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Kinetics of transformation during supersaturation and aging of the Al-4.7mass%Cu alloy: Grain size, dilatometric, and differential thermal analysis studies

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Abstract

The processes taking place during supersaturation of the Al-4.7mass%Cu alloy have been studied by the methods of quantitative metallography and dilatometry. The grain growth activation energy was about 95 kJ/mol, and the exponent of time, n, was close to 0.4. Dissolution of precipitates caused two-stage shrinkage of the sample, which had activation energies of 90 kJ/mol (first stage, n=0.8) and 63 kJ/mol (second stage, n=0.4). The kinetics of the phase transformation during aging of the Al-4.7mass%Cu alloy has been studied by the dilatometry and differential thermal analysis The activation energy of the precipitation processes within the range of 50–320 °C varied between 50 and 100 kJ/mol and confirmed the results obtained previously. For the precipitation processes within the range of 320–462 °C, the activation energy varied from 226 to 300 kJ/mol. The results obtained were compared with literature data with good agreement.

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This article is a revised version of the paper printed in the Proceedings of the First International Conference on Diffusion in Solids and Liquids—DSL-2005, Aveiro, Portugal, July 6–8, 2005, Andreas Öchsner, José Grácio and Frédéric Barlat, eds., University of Aveiro, 2005.

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Wierszyłłowski, I., Stankowiak, A., Wieczorek, S. et al. Kinetics of transformation during supersaturation and aging of the Al-4.7mass%Cu alloy: Grain size, dilatometric, and differential thermal analysis studies. J Phs Eqil and Diff 26, 555–560 (2005). https://doi.org/10.1007/s11669-005-0050-3

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  • DOI: https://doi.org/10.1007/s11669-005-0050-3

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