published:
Ionics Aims and scope Submit manuscript

Abstract

Li1.1Mn2 − 2x Co x Ni x O4 (x = 0, 0.075) spinel powders were successfully synthesized using a liquid stirred tank reactor method. The electrochemical performances of the undoped and doped spinels at 4.3 and 5 V were investigated by X-ray diffraction, field-emission scanning electron microscopy, and electrochemical impedance spectroscopy. The capacity of Li1.1Mn2 − 2x Co x Ni x O4 could be divided into two parts, with 4.3 V as the dividing line in the 3–5 V charge–discharge range. Low capacity and good cyclic performance were obtained when cycled in the 3–4.3 V range for the multi-doped Li1.1Mn2 − 2x Co x Ni x O4 spinel. In comparison with multi-doped spinel at 4.3 V, the results of the cyclic performance worsened at 5 V because the structure underwent further shrinkage, the charge transfer resistance rose and the electrolyte decomposed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. Tarascon JM, Armand M (2001) Nature 414:359

    Article  CAS  Google Scholar 

  2. Teruaki K, Kazuyoshi U, Kenji T, Mineo S (2007) J Power Sources 167:499

    Article  Google Scholar 

  3. Wu NN, Yang DJ, Liu JH, Tian WH (2012) Electrochim Acta 62:91

    Article  CAS  Google Scholar 

  4. Amatucci GG, Schmutz CN, Blyr A, Sigala C, Gozdz AS, Larcher D, Tarascon JM (1997) J Power Sources 69:11

    Article  CAS  Google Scholar 

  5. Guyomard D, Tarascon JM (1992) J Electrochem Soc 139:937

    Article  CAS  Google Scholar 

  6. Thackeray MM (1997) Prog Solid State Chem 25:1

    Article  CAS  Google Scholar 

  7. Wang C, Lu SG, Kan SR, Pang J, Jin WR, Zhang XJ (2009) J Power Sources 189:607

    Article  CAS  Google Scholar 

  8. Huang H, Wang C, Zhang WK, Gan YP, Kang L (2008) J Power Sources 184:583

    Article  CAS  Google Scholar 

  9. Wei YJ, Yan LY, Wang CZ, Xu XG, Wu F, Chen G (2004) J Phys Chem B 108:18547

    Article  CAS  Google Scholar 

  10. Göktepe H, Şahan H, Patat Ş, Ülgen A (2009) Ionics 15:233

    Article  Google Scholar 

  11. Alcantara R, Jaraba M, Lavela P, Lloris JM, Perez Vicente C, Tirado JL (2005) J Electrochem Soc 152:A13

    Article  CAS  Google Scholar 

  12. Şahan H, Göktepe H, Patat Ş (2008) Inorg Mater 44:420

    Article  Google Scholar 

  13. Rajakumar S, Thirunakaran R, Sivashanmugam A, Yamaki J, Gopukumara S (2009) J Electrochem Soc 156:A246

    Article  CAS  Google Scholar 

  14. Hwang BJ, Santhanam R, Hu SG (2002) J Power Sources 108:250

    Article  CAS  Google Scholar 

  15. Rajakumar S, Thirunakaran R, Sivashanmugam A, Yamaki J, Gopukumar S (2011) J Appl Electrochem 41:129

    Article  CAS  Google Scholar 

  16. Taniguchi I (2005) Mater Chem Phys 92:172

    Article  CAS  Google Scholar 

  17. Molenda J, Marzec J, Wierczek KS, Ojczyk W, Ziemnicki M, Molenda M, Drozdek M, Dziembaj R (2004) Solid State Ionics 171:215

    Article  CAS  Google Scholar 

  18. Park SH, Kang SH, Belharouak I, Sun YK, Amine K (2008) J Power Sources 177:177

    Article  CAS  Google Scholar 

  19. Levi MD, Levi EA, Aurbach DJ (1997) Electroanal Chem 421:79

    Article  CAS  Google Scholar 

  20. Shu D, Chung KY, Cho WI, Kim KB (2003) J Power Sources 114:253

    Article  CAS  Google Scholar 

  21. Zhang SS, Xu K, Jow TR (2004) Electrochim Acta 49:1057

    Article  CAS  Google Scholar 

  22. Lee YS, Leea KS, Sunb YK, Leec YM, Kima DW (2011) J Power Sources 196:6997

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was financially supported by the National High-Tech Research and Development (863) Plan of China (no. 2011AA11A230).

Author information

Authors and Affiliations

  1. School of Chemical Engineering and Environment, Beijing Institute of Technology, Beijing, 100081, China

    Jianhong Liu & Borong Wu

  2. CITIC Guoan Mengguli Power Science and Technology Co., LTD, Beijing, 102200, China

    Jianhong Liu, Zhaoqin Sun, Jiaona Xie, Hongyu Chen & Ningning Wu

Authors
  1. Jianhong Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Zhaoqin Sun
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Jiaona Xie
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Hongyu Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Ningning Wu
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Borong Wu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Borong Wu.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Liu, J., Sun, Z., Xie, J. et al. Study of electrochemical performances of multi-doped spinel Li1.1Mn1.85Co0.075Ni0.075O4 at 4.3 and 5 V. Ionics 19, 1867–1874 (2013). https://doi.org/10.1007/s11581-013-0920-3

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11581-013-0920-3

Keywords

Search

Navigation