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Erschienen in: Metallurgical and Materials Transactions B 4/2013

01.08.2013

Structure–Property Relationship of CaO-MgO-SiO2 Slag: Quantitative Analysis of Raman Spectra

verfasst von: Joo Hyun Park

Erschienen in: Metallurgical and Materials Transactions B | Ausgabe 4/2013

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Abstract

The quantitative structural information such as the relative abundance of silicate discrete anions (Q n units) and the concentration of three types of oxygens, viz. free-, bridging- and nonbridging oxygen can be obtained from micro-Raman spectra of the quenched CaO-SiO2-MgO glass samples. Various transport properties such as viscosity, density, and electrical conductivity can be expected as a simple linear function of “ln (Q3/Q2),” indicating that these physical properties are strongly dependent on a degree of polymerization of silicate melts. The methodology outlined in the current study can be extended to predict the physicochemical properties of silicate melts in ferrous and non-ferrous metallurgical processes.

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Literatur
1.
Zurück zum Zitat Y. Waseda and J.M. Toguri: The Structure and Properties of Oxide Melts, World Scientific Publishing, Singapore, 1998. Y. Waseda and J.M. Toguri: The Structure and Properties of Oxide Melts, World Scientific Publishing, Singapore, 1998.
2.
Zurück zum Zitat K.C. Mills: Slag Atlas, 2nd ed. Verlag Stahleisen GmbH, Düsseldorf, Germany, 1995. K.C. Mills: Slag Atlas, 2nd ed. Verlag Stahleisen GmbH, Düsseldorf, Germany, 1995.
3.
Zurück zum Zitat B. Cochain, D.R. Neuville, G.S. Henderson, C.A. McCammon, O. Pinet and P. Richet: J. Am. Ceram. Soc., 2012, vol. 95, pp. 962–71. B. Cochain, D.R. Neuville, G.S. Henderson, C.A. McCammon, O. Pinet and P. Richet: J. Am. Ceram. Soc., 2012, vol. 95, pp. 962–71.
4.
Zurück zum Zitat H. Kim, W.H. Kim, J.H. Park, and D.J. Min: Steel Res. Int., 2010, vol. 81, pp. 17–24.CrossRef H. Kim, W.H. Kim, J.H. Park, and D.J. Min: Steel Res. Int., 2010, vol. 81, pp. 17–24.CrossRef
5.
Zurück zum Zitat J.H. Park, H. Kim and D.J. Min: Metall. Mater. Trans. B, 2008, vol. 39B, pp. 150–3.CrossRef J.H. Park, H. Kim and D.J. Min: Metall. Mater. Trans. B, 2008, vol. 39B, pp. 150–3.CrossRef
6.
7.
Zurück zum Zitat X. Hou, R.J. Kirkpatrick, L.J. Struble and P.J.M. Monteiro: J. Am. Ceram. Soc., 2005, vol. 88, pp. 943–9.CrossRef X. Hou, R.J. Kirkpatrick, L.J. Struble and P.J.M. Monteiro: J. Am. Ceram. Soc., 2005, vol. 88, pp. 943–9.CrossRef
8.
Zurück zum Zitat S. Seetharaman, K. Mukai and Du Sichen: Steel Res. Int., 2005, vol. 76, pp. 267–78. S. Seetharaman, K. Mukai and Du Sichen: Steel Res. Int., 2005, vol. 76, pp. 267–78.
9.
Zurück zum Zitat R.E. Aune, M. Hayashi and S. Sridhar: Ironmaking & Steelmaking, 2005, vol. 32, pp. 141–50.CrossRef R.E. Aune, M. Hayashi and S. Sridhar: Ironmaking & Steelmaking, 2005, vol. 32, pp. 141–50.CrossRef
10.
Zurück zum Zitat J.H. Park and D.J. Min: J. Non-Cryst. Solids, 2004, vol. 337, pp. 150–6.CrossRef J.H. Park and D.J. Min: J. Non-Cryst. Solids, 2004, vol. 337, pp. 150–6.CrossRef
11.
Zurück zum Zitat J.H. Park, D.J. Min and H.S. Song: Metall. Mater. Trans. B, 2004, vol. 35B, pp. 269–75.CrossRef J.H. Park, D.J. Min and H.S. Song: Metall. Mater. Trans. B, 2004, vol. 35B, pp. 269–75.CrossRef
12.
Zurück zum Zitat J.H. Park, D.J. Min and H.S. Song: Metall. Mater. Trans. B, 2002, vol. 33B, pp. 723–9.CrossRef J.H. Park, D.J. Min and H.S. Song: Metall. Mater. Trans. B, 2002, vol. 33B, pp. 723–9.CrossRef
13.
Zurück zum Zitat J.H. Park, D.J. Min and H.S. Song: ISIJ Int., 2002, vol. 42, pp. 344–51.CrossRef J.H. Park, D.J. Min and H.S. Song: ISIJ Int., 2002, vol. 42, pp. 344–51.CrossRef
14.
Zurück zum Zitat J.H. Park and P.C.H. Rhee: J. Non-Cryst. Solids, 2001, vol. 282, pp. 7–14.CrossRef J.H. Park and P.C.H. Rhee: J. Non-Cryst. Solids, 2001, vol. 282, pp. 7–14.CrossRef
15.
Zurück zum Zitat S. Sridhar, K.C. Mills, O.D.C. Afrange, H.P. Lorz and R. Carli: Ironmaking & Steelmaking, 2000, vol. 27, pp. 238–42.CrossRef S. Sridhar, K.C. Mills, O.D.C. Afrange, H.P. Lorz and R. Carli: Ironmaking & Steelmaking, 2000, vol. 27, pp. 238–42.CrossRef
17.
Zurück zum Zitat G. Urbain and M. Boiret: Ironmaking & Steelmaking, 1990, vol. 17, pp. 255–60. G. Urbain and M. Boiret: Ironmaking & Steelmaking, 1990, vol. 17, pp. 255–60.
18.
Zurück zum Zitat J.O’M. Bockris, J.D. Mackenzie and J.A. Kitchener: Trans. Faraday Soc., 1955, vol. 51, pp. 1734–48. J.O’M. Bockris, J.D. Mackenzie and J.A. Kitchener: Trans. Faraday Soc., 1955, vol. 51, pp. 1734–48.
19.
Zurück zum Zitat J.O’M. Bockris and D.C. Lowe: Proc. Roy. Soc. London A, 1954, vol. 226A, pp. 423–35. J.O’M. Bockris and D.C. Lowe: Proc. Roy. Soc. London A, 1954, vol. 226A, pp. 423–35.
20.
Zurück zum Zitat J.O’M. Bockris, J.A. Kitchener, S. Ignatowicz and J.W. Tomlinson: Trans. Faraday Soc., 1952, vol. 48, pp. 75–91.CrossRef J.O’M. Bockris, J.A. Kitchener, S. Ignatowicz and J.W. Tomlinson: Trans. Faraday Soc., 1952, vol. 48, pp. 75–91.CrossRef
21.
Zurück zum Zitat J.O’M. Bockris, J.A. Kitchener and A.E. Davies: Trans. Faraday Soc., 1952, vol. 48, pp. 536–48.CrossRef J.O’M. Bockris, J.A. Kitchener and A.E. Davies: Trans. Faraday Soc., 1952, vol. 48, pp. 536–48.CrossRef
22.
Zurück zum Zitat B.O. Mysen and P. Richet: Silicate Glasses and Melts: Properties and Structure. Elsevier, Amsterdam, The Netherlands, 2005. B.O. Mysen and P. Richet: Silicate Glasses and Melts: Properties and Structure. Elsevier, Amsterdam, The Netherlands, 2005.
23.
Zurück zum Zitat J. Etchepare: Study by Raman Spectroscopy of Crystalline and Glassy Diopside, in Amorphous Materials, eds. R. W. Douglas and E. Ellis, Wiley-Interscience, New York, NY, 1972. J. Etchepare: Study by Raman Spectroscopy of Crystalline and Glassy Diopside, in Amorphous Materials, eds. R. W. Douglas and E. Ellis, Wiley-Interscience, New York, NY, 1972.
24.
Zurück zum Zitat T. Furukawa, K.E. Fox and W.B. White: J. Chem. Phys., 1981, vol. 75, pp. 3226–37.CrossRef T. Furukawa, K.E. Fox and W.B. White: J. Chem. Phys., 1981, vol. 75, pp. 3226–37.CrossRef
25.
Zurück zum Zitat S.A. Brawer and W.B. White: J. Non-Cryst. Solids, 1977, vol. 23, pp. 261–78.CrossRef S.A. Brawer and W.B. White: J. Non-Cryst. Solids, 1977, vol. 23, pp. 261–78.CrossRef
26.
Zurück zum Zitat S.A. Brawer and W.B. White: J. Chem. Phys., 1975, vol. 63, pp. 2421–32.CrossRef S.A. Brawer and W.B. White: J. Chem. Phys., 1975, vol. 63, pp. 2421–32.CrossRef
27.
Zurück zum Zitat P. McMillan: Am. Mineral., 1984, vol. 69, pp. 622–44. P. McMillan: Am. Mineral., 1984, vol. 69, pp. 622–44.
28.
Zurück zum Zitat D. Virgo, B.O. Mysen and I. Kushiro: Science, 1980, vol. 208, pp. 1371–3.CrossRef D. Virgo, B.O. Mysen and I. Kushiro: Science, 1980, vol. 208, pp. 1371–3.CrossRef
29.
Zurück zum Zitat B.O. Mysen: Am. Mineral., 1980, vol. 65, pp. 690–710. B.O. Mysen: Am. Mineral., 1980, vol. 65, pp. 690–710.
30.
Zurück zum Zitat M.B. Silva, C.M. Queiroz, S. Agathopoulos, R.N. Correia, M.H.V. Fernandes and J.M. Oliveira: J. Mol. Struc., 2011, vol. 986, pp. 16–21.CrossRef M.B. Silva, C.M. Queiroz, S. Agathopoulos, R.N. Correia, M.H.V. Fernandes and J.M. Oliveira: J. Mol. Struc., 2011, vol. 986, pp. 16–21.CrossRef
31.
32.
33.
Zurück zum Zitat M. Schramm, B.H.W.S. DeJong and V.F. Parziale: J. Am. Chem. Soc., 1984, vol. 106, pp. 4396–4402.CrossRef M. Schramm, B.H.W.S. DeJong and V.F. Parziale: J. Am. Chem. Soc., 1984, vol. 106, pp. 4396–4402.CrossRef
34.
Zurück zum Zitat J.F. Stebbins, J.B. Murdoch, E. Schneider, I.S.E. Carmichael and A. Pines: Nature, 1985, vol. 314, pp. 250–2.CrossRef J.F. Stebbins, J.B. Murdoch, E. Schneider, I.S.E. Carmichael and A. Pines: Nature, 1985, vol. 314, pp. 250–2.CrossRef
36.
37.
38.
39.
Zurück zum Zitat P. McMillan: Am. Mineral., 1984, vol. 69, pp. 645–59. P. McMillan: Am. Mineral., 1984, vol. 69, pp. 645–59.
40.
Zurück zum Zitat A. Chrissanthopoulos, N. Bouropoulos and S.N. Yannopoulos: Vib. Spectrosc., 2008, vol. 48, pp. 118–25.CrossRef A. Chrissanthopoulos, N. Bouropoulos and S.N. Yannopoulos: Vib. Spectrosc., 2008, vol. 48, pp. 118–25.CrossRef
41.
Zurück zum Zitat J. Schneider, V.R. Mastelaro, E.D. Zanotto, B.A. Shakhmatkin, N.M. Vedishcheva, A.C. Wright and H. Panepucci: J. Non-Cryst. Solids, 2003, vol. 325, pp. 164–78.CrossRef J. Schneider, V.R. Mastelaro, E.D. Zanotto, B.A. Shakhmatkin, N.M. Vedishcheva, A.C. Wright and H. Panepucci: J. Non-Cryst. Solids, 2003, vol. 325, pp. 164–78.CrossRef
42.
Zurück zum Zitat N.K. Nasikas, A.A. Chrissanthopoulos, N. Bouropoulos, S. Sen and G.N. Papatheodorou: Chem. Mater., 2011, vol. 23, pp. 3692–7.CrossRef N.K. Nasikas, A.A. Chrissanthopoulos, N. Bouropoulos, S. Sen and G.N. Papatheodorou: Chem. Mater., 2011, vol. 23, pp. 3692–7.CrossRef
43.
Zurück zum Zitat Y.Q. Wu, G.C. Jiang, J.L. You, H.Y. Hou, H. Chen and K.D. Xu: J. Chem. Phys., 2004, vol. 121, pp. 7883–95.CrossRef Y.Q. Wu, G.C. Jiang, J.L. You, H.Y. Hou, H. Chen and K.D. Xu: J. Chem. Phys., 2004, vol. 121, pp. 7883–95.CrossRef
44.
Zurück zum Zitat L.W. Finger, Y. Ohashi: Am. Mineral., 1976, vol. 61, pp. 303–10. L.W. Finger, Y. Ohashi: Am. Mineral., 1976, vol. 61, pp. 303–10.
45.
Zurück zum Zitat L. Levien and C.T. Prewitt: Am. Mineral., 1981, vol. 66, pp. 315–23. L. Levien and C.T. Prewitt: Am. Mineral., 1981, vol. 66, pp. 315–23.
46.
Zurück zum Zitat R.M. Thompson and R.T. Downs: Am. Mineral., 2008, vol. 93, pp. 177–86.CrossRef R.M. Thompson and R.T. Downs: Am. Mineral., 2008, vol. 93, pp. 177–86.CrossRef
47.
48.
Zurück zum Zitat H. Yang and C.T. Prewitt: Am. Mineral., 1999, vol. 84, pp. 929–32. H. Yang and C.T. Prewitt: Am. Mineral., 1999, vol. 84, pp. 929–32.
49.
50.
Zurück zum Zitat A.N. Grundy, H. Liu, I.H. Jung, S.A. Decterov and A.D. Pelton: Int. J. Mater. Res., 2008, vol. 99, pp. 1185–94.CrossRef A.N. Grundy, H. Liu, I.H. Jung, S.A. Decterov and A.D. Pelton: Int. J. Mater. Res., 2008, vol. 99, pp. 1185–94.CrossRef
51.
Zurück zum Zitat A.N. Grundy, I.H. Jung, A.D. Pelton and S.A. Decterov: Int. J. Mater. Res., 2008, vol. 99, pp. 1195–1209.CrossRef A.N. Grundy, I.H. Jung, A.D. Pelton and S.A. Decterov: Int. J. Mater. Res., 2008, vol. 99, pp. 1195–1209.CrossRef
52.
Zurück zum Zitat G. Urbain, Y. Bottinga and P. Richet: Geochim. Cosmochim. Acta, 1982, vol. 46, pp. 1061–72.CrossRef G. Urbain, Y. Bottinga and P. Richet: Geochim. Cosmochim. Acta, 1982, vol. 46, pp. 1061–72.CrossRef
53.
Zurück zum Zitat Y. Kawai and Y. Shiraishi: Handbook of Physico–chemical Properties at High Temperatures, The Iron and Steel Institute of Japan, Tokyo, 1988. Y. Kawai and Y. Shiraishi: Handbook of Physicochemical Properties at High Temperatures, The Iron and Steel Institute of Japan, Tokyo, 1988.
54.
Zurück zum Zitat T. Licko and V. Danek: Phys. Chem. Glasses, 1986, vol. 27, pp. 22–26. T. Licko and V. Danek: Phys. Chem. Glasses, 1986, vol. 27, pp. 22–26.
55.
Zurück zum Zitat A.M. Scarfe and D.J. Cronin: Am. Mineral., 1986, vol. 71, pp. 767–71. A.M. Scarfe and D.J. Cronin: Am. Mineral., 1986, vol. 71, pp. 767–71.
56.
Zurück zum Zitat J.O’M. Bockris, J.W. Tomlinson and J.L. White: Trans. Faraday Soc., 1956, vol. 53, pp. 299–310. J.O’M. Bockris, J.W. Tomlinson and J.L. White: Trans. Faraday Soc., 1956, vol. 53, pp. 299–310.
57.
Zurück zum Zitat J.W. Tomlinson, M.S.R. Heynes and J.O’M. Bockris: Trans. Faraday Soc., 1958, vol. 54, pp. 1822–33. J.W. Tomlinson, M.S.R. Heynes and J.O’M. Bockris: Trans. Faraday Soc., 1958, vol. 54, pp. 1822–33.
58.
Zurück zum Zitat R. Bruckner: Glastech. Ber., 1964, vol. 37, pp. 459–75. R. Bruckner: Glastech. Ber., 1964, vol. 37, pp. 459–75.
59.
Zurück zum Zitat Y. Bottinga and P. Richet: Geochim. Cosmochim. Acta, 1995, vol. 59, pp. 2725–31.CrossRef Y. Bottinga and P. Richet: Geochim. Cosmochim. Acta, 1995, vol. 59, pp. 2725–31.CrossRef
60.
Zurück zum Zitat P. Courtial, D.B. Dingwell: Am. Mineral., 1999, vol. 84, pp. 465–76. P. Courtial, D.B. Dingwell: Am. Mineral., 1999, vol. 84, pp. 465–76.
61.
Zurück zum Zitat Y. Linard, H. Nonnet and T. Advocat: J. Non-Cryst. Solids, 2008, vol. 354, pp. 4917–26.CrossRef Y. Linard, H. Nonnet and T. Advocat: J. Non-Cryst. Solids, 2008, vol. 354, pp. 4917–26.CrossRef
62.
Zurück zum Zitat L. Muhmood and S. Seetharaman: Metall. Mater. Trans. B, 2010, vol. 41B, pp. 833–40.CrossRef L. Muhmood and S. Seetharaman: Metall. Mater. Trans. B, 2010, vol. 41B, pp. 833–40.CrossRef
63.
Zurück zum Zitat L. Zhang and S. Jahanshahi: Metall. Mater. Trans. B, 1998, vol. 29B, pp. 177–86.CrossRef L. Zhang and S. Jahanshahi: Metall. Mater. Trans. B, 1998, vol. 29B, pp. 177–86.CrossRef
Metadaten
Titel
Structure–Property Relationship of CaO-MgO-SiO2 Slag: Quantitative Analysis of Raman Spectra
verfasst von
Joo Hyun Park
Publikationsdatum
01.08.2013
Verlag
Springer US
Erschienen in
Metallurgical and Materials Transactions B / Ausgabe 4/2013
Print ISSN: 1073-5615
Elektronische ISSN: 1543-1916
DOI
https://doi.org/10.1007/s11663-013-9825-9

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