Skip to main content

Advertisement

SpringerLink
Log in

Synthesis and characterization of spinel LiMn2O4 nanoparticles prepared by high-energy milling and hydrothermal method

  • Original Paper
  • Published:
Ionics Aims and scope Submit manuscript

Abstract

Spinel LiMn2O4 has been known to be a technologically important, environmental-friendly, and low-cost cathode material used in Li-based rechargeable batteries, and it is also widely available. Nanoparticle spinel LiMn2O4 has been synthesized by the top-down, high-energy milling, and hydrothermal methods. SEM images, X-ray diffraction patterns, and neutron high-resolution powder diffraction patterns have confirmed the nanocrystalline nature of the spinel LiMn2O4 samples. Raman and Fourier transform infrared (FTIR) measurements show typical absorption and vibration spectra typical for the spinel LiMn2O4 showing the formation of various metallic bonds in the sample. The strongest Raman and FTIR signals come from the higher frequency region, with weaker signals appearing in the lower frequency range.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12

Similar content being viewed by others

References

  1. Kim DK, Muralidharan P, Lee H-W, Ruffo R, Yang Y, Chan CK, Peng H, Huggins RA, Cui Y (2008) Nano Lett 8(11):3948–3952

    Article  CAS  Google Scholar 

  2. Knauth P (2009) Solid State Ionics 180:911–916

    Article  CAS  Google Scholar 

  3. Ganesh Kumar V, Gnanaraj JS, Ben-David S, Pickup DM, van-Eck ERH, Gedanken A, Aurbach D (2003) Chem Mater 15:4211–4216

    Article  Google Scholar 

  4. Jayaprakash N, Kalaiselvi N, Periasamy P (2008) Int J Electrochem Sci 3:476

    CAS  Google Scholar 

  5. Panca Putra TYS, Yonemura M, Torii S, Ishigaki T, Kamiyama T (2014) Solid state. Ionics 262:83–87

    Article  Google Scholar 

  6. Rajeswari N, Selvasekarpandian S, Prabharan SRS, Kawamura J, Iwai Y, Karthikeyan S, Proceedings of the 13th Asian Conference on Solid State Ionics, 17–20 July, 2012 Sendai, Japan, Copyright © 2012 by World Scientific Publishing Co. Pte. Ltd., Singapore, ISBN 978-981-4415-03-3, 515–522

  7. Jahja AK, Nugraha T, Fajar A, Kartini E (2009) Ind J Mat Sci. Special Edition: December 2009 123–126 (in Indonesian)

  8. Shioya T(2011) R&D Report, “SUMITOMO KAGAKU”, Sumitomo Chemical Co. Ltd. , Tsukuba Research Lab. I: 1–9

  9. Julien M, Camacho-Lopez MA (2004) Materials Science and Engineering B 108:179–186

    Article  Google Scholar 

  10. Lagashetty A, Havanoor V, Basavaraja S, Venkataraman A (2008) Indian J Chem Tech 15:41–44

    CAS  Google Scholar 

  11. Nakamura K, Shimokita K, Sakamoto Y, Michihiro Y, Moriga T, Kuwata N, Iwai Y, Kawamura J (2012) Proceedings of the 13th Asian Conference on Solid State Ionics, 17–20 July. Sendai, Japan, Copyright © 2012 by World Scientific Publishing Co. Pte. Ltd., Singapore, ISBN 978-981-4415-03-3, 289

Download references

Author information

Authors and Affiliations

  1. Center for Science and Technology of Advanced Materials, BATAN, Kawasan Puspiptek, Serpong, Tangerang, 15314, Indonesia

    Aziz K. Jahja, Mardiyanto Panitra, Wagiyo Honggowiranto, Salim Mustofa & Yunasfi Yunasfi

Authors
  1. Aziz K. Jahja
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Mardiyanto Panitra
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Wagiyo Honggowiranto
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Salim Mustofa
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yunasfi Yunasfi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Aziz K. Jahja.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Jahja, A.K., Panitra, M., Honggowiranto, W. et al. Synthesis and characterization of spinel LiMn2O4 nanoparticles prepared by high-energy milling and hydrothermal method. Ionics 22, 219–227 (2016). https://doi.org/10.1007/s11581-015-1438-7

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11581-015-1438-7

Keywords

Search

Navigation