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Kinetics, isotherm and thermodynamic investigations for the adsorption of Co(II) ion onto crystal violet modified amberlite IR-120 resin

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Abstract

The adsorption characteristics of crystal violet (CY)-modified amberlite IRA-120 resin for the removal of Co(II) ion from aqueous medium at different experimental conditions were established by means of batch method. The adsorption uptake was increased with the increase in contact time and temperature. The adsorption process was controlled by pseudo-first-order kinetic model. Adsorption isotherms were expressed by Langmuir and Freundlich adsorption models. The Freundlich adsorption model fitted the experimental data reasonably well compared to the Langmuir model. A well-known thermodynamic equation was used to assess the ΔG 0 (standard free energy change), ∆H 0 (enthalpy change), and ∆S 0 (entropy change). The thermodynamic data was indicative of the spontaneous nature of the endothermic sorption process of Co(II) ion onto CY-modified amberlite IRA-120 resin.

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References

  1. Fu F, Wang Q (2011) Removal of heavy metal ions from wastewaters: a review. J Env Manag 92:407–418

    Article  CAS  Google Scholar 

  2. Sharma G, Pathania D, Naushad M (2014) Fabrication, characterization and antimicrobial activity of polyaniline Th (IV) tungstomolybdophosphate nanocomposite material: efficient removal of toxic metal ions from water. Chem Eng J 251:413–421

    Article  CAS  Google Scholar 

  3. Naushad M, Khan MA, ALOthman ZA, Khan MR (2014) Adsorptive removal of nitrate from synthetic and commercially available bottled water samples by using De-Acidite FF-IP resin. J Ind Eng Chem 20:3400–3407

    Article  CAS  Google Scholar 

  4. Naushad M, ALOthman ZA, Khan MR, ALQahtani NJ, ALSohaimi IH (2014) Equilibrium, kinetics and thermodynamic studies for the removal of organophosphorus pesticide using Amberlyst-15 resin: quantitative analysis by liquid chromatography–mass spectrometry. J Ind Eng Chem 20:4393–4400

    Article  CAS  Google Scholar 

  5. Naushad M, ALOthman ZA, Khan MR, Wabaidur SM (2013) Removal of bromate from water using De-Acidite FF-IP resin and determination by ultra-performance liquid chromatography-tandem mass spectrometry. CLEAN–Soil, Air, Water 41:528–533

    Article  CAS  Google Scholar 

  6. Awual MR, Yaita T, Okamoto Y (2014) A novel ligand based dual conjugate adsorbent for cobalt(II) and copper(II) ions capturing from water. Sensors and Actuators B: Chemical 203:71–80

    Article  CAS  Google Scholar 

  7. ALOthman ZA, Naushad, Inamuddin D (2011) Organic–inorganic type composite cation exchanger poly-o-toluidine Zr(IV) tungstate: preparation, physicochemical characterization and its analytical application in separation of heavy metals. Chem Eng J 172:369–375

    Article  CAS  Google Scholar 

  8. Zainol Z, Nicol MJ (2009) Comparative study of chelating ion exchange resins for the recovery of nickel and cobalt from laterite leach tailings. Hydrometallurgy 96:283–287

    Article  CAS  Google Scholar 

  9. Kumar A, Sharma G, Naushad M, Kalia S, Singh P (2014) A polyacrylamide/Ni0.02Zn0.98O nanocomposite with high solar light photoacatalytic activity and efficient adsorption capacity for toxic dyes removal. Ind Eng Chem Res 53:15549–15560

    Article  CAS  Google Scholar 

  10. Awual MR, Ismael M, Yaita T (2014) Efficient detection and extraction of cobalt(II) from lithium ion batteries and wastewater by novel composite adsorbent. Sensors & Act B: Chem 191:9–18

    Article  CAS  Google Scholar 

  11. El-Safty SA, Awual MR, Shenashen MA, Shahat A (2013) Simultaneous optical detection and extraction of cobalt(II) from lithium ion batteries using nanocollector monoliths. Sensors & Act B: Chem 176:1015–1025

    Article  CAS  Google Scholar 

  12. Lauwerys R, Lison D (1994) Health risks associated with cobalt exposure—an overwiew. The Sci of the Total Envir 150:1–6

    Article  CAS  Google Scholar 

  13. Rengaraj S, Kim Y, Joo CK, Choi K, Yi J (2004) Batch adsorptive removal of copper ions in aqueous solutions by ion exchange resins: 1200H and IRN97H. Korean J Chem Eng 21:187–194

    Article  CAS  Google Scholar 

  14. Omer Y, Yalcin A, Fuat G (2003) Removal of copper, nickel, cobalt and manganese from aqueous solution by kaolinite. Water Res 37:948–952

    Article  Google Scholar 

  15. Nabi SA, Laiq E, Islam A (2001) Selective separation of metal ions on strong acid cation-exchange resin loaded with crystal violet. Acta Chromatographica 11:118–129

    CAS  Google Scholar 

  16. Lehto J, Harjula R, Leinonen H, Paajanen A, Laurila T, Mononen K, Saarinen L (1996) Advanced separation of harmful metals from industrial waste effluents by ion exchange. J Radioanal Nucl Chem 208:435–443

    Article  CAS  Google Scholar 

  17. Koivula R, Lehto J, Pajo L, Gale T, Leinonen H (2000) Purification of metal plating rinse waters with chelating ion exchangers. Hydrometallurgy 56:93–108

    Article  CAS  Google Scholar 

  18. Naushad M (2014) Surfactant assisted nano-composite cation exchanger: development, characterization and applications for the removal of toxic Pb2+ from aqueous medium. Chem Eng J 235:100–108

    Article  CAS  Google Scholar 

  19. Ajmal M, Rao RAK, Khan MA (2005) Adsorption of copper from aqueous solution on Brassica cumpestris. J Hazard Mater 122:177–183

    Article  CAS  Google Scholar 

  20. Lagergren S (1898) About the theory of so called adsorption of soluble substances, Kungliga Svenska Vetenskapsakademiens. Handlingar, Band 24:1–39

    Google Scholar 

  21. HO YS, Mckay G, Wase DAJ, Foster CF (2000) Study of the sorption of divalent metal ions on to peat. Ads Sci and Tech 18:639–650

    Article  CAS  Google Scholar 

  22. Liu HJ, Yang F, Zheng YM, Kang J, Qu JH, Chen JP (2011) Improvement of metal adsorption onto chitosan/Sargassum sp. composite sorbent by an innovative ion-imprint technology. Water Res 45:145–154

    Article  CAS  Google Scholar 

  23. Hall KR, Eagleton LC, Acrivos A, Vermeulen T (1966) Pore-and solid-diffusion kinetics in fixed-bed adsorption under constant-pattern conditions. Ind & Eng Chem Fund 5:212–223

    Article  CAS  Google Scholar 

  24. Wang L, Zhang J, Zhao R, Li Y, Li C, Zhang C (2010) Adsorption of Pb(II) on activated carbon prepared from Polygonum orientale Linn.: kinetics, isotherms, pH, and ionic strength studies. Biores Technol 101:5808–5814

  25. Naushad M, ALOthman ZA, Khan MR (2013) Removal of malathion from water using De-Acidite FF-IP resin and determination by UPLC-MS/MS: equilibrium, kinetics and thermodynamic studies. Talanta 115:15–23

    Article  CAS  Google Scholar 

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Acknowledgments

This project was supported by King Saud University, Deanship of Scientific Research, College of Science Research Center.

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Correspondence to Mu. Naushad.

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Naushad, M., ALOthman, Z.A., Sharma, G. et al. Kinetics, isotherm and thermodynamic investigations for the adsorption of Co(II) ion onto crystal violet modified amberlite IR-120 resin. Ionics 21, 1453–1459 (2015). https://doi.org/10.1007/s11581-014-1292-z

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  • DOI: https://doi.org/10.1007/s11581-014-1292-z

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