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Effect of an antioxidant on the life cycle of wood flour/polypropylene composites

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Abstract

This study assessed the life cycle of biocomposites with antioxidants by repeated processing. The effects of antioxidants on the life cycle of wood flour/polypropylene (PP) composites were determined by analyzing their mechanical and thermal properties. The composites were repeatedly processed for seven times with pelletizing and extruding. An antioxidant, pentaerythritoltetrakys 3-(3,5-ditert-butyl-4-hydroxyphenyl) propionate, was used. The mechanical strength of the biocomposites decreased after reprocessing. Fourier transformed infrared analysis showed that thermo-oxidative aging occurred during reprocessing. The thermal performance of the resulting composites decreased because of reprocessing. Wood flour/PP has a long lifetime and antioxidants can slow the thermo-oxidative and mechanical degradation during reprocessing.

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References

  • Ashori A, Nourbakhsh A (2010) Reinforced polypropylene composites: effects of chemical compositions and particle size. Bioresour Technol 101(7):2515–2519

    Article  CAS  PubMed  Google Scholar 

  • Balasuriya PW, Ye L, Mai YW, Wu J (2010) Mechanical properties of wood flake and ash; polyethylene composites. II. Interface modification. J Appl Polym Sci 83(12):2505–2521

    Article  Google Scholar 

  • Beg MD, Pickering KL (2008) Reprocessing of wood fibre reinforced polypropylene composites. Part I: effects on physical and mechanical properties. Compos Part A Appl Sci Manuf 39(7):1091–1100

    Article  Google Scholar 

  • Bourmaud A, Baley C (2007) Investigations on the recycling of hemp and sisal fibre reinforced polypropylene composites. Polym Degrad Stab 92(6):1034–1045

    Article  CAS  Google Scholar 

  • Burgstaller C (2007) Processing of thermal sensitive materials—a case study for wood plastic composites. Monatshefte für Chemie Chem Mon 138(4):343–346

    Article  CAS  Google Scholar 

  • Cadena C, Delicia A (2014) Effects of solar UV radiation on materials used in agricultural industry in Salta, Argentina: study and characterization. J Mater Sci Chem Eng 02(4):1–14

    CAS  Google Scholar 

  • CPHC (2017) WPCisapromisingbuildingmaterial. http://www.cphcweb.com/hbjc/show.php?itemid=317

  • Fonseca-Valero C, Ochoa-Mendoza A, Arranz-Andrés J, González-Sánchez C (2015) Mechanical recycling and composition effects on the properties and structure of hardwood cellulose-reinforced high density polyethylene eco-composites. Compos Part A Appl Sci Manuf 69(69):94–104

    Article  CAS  Google Scholar 

  • Guerrica-Echevarría G, Eguiazábal JI, Nazábal J (1996) Effects of reprocessing conditions on the properties of unfilled and talc-filled polypropylene. Polym Degrad Stab 53(1):1–8

    Article  Google Scholar 

  • Iizuka T, Ohtake Y, Tanaka K (2017) A synergistic effect of light and heat on degradation for polypropylene. Zairyo/J Soc Mater Sci Jpn 66(3):238–243

    Article  CAS  Google Scholar 

  • Jansson A, Kenneth M, Thomas G (2003) Degradation of post-consumer polypropylene materials exposed to simulated recycling—mechanical properties. Polym Degrad Stab 82(1):37–46

    Article  CAS  Google Scholar 

  • Khonsari A, Taghiyari HR, Karimi A, Tajvidi M (2015) Study on the effects of wood flour geometry on physical and mechanical properties of wood-plastic composites. Maderas Ciencia Y Tecnologia 51(4):289–296

    Google Scholar 

  • Kurniawan D, Kim BS, Lee HY, Lim J (2013) Effects of repetitive processing, wood content, and coupling agent on the mechanical, thermal, and water absorption properties of wood/polypropylene green composites. J Adhes Sci Technol 27(12):1301–1312

    Article  CAS  Google Scholar 

  • Lee CH, Hung KC, Chen YL, Wu TL, Chien YC, Wu JH (2012) Effects of polymeric matrix on accelerated UV weathering properties of wood-plastic composites. Holzforschung 66(8):981–987

    Article  CAS  Google Scholar 

  • Mantia F, La P, Gardette JL (2002) Improvement of the mechanical properties of photo-oxidized films after recycling. Polym Degrad Stab 75(1):1–7

    Article  Google Scholar 

  • Markarian J (2002) Additive developments aid growth in wood-plastic composites. Plast Addit and Compd 4(11):18–21

    Article  Google Scholar 

  • Mathew A, Oksman K, Sain M (2006) The effect of morphology and chemical characteristics of cellulose reinforcements on the crystallinity of polylactic acid. J Appl Polym Sci 101(1):300–310

    Article  CAS  Google Scholar 

  • Migneault S, Koubaa A, Erchiqui F, Chaala A, Englund K, Krause C, Wolcott M (2008) Effect of fiber length on processing and properties of extruded wood-fiber/HDPE composites. J Appl Polym Sci 110(2):1085–1092

    Article  CAS  Google Scholar 

  • Minoshima W, White JL, Spruiell JE (1980) Experimental investigation of the influence of molecular weight distribution on the rheological properties of polypropylene melts. Polym Eng Sci 20(17):1166–1176

    Article  CAS  Google Scholar 

  • Monasse B, Haudin JM (1985) Growth transition and morphology change in polypropylene. Colloid Polym Sci 263(10):822–831

    Article  CAS  Google Scholar 

  • Najafi SK, Mostafazadeh-Marznaki M, Chaharmahali M, Tajvidi M (2009) Effect of thermomechanical degradation of polypropylene on mechanical properties of wood-polypropylene composites. J Compos Mater 43(22):2543–2554

    Article  CAS  Google Scholar 

  • Nourbakhsh A, Ashori A, Tabari HZ, Rezaei F (2010) Mechanical and thermo-chemical properties of wood-flour/polypropylene blends. Polym Bull 65(7):691–700

    Article  CAS  Google Scholar 

  • Peng Y, Liu R, Cao JZ, Guo X (2014) Effects of vitamin E combined with antioxidants on wood flour/polypropylene composites during accelerated weathering. Holzforschung 69(1):113–120

    Article  Google Scholar 

  • Sailaja RR, Deepthi MV (2011) Mechanical and thermal properties of compatibilized composites of LDPE and esterified unbleached wood pulp. Polym Compos 32(2):199–209

    Article  CAS  Google Scholar 

  • Sarabi TM, Behravesh AH, Shahi P, Soury E (2012) Reprocessing of extruded wood-plastic composites; mechanical properties. J Biobased Mater Bioenergy 6(2):221–229

    Article  CAS  Google Scholar 

  • Sarabi TM, Behravesh A, Shahi A, Daryabari Y (2014) Effect of polymeric matrix melt flow index in reprocessing extruded wood-plastic composites. J Thermoplast Compos Mater 27(7):881–894

    Article  CAS  Google Scholar 

  • Shahi P, Amir H, Behravesh (2011) Processing considerations in the recycling of wood-plastic composites. Regional Meeting of the Polymer Processing Society

  • Srebrenkoska V, Bogoevagaceva G, Avella M, Errico M, Gentile G (2008) Recycling of polypropylene 1 based eco-composites. Polym Int 57(11):1252–1257

    Article  CAS  Google Scholar 

  • Stark NM, Berger MJ (1997) Effect of particle size on properties of wood-flour reinforced polypropylene composites. In: Proceedings of the fourth international conference on wood fibre–plastic composites, pp 12–14

  • Stark N, Rowlands R (2003) Effects of wood fiber characteristics on mechanical properties of wood/polypropylene composites. Wood Fiber Sci 35(2):167–174

    CAS  Google Scholar 

  • Walz K, Jacobson R, Sanadi AR (1994) Effect of reprocessing/recycling on the mechanical properties of kenaf-PP composites. Internal Report, University of Wisconsin-Madison and Forest Product Laboratory

  • Zhang ZM, Du H, Wang W, Wang Q (2010) Property changes of wood-fiber/HDPE composites colored by iron oxide pigments after accelerated UV weathering. J For Res 21(1):59–62

    Article  Google Scholar 

  • Zhang J, Wang H, Ou R, Wang Q (2018) The properties of flax fiber reinforced wood flour/high density polyethylene composites. J For Res 29(2):533–540

    Article  CAS  Google Scholar 

  • Zhou X, Chen L (2015) Anti-aging agents improving natural weathering properties of bamboo powder/polypropylene foamed composites. Trans Chin Soc Agric Eng 31(12):301–307

    CAS  Google Scholar 

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Authors and Affiliations

  1. Key Laboratory of Bio-Based Material Science and Technology (Ministry of Education), Northeast Forestry University, Harbin, 150040, People’s Republic of China

    Haigang Wang, Jingfa Zhang, Haitao Fu & Weihong Wang

  2. College of Materials and Energy, South China Agricultural University, Guangzhou, 510642, People’s Republic of China

    Qingwen Wang

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  1. Haigang Wang
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  2. Jingfa Zhang
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  3. Haitao Fu
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  4. Weihong Wang
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  5. Qingwen Wang
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Correspondence to Weihong Wang or Qingwen Wang.

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Project funding: This work was supported by the Fundamental Research Funds for the Central Universities (Grant No. 2572018BB07) and the National Natural Science Foundation of China (Grant No. 31670570).

The online version is available at http://www.springerlink.com

Corresponding editor: Yu Lei.

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Wang, H., Zhang, J., Fu, H. et al. Effect of an antioxidant on the life cycle of wood flour/polypropylene composites. J. For. Res. 31, 1435–1443 (2020). https://doi.org/10.1007/s11676-019-00898-w

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  • DOI: https://doi.org/10.1007/s11676-019-00898-w

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