Skip to main content
Log in

Formation of NiAl Intermetallic Compound by Cold Spraying of Ball-Milled Ni/Al Alloy Powder Through Postannealing Treatment

  • Peer Reviewed
  • Published:
Journal of Thermal Spray Technology Aims and scope Submit manuscript

Abstract

Ni/Al alloy powders were synthesized by ball milling of nickel-aluminum powder mixture with a Ni/Al atomic ratio of 1:1. Ni/Al alloy coating was deposited by cold spraying using N2 as accelerating gas. NiAl intermetallic compound was evolved in situ through postspray annealing treatment of cold-sprayed Ni/Al alloy coating. The effect of annealing temperature on the phase transformation behavior from Ni/Al mechanical alloy to intermetallics was investigated. The microstructure of the mechanically alloying Ni/Al powder and NiAl coatings was characterized by scanning electron microscopy and x-ray diffraction analysis. The results show that a dense Ni/Al alloy coating can be successfully deposited by cold spraying using the mechanically alloyed powder as feedstocks. The as-sprayed alloy coating exhibited a laminated microstructure retained from the mechanically alloying powder. The annealing of the subsequent Ni/Al alloy coating at a temperature higher than 850 °C leads to complete transformation from Ni/Al alloy to NiAl intermetallic compound.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. V.K. Sikka, J.T. Mavity, K. Anderson, Processing of Nickel Aluminides and Their Industrial Applications, Mater. Sci. Eng. A, 1992, 153(1-2), p 712-721

    Article  Google Scholar 

  2. C.T. Liu, J.O. Stiegler, Ductile Ordered Intermetallic Alloys, Science, 1984, 226, p 636-642

    Article  PubMed  ADS  CAS  Google Scholar 

  3. Z. Yu, D.D. Hass, H.N.G. Wadley, NiAl Bond Coats Made by a Directed Vapor Deposition Approach, Mater. Sci. Eng. A, 2005, 394(1-2), p 43-52

    Article  Google Scholar 

  4. J. Angenete, K. Stiller, A Comparative Study of Two Inward Grown Pt Modified Al Diffusion Coatings on a Single Crystal Ni Base Superalloy, Mater. Sci. Eng. A, 2001, 316(1-2), p 182-194

    Article  Google Scholar 

  5. M. Chigasaki, K. Otaka, A. Okayama, K. Onisawa, and K. Soeno, Method of Producing Nickel Base Alloy Structure with NiAl Coating, U.S. Patent 4,486,245

  6. B.M. Warnes, D.C. Punola, Clean Diffusion Coatings by Chemical Vapor Deposition, Surf. Coat. Technol., 1997, 94-95, p 1-6

    Article  CAS  Google Scholar 

  7. Y. Zhang, W.Y. Lee, J.A. Haynes, I.G. Wright, K.M. Cooley, P.K. Liaw, Synthesis and Cyclic Oxidation Behavior of a (Ni, Pt) Al Coating on a Desulfurized Ni-Base Superalloy, Metall. Mater. Trans. A, 1999, 30(10), p 2679-2687

    Article  Google Scholar 

  8. W.Y. Lee, Y. Zhang, I.G. Wright, B.A. Pint, P.K. Liaw, Effects of Sulfur Impurity on the Scale Adhesion Behavior of a Desulfurized Ni-Based Superalloy Aluminized by Chemical Vapor Deposition, Metall. Trans. A, 1998, 29(3), p 833-841

    Article  Google Scholar 

  9. N.P. Padture, M. Gell, E.H. Jordan, Thermal Barrier Coatings for Gas-Turbine Engine Applications. Science, 2002, 296, p 280-284

    Article  PubMed  ADS  CAS  Google Scholar 

  10. W.Y. Hua, M.H. Li, M. Fukumoto, Preparation and Properties of HVOF NiAl Nanostructured Coatings, Mater. Sci. Eng. A, 2008, 478(1-2), p 1-8

    Article  Google Scholar 

  11. J.A. Hearley, J.A. Little, A.J. Sturgeon, The Effect of Spray Parameters on the Properties of High Velocity Oxy-Fuel NiAl Intermetallic Coatings, Surf. Coat. Technol., 2000, 123(2-3), p 210-218

    Article  CAS  Google Scholar 

  12. Y. Wang, W. Chen, L. Wang, Micro-Indentation and Erosion Properties of Thermal Sprayed NiAl Intermetallic-Based Alloy Coatings, Wear, 2003, 254(3-4), p 350-355

    Article  CAS  Google Scholar 

  13. C.J. Li, W.Y. Li, Deposition Characteristics of Titanium Coatings in Cold Spraying, Surf. Coat. Technol., 2003, 167(2-3), p 278-283

    Article  ADS  CAS  Google Scholar 

  14. C.J. Li, W.Y. Li, Y.Y. Wang, Formation of Metastable Phases in Cold-Sprayed Soft Metallic Deposit, Surf. Coat. Technol., 2005, 198(1-3), p 469-473

    Article  CAS  Google Scholar 

  15. C.J. Li, W.Y. Li, Y.Y. Wang, G.J. Yang, H. Fukanuma, A Theoretical Model for Prediction of Deposition Efficiency in Cold Spraying, Thin Solid Films, 2005, 489(1-2), p 79-85

    Article  ADS  CAS  Google Scholar 

  16. C.J. Li, W.Y. Li, W.H. Ma, and H. Fukanuma, Characterization of Microstructure of Nanostructured Fe-Si Coating Deposited by Cold Spraying, Thermal Spray Solutions: Advances in Technology and Application, Conference Proceedings, May 10-12 2004 (Osaka, Japan), DVS, Düsseldorf, 2004, p 371-377

  17. H.T. Wang, C.J. Li, G.J. Yang, C.-X. Li, Q. Zhang, W.-Y. Li, Microstructural Characterization of Cold-Sprayed Nanostructured FeAl Intermetallic Compound Coating and Its Ball-Milled Feedstock Powders, J. Therm. Spray Technol., 2007, 16(5-6), p 669-676

    Article  ADS  CAS  Google Scholar 

  18. Q. Zhang, C.J. Li, C.X. Li, G.J. Yang, S.C. Lui, Study of Oxidation Behavior of Nanostructured NiCrAlY Bond Coatings Deposited by Cold Spraying, Surf. Coat. Technol., 2008, 202(14), p 3378-3384

    Article  CAS  Google Scholar 

  19. H.Y Lee, S.H. Jung, S.Y Lee, K.H. Ko, Alloying of Cold-Sprayed Al-Ni Composite Coatings by Post-Annealing, Appl. Surf. Sci., 2007, 253(7), p 3496-3502

    Article  ADS  CAS  Google Scholar 

  20. H.C. Zhu, R. Abbaschian, Reactive Processing of Nickel-Aluminide Intermetallic Compounds, J. Mater. Sci., 2003, 38(18), p 3861-3870

    Article  CAS  Google Scholar 

  21. L. Farber, L. Klinger, I. Gotman, Modeling of Reactive Synthesis in Consolidated Blends of Fine Ni and Al Powders, Mater. Sci. Eng. A, 1998, 254(1-2), p 155-165

    Article  Google Scholar 

  22. L. Farber, Irena E.Y. Gutmanas, and A. Lawley, Solid State Synthesis of NiAl-Nb Composites from Fine Elemental Powders, Mater. Sci. Eng. A, 1998, 244(1), p 97-102

  23. A. Battezzati, P. Pappalepore, F. Durbiano, I. Gallino, Solid State Reactions in Al/Ni Alternate Foils Induced by Cold Rolling and Annealing, Acta Mater., 1999, 47(6), p 1901-1914

    Article  CAS  Google Scholar 

  24. A. Biswas, S.K. Roy, Comparrison between the Microstructural Evolutions of Two Modes of SHS of NiAl: Key to a Common Reaction Mechanism, Acta Mater., 2004, 52(2), p 257-270

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The present work is supported by National Basic Research Program of China (Grant No. 2007CB707702), National Science Fund for Distinguished Young Scholars (Grant No. 50725101).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Chang-Jiu Li.

Additional information

This article is an invited paper selected from presentations at the 2008 International Thermal Spray Conference and has been expanded from the original presentation. It is simultaneously published in Thermal Spray Crossing Borders, Proceedings of the 2008 International Thermal Spray Conference, Maastricht, The Netherlands, June 2-4, 2008, Basil R. Marple, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and Ghislain Montavon, Ed., ASM International, Materials Park, OH, 2008.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zhang, Q., Li, CJ., Wang, XR. et al. Formation of NiAl Intermetallic Compound by Cold Spraying of Ball-Milled Ni/Al Alloy Powder Through Postannealing Treatment. J Therm Spray Tech 17, 715–720 (2008). https://doi.org/10.1007/s11666-008-9225-x

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11666-008-9225-x

Keywords

Navigation