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Diffusion Mobilities in fcc Cu-Au and fcc Cu-Pt Alloys

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Abstract

Abundant diffusion data in binary fcc Cu-Au and fcc Cu-Pt alloys have been assessed to obtain the atomic diffusion mobilities of fcc Cu-Au and fcc Cu-Pt alloys by the CALPHAD method. The obtained mobilities are expressed as functions of compositions and temperatures. Good agreements are obtained from comprehensive comparisons between the calculated and experimentally measured self-diffusion coefficients, impurity diffusion coefficients, tracer diffusion coefficients, interdiffusion coefficients, and concentration curves. Accordingly, the developed mobility parameters, in conjunction with the CALPHAD-type thermodynamic descriptions, can be used to simulate diffusion behaviors at high temperatures. It is believed that the results of this work contribute to the design of a general Cu mobility database.

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Authors and Affiliations

  1. Western Transportation Institute, Montana State University, Bozeman, MT, 59715, USA

    Yajun Liu

  2. State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan, 410083, People’s Republic of China

    Lijun Zhang

  3. American Water Chemicals Inc, Tampa, FL, 33619, USA

    Di Yu

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Liu, Y., Zhang, L. & Yu, D. Diffusion Mobilities in fcc Cu-Au and fcc Cu-Pt Alloys. J. Phase Equilib. Diffus. 30, 136–145 (2009). https://doi.org/10.1007/s11669-009-9469-2

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