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Thermodynamic Description of \({\hbox{SrO-Al}_{2}\hbox{O}_{3}}\) System and Comparison with Similar Systems

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Abstract

The Al2O3-SrO binary system has been studied using the CALPHAD technique in this paper. The modeling of Al2O3 in the liquid phase is modified from the traditional formula with the liquid phase represented by the ionic two-sublattice model as (Al3+, Sr2+) P (\({\hbox{AlO}_{2}^{1-}}\), O2−) Q . Based on the measured phase equilibrium data and experimental thermodynamic properties, a set of thermodynamic functions has been optimized using an interactive computer-assisted analysis. The calculated results are compared with experimental data. A comparison between this system and similar systems is also given.

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References

  1. Ohta M., Maruyama M., Hayakawa T., Nishijo T. (2000) Role of Dopant on Long-lasting Phosphor of Strontium Aluminate. J. Ceram. Soc. Jpn 108(3):284-289

    Google Scholar 

  2. Mao H., Selleby M., Sundman B. (2004) A Reevaluation of the Liquid Phases in the CaO-Al2O3 and MgO-Al2O3 Systems. Calphad 28(3):307-312

    Article  Google Scholar 

  3. Ye X., Zhuang W., Deng C., Yuan W., Qiao Z. (2006) Thermodynamic Investigation on the Al2O3-BaO Binary System. Calphad 30 (3):349-353

    Google Scholar 

  4. Lagerqvist L., Wallmark S., Westgren A. (1937) X-ray study of the systems CaO-Al2O3 and MgO-Al2O3. Z. Anorg. Allgem. Chem. 234:1-16

    Article  Google Scholar 

  5. Jander W., Kreiger A. (1937) Formation of Strontium Aluminates from the Oxides in the Solid State-Reaction in the Solid State at High Temperature. Z. Anorg. Allgem. Chem. 235:89-96

    Article  Google Scholar 

  6. Adelskold V. (1938) X-ray Studies on Magneto-plumbite, PbO · 6Fe2O3, and Other Substances Resembling ‘Beta-Alumina’, Na2O · 11Al2O3. Alk. Kemi. Mineral Geol. 12A(29):1-9

    Google Scholar 

  7. Toropov N.A. (1939) Crystalloptical Analysis of Strontium Aluminates. Compt. Rend. Acad. Sci. U.R.S.S. 23:74-75

    Google Scholar 

  8. Toropov N.A., Stukalova M.M. (1940) Replacement of Sodium in Crystals of “\({\upbeta}\)-alumina” With Calcium, Strontium and Barium. Compt. Rend. Acad. Sci. U.R.S.S. 27:974-977

    Google Scholar 

  9. P.S. Dear, X-ray Diffraction Data for Silicates, Aluminates and Aluminosilicates of Strontium, Bull. Virginia Ploytechn. Inst., 50(6), Eng. Expt. Stat., 1957, 117, p 1-15

  10. F. Massazza, The System SrO-Al2O3. Chim. Ind. (Milan), 1959, 41, p 108-115 (in Italian); E. M. Levin, C. R. Robbins, and H. F. McMurdie, Ed., Phase Diagrams for Ceramists, American Ceramic Society, Colombus, OH, 1964, Fig. 294-295

  11. Massazza F., Cannas M. (1959) Research on the System CaO-Al2O3-SrO. Ann. Chimica (Rome) 49:1342-1351, in Italian

    Google Scholar 

  12. Brisi C., Abbattista F. (1960) Searches on the Heats of Formation of the Strontium Aluminated One. Ann. Chimica 50:165-169, in Italian

    Google Scholar 

  13. Appendino P. (1972) Balances in a solid equilibria in the system SrO-BaO-Al2O3. Rev. Int. Hautes Temper. Refract. 9:297-302, in French

    Google Scholar 

  14. F. Ganits, T. Yu. Chemekova, and Yu. P. Udalov, The System SrO-Al2O3, Zh. Neorg. Khim., 24(2), p 471-475 (in Russian); R.S. Roth, T. Negas, and L.P. Cook, Ed., Phase Diagrams for Ceramists, American Ceramic Society, Colombus, OH, 1987, Fig. 6427

  15. Song Y.K., Choi S.K., Moon H.S., Kim T.W., Mho S.I., Park H.L. (1997) Phase Studies of SrO-Al2O3 by Emission Signatures of Eu2+ and Eu3+. Mater. Res. Bull. 32(3):337-341

    Article  Google Scholar 

  16. T. N. Nadezhina, E. A. Pobedimskaya, and N. V. Belov, Coordination Polyhedra of Strontium in the Structures Sodium strontium germanate Na4SrGe3O3[GeO4]3, Strontium germanate Sr3[Ge3O9], Strontium aluminate Sr4Al4O2[Al10O23] and bis(hydroxystrontium) tetrahydroxycuprate(II) Sr2(OH)2[Cu(OH)4]. Kristallografiya, 1980, 25, p 938-943 (Sov. Phys. Crystallogr., 1980, 25, p 537-540)

    Google Scholar 

  17. Wang M., Wang D., Lu G. (1998) Research on Fluorescence Spectra and Structure of Single-phase 4SrO · 7Al2O3:Eu2+ Phosphor Prepared by Solid-state Reaction Method. Mater. Sci. Engin. B 57:18-23

    Article  Google Scholar 

  18. Lin Y., Tang Z., Zhang Z. (2001) Preparation of Long-afterglow Sr4Al14O25-based Luminescent Material and Its Optical Properties. Mater. Lett. 51:14-18

    Article  Google Scholar 

  19. M. Capron, Synthesis and Characterization of Aluminates and Aluminosilicates of the Ambient Temperature to the Liquid at High Temperatures. Thesis, University of Orleans, 2001 (in French)

  20. Andre D., Capron M. (2003) Crystallisation of Spray-dried Amorphous Precursors in the SrO-Al2O3 System: A DSC Study. J. Euro. Ceram. Soc. 23:2075-2081

    Article  Google Scholar 

  21. Yamaguchi O., Narai A., Shimizu K. (1986) New Compound in the System SrO-Al2O3. J. Am. Ceram. Soc. 69:C36-C37

    Google Scholar 

  22. Kahlenberg V. (2002) Synthesis and Crystal Structure of Sr10Al6O19: A Derivative of the Perovskite Structure Type in the System SrO-Al2O3. Mat. Res. Bull. 37:715-726

    Article  Google Scholar 

  23. Knacke O., Kubaschewski O., Hesselmann K. (1991) Thermochemical Properties of Inorganic Substances, 2nd ed. Springer-Verlag, Berlin, Heidelberg, New York, London

    Google Scholar 

  24. X. Zhang, Solid-State Combinatorial Chemistry Method and Its Application in Inorganic Luminescent Materials, Dissertation for post-doctor, Peking University, 2005 (in Chinese)

  25. Risold D., Hallstedt B., Gauckler L.J. (1996) The Strontium-Oxygen System. Calphad 20(3):353-361

    Article  Google Scholar 

  26. The SGTE Substance Database, Version 1994, SGTE (Scientific Group Thermodata Europe), Grenoble, France, 1994

  27. Capron M., Florian P., Fayon F., Trumeau D., Hennet L., Gaihlanou M., Thiaudiere D., Landron C., Douy A., Massiot D. (2001) Local Structure and Dynamics of High Temperature SrO-Al2O3 Liquids Studied by 27Al NMR and Sr K-edge XAS Spectroscopy. J. Non-crystal. Solids 293-295:496-501

    Article  Google Scholar 

  28. Hillert M., Jansson B., Sundman B., Agren J. (1985) A Two-sublattice Model for Molten Solutions with Different Tendency for Ionization. Metall. Trans. A 16A:261-266

    Google Scholar 

  29. Hallstedt B. (1992) Thermodynamic Assessment of the System MgO-Al2O3. J. Am. Ceram. Soc. 75(6):1497-1507

    Article  Google Scholar 

  30. Hallstedt B. (1990) Assessment of the CaO-Al2O3 System. J. Am. Ceram. Soc. 73(1):15-23

    Article  Google Scholar 

  31. Gutierrez G., Belonoshko A.B., Ahuja R., Johansson B. (2000) Structural Properties of Liquid Al2 O3: A Molecular Dynamics Study. Phys. Rev. E 61:2723-2729

    Article  ADS  Google Scholar 

  32. G. Gruener, P. Odier, D. De Sousa Meneses, P. Florian, and P. Richet, Bulk and Local Dynamics in Glass-Forming Liquids: A Viscosity, Electrical Conductivity, and NMR study of Aluminosilicate melts, Phys. Rev. B, 2001, 64(2), Art.024206

  33. Mao H., Hillert M., Selleby M., Sundman B. (2006) Thermodynamic Assessment of the CaO-Al2O3-SiO2 system. J. Am. Ceram. Soc. 89(1):298-308

    Article  Google Scholar 

  34. Mao H., Fabrichnaya O., Selleby M., Sundman B. (2005) Thermodynamic Assessment of MgO-Al2O3-SiO2 System. J. Mater. Res. 20(4):975-986

    Article  Google Scholar 

  35. Redlich O., Kister A. (1948) Algebraic Representation of Thermodynamic Properties and the Classification of Solutions. Ind. Eng. Chem. 40:345-348

    Article  Google Scholar 

  36. Andersson J.-O., Helander T., Hoglund L., Shi P., Sundman B. (2002) Thermo-Calc & DICTRA Computational Tools for Materials Science. Calphad 26(2):273-312

    Article  Google Scholar 

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Acknowledgments

The authors thank the National Natural Science Foundation of China for financial support No. 50204002, and Dr. Bo Sundman for the Thermo-Calc program package.

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Correspondence to Weidong Zhuang.

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Ye, X., Zhuang, W., Wang, J. et al. Thermodynamic Description of \({\hbox{SrO-Al}_{2}\hbox{O}_{3}}\) System and Comparison with Similar Systems. J Phs Eqil and Diff 28, 362–368 (2007). https://doi.org/10.1007/s11669-007-9086-x

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  • DOI: https://doi.org/10.1007/s11669-007-9086-x

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