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Honeycomb-like manganese oxide nanospheres for redox supercapacitors

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Abstract

Honeycomb-like MnO2 nanospheres were synthesized using stainless steel substrates by a facile chemical bath deposition method. The obtained nanospheres were about 200–400 nm in diameter and consisted of porous ultrathin nanosheets. Honeycomb-like MnO2 nanospheres exhibited a high specific capacitance of 240 F g−1 and 87.1% capacitance retention after 1000 cycles at a current density of 0.5 A g−1. These remarkable electrochemical results imply great potential for applications of the honeycomb-like MnO2 nanospheres in supercapacitors.

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References

  1. Babakhani B, Ivey DG (2010) Anodic deposition of manganese oxide electrodes with rod-like structures for application as electrochemical capacitors. J Power Sources 195:2110–2117

    Article  CAS  Google Scholar 

  2. Singu BS, Male U, Hong SE, Yoon KR (2016) Synthesis and performance of nickel hydroxide nanodiscs for redox supercapacitors. Ionics (Kiel) 22:1485–1491

    Article  CAS  Google Scholar 

  3. Singu BS, Palaniappan S, Yoon KR (2016) Polyaniline–nickel oxide nanocomposites for supercapacitor. J Appl Electrochem 46:1039–1047

    Article  CAS  Google Scholar 

  4. Singu BS, Yoon KR (2016) Porous manganese oxide nanospheres for pseudocapacitor applications. J Alloys Compd 695:771–778

    Article  Google Scholar 

  5. Wei W, Cui X, Chen W, Ivey DG (2011) Manganese oxide-based materials as electrochemical supercapacitor electrodes. Chem Soc Rev 40:1697–1721

    Article  CAS  Google Scholar 

  6. Zhang Y, Feng H, Wu X et al (2009) Progress of electrochemical capacitor electrode materials: a review. Int J Hydrog Energy 34:4889–4899

    Article  CAS  Google Scholar 

  7. Sydulu Singu B, Srinivasan P, Yoon KR (2016) Emulsion polymerization method for polyaniline-multiwalled carbon nanotube nanocomposites as supercapacitor materials. J Solid State Electrochem 20:3447–3457

    Article  CAS  Google Scholar 

  8. Xia H, Lai MO, Lu L (2011) Nanostructured manganese oxide thin films as electrode material for supercapacitors. JOM 63:54–59

    Article  CAS  Google Scholar 

  9. Kim KS, Park SJ (2011) Synthesis of nano-scale coated manganese oxide on graphite nanofibers and their high electrochemical performance. Synth Met 161:1966–1971

    Article  CAS  Google Scholar 

  10. Aghazadeh M, Asadi M, Maragheh MG et al (2016) Facile preparation of MnO2 nanorods and evaluation of their supercapacitive characteristics. Appl Surf Sci 364:726–731

    Article  CAS  Google Scholar 

  11. Lokhande CD, Dubal DP, Joo O-S (2011) Metal oxide thin film based supercapacitors. Curr Appl Phys 11:255–270

    Article  Google Scholar 

  12. Pawar SM, Pawar BS, Kim JH et al (2011) Recent status of chemical bath deposited metal chalcogenide and metal oxide thin films. Curr Appl Phys 11:117–161

    Article  Google Scholar 

  13. Yu SP, Liu RT, Yang WS et al (2014) Synthesis and electrocatalytic performance of MnO2-promoted Ag@Pt/MWCNT electrocatalysts for oxygen reduction reaction. J Mater Chem A 2:5371

    Article  CAS  Google Scholar 

  14. Sun M, Lan B, Lin T et al (2013) Controlled synthesis of nanostructured manganese oxide: crystalline evolution and catalytic activities. CrystEngComm 15:7010

    Article  CAS  Google Scholar 

  15. Brousse T, Toupin M, Dugas R et al (2006) Crystalline MnO[sub 2] as possible alternatives to amorphous compounds in electrochemical Supercapacitors. J Electrochem Soc 153:A2171

    Article  CAS  Google Scholar 

  16. Singu BS, Yoon KR (2017) Synthesis and characterization of MnO 2 -decorated graphene for supercapacitors. Electrochim Acta 231:749–758

    Article  CAS  Google Scholar 

  17. Singu BS, Yoon KR (2017) Porous manganese oxide nanospheres for pseudocapacitor applications. J Alloys Compd 695:771–778

  18. Kumbhar VS, Lokhande AC, Gaikwad NS, Lokhande CD (2015) Facile synthesis of Sm2S3 diffused nanoflakes and their pseudocapactive behavior. Ceram Int 41:5758–5764

    Article  CAS  Google Scholar 

  19. Hatzell KB, Beidaghi M, Campos JW et al (2013) A high performance pseudocapacitive suspension electrode for the electrochemical flow capacitor. Electrochim Acta 111:888–897

    Article  CAS  Google Scholar 

  20. Zhu Y, Ji X, Wu Z et al (2014) Spinel NiCo2O4 for use as a high-performance supercapacitor electrode material: understanding of its electrochemical properties. J Power Sources 267:888–900

    Article  CAS  Google Scholar 

  21. Sydulu Singu B, Srinivasan P, Pabba S (2012) Benzoyl peroxide oxidation route to Nano form Polyaniline salt containing dual dopants for Pseudocapacitor. J Electrochem Soc 159:A6

    Article  CAS  Google Scholar 

  22. Chodankar NR, Dubal DP, Gund GS, Lokhande CD (2015) Flexible all-solid-state MnO2 thin films based symmetric supercapacitors. Electrochim Acta 165:338–347

    Article  CAS  Google Scholar 

  23. Dubal DP, Holze R (2013) Self-assembly of stacked layers of Mn3O4 nanosheets using a scalable chemical strategy for enhanced, flexible, electrochemical energy storage. J Power Sources 238:274–282

    Article  CAS  Google Scholar 

  24. Dubal DPP, Kim WBB, Lokhande CDD (2012) Galvanostatically deposited Fe: MnO2 electrodes for supercapacitor application. J Phys Chem Solids 73:18–24

    Article  CAS  Google Scholar 

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Acknowledgements

This work was supported by the National Research Foundation of Korea Grant funded by the Korean Government (MEST) (NRF2016R1D1A1B03934229) and Hannam University research fund in 2017.

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Correspondence to Kuk Ro Yoon.

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Singu, B.S., Hong, S.E. & Yoon, K.R. Honeycomb-like manganese oxide nanospheres for redox supercapacitors. Ionics 24, 523–528 (2018). https://doi.org/10.1007/s11581-017-2218-3

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  • DOI: https://doi.org/10.1007/s11581-017-2218-3

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