Skip to main content
Log in

Morphological and mechanical characterization of a PMMA/CdS nanocomposite

  • Research Article
  • Published:
Frontiers of Chemical Science and Engineering Aims and scope Submit manuscript

Abstract

Thick film of poly(methyl methacrylate) (PMMA)/CdS nanocomposite have been synthesized by the solution casting process. The nanostructure of the CdS particles has been ascertained through the small angle X-ray scattering (SAXS) technique. The surface morphological characterization of the PMMA/CdS nanocomposite has been done through scanning electron microscopy (SEM) analysis. The variation of mechanical loss factor (Tanδ) with temperature and tensile properties of prepared samples have been studied using Dynamic Mechanical Analyzer (DMA). This study reveals that the glass transition temperature (T g), Young’s modulus, and fracture energy of the PMMA/CdS nanocomposite are greatly influenced by the existence of interfacial energetic interaction between dispersed CdS nanoparticles and the matrix of PMMA.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Wang L, Liu Y S, Jiang X, Qin D H, Cao Y. Enhancement of photovoltaic characteristics using a suitable solvent in hybrid polymer/multiarmed CdS nanorods solar cells. Journal of Physical Chemistry C, 2007, 111(26): 9538–9542

    Article  CAS  Google Scholar 

  2. Kundu S, Liang H. Photochemical synthesis of electrically conductive CdS nanowires on DNA scaffolds. Advanced Materials, 2008, 20(4): 826–831

    Article  CAS  Google Scholar 

  3. Hsu Y J, Lu S Y, Lin Y F. Spontaneous reduction of metal ions initiated by ethylenediamine-capped CdS nanowires: a sensing mechanism revealed. Chemistry of Materials, 2008, 20(9): 2854–2856

    Article  CAS  Google Scholar 

  4. Lee J C, Lee W J, Han S H, Kim T G, Sung Y M. Synthesis of hybrid solar cells using CdS nanowire array grown on conductive glass substrates. Electrochemistry Communications, 2009, 11(1): 231–234

    Article  CAS  Google Scholar 

  5. Rong M Z, Zhang M Q, Liang H C. Zeng H M. Surface modification and particles size distribution control in nano-CdS/polystyrene composite film. Chemical Physics, 2003, 286(2–3): 267–276

    Article  CAS  Google Scholar 

  6. Zeng J H, Yang J, Zhu Y, Liu Y F, Qian Y T, Zheng H G. Nanocomposite of CdS particles in polymer rods fabricated by a novel hydrothermal polymerization and simultaneous sulfidation technique. Chemical Communications, 2001, 15: 1332–1333

    Article  Google Scholar 

  7. Leventis H C, King S P, Sudlow A, Hill M S, Molloy K C, Haque S A. Nanostructured hybrid polymer-inorganic solar cell active layers formed by controllable in situ growth of semiconducting sulfide networks. Nano Letters, 2010, 10(4): 1253–1258

    Article  CAS  Google Scholar 

  8. Chen L, Zhu J, Qing L, Chen S, Wang Y R. Controllable synthesis of functionalized CdS nanocrystals and CdS/PMMA nanocomposite hybrids. European Polymer Journal, 2007, 43(11): 4593–4601

    Article  CAS  Google Scholar 

  9. Pentimalli M, Antolini F, Bauer E M, Capitani D, Di Luccio T, Viel S. A solid state nuclear magnetic resonance study on the thermolytic synthesis of CdS nanoparticles in a polystyrene matrix. Materials Letters, 2006, 60(21–22): 2657–2661

    Article  CAS  Google Scholar 

  10. Rathore K S, Patidar D, Janu Y, Saxena N S, Sharma K B, Sharma T P. Structural and optical characterization of chemically synthesized ZnS nanoparticles. Chalcogenide Letters, 2008, 5(6): 105–110

    CAS  Google Scholar 

  11. Dixit M, Gupta S, Mathur V, Rathore K S, Sharma K B, Saxena N S. Study of glass transition temperature of PMMA and CdS-PMMA composite. Chalcogenide Letters, 2009, 6(3): 131–136

    CAS  Google Scholar 

  12. Jelcia Z, Holjevac-Grguric T, Rek V. Mechanical properties and fractal morphology of high-impact polystyrene/poly(styrene-bbutadiene-b-styrene) blends. Polymer Degradation and Stability, 2005, 90(2): 295–302

    Article  Google Scholar 

  13. Ash B J, Schadler L S, Siegel R W. Glass transition behavior of alumina/polymethylmethacrylate nanocomposites. Materials Letters, 2002, 55(1–2): 83–87

    Article  CAS  Google Scholar 

  14. Choi SW, Yoon J H, An M J, Chae W S, Cho H M, Choi M G, Kim Y R. Organic nanotube induced by photocorrosion of CdS nanorod. Bulletin of the Korean Chemical Society, 2004, 25(7): 983–985

    Article  CAS  Google Scholar 

  15. Lu X F, Mao H, Zhang W J, Wang C. Synthesis and characterization of CdS nanoparticles in polystyrene microfibers. Materials Letters, 2007, 61(11–12): 2288–2291

    Article  CAS  Google Scholar 

  16. Mammeri F, Bourhis E L, Rozes L, Sanchez C. Mechanical properties of hybrid organic-inorganic materials. Journal of Materials Chemistry, 2005, 15(35–36): 3787–3811

    Article  CAS  Google Scholar 

  17. Gao Z, Xie W, Hwu J M, Wells L, Pan W P. The characterization of organically modified montmorillonite and its filled PMMA nanocomposite. Journal of Thermal Analysis and Calorimetry, 2001, 64(2): 467–475

    Article  CAS  Google Scholar 

  18. Whittington A P, Nguyen S T, Kim J H. Thermal behavior of polystyrene-silica nanocomposites. Nanoscape, 2009, 6(1): 26–29

    Google Scholar 

  19. Zhao Q, Samulski E T. A comparative study of poly(methyl methacrylate) and polystyrene/clay nanocomposites prepared in supercritical carbon dioxide. Polymer, 2006, 47(2): 663–671

    Article  CAS  Google Scholar 

  20. Chung H J, Taubert A, Deshmukh R D, Composto R J. Mobile nanoparticles and their effect on phase separation dynamics in thin-film polymer blends. Europhysics Letters, 2004, 68(2): 219–225

    Article  CAS  Google Scholar 

  21. Ginzburg V V, Qiu F, Paniconi M, Peng G W, Jasnow D, Balazs A C. Simulation of hard particles in a phase-separating binary mixture. Physical Review Letters, 1999, 82(20): 4026–4029

    Article  CAS  Google Scholar 

  22. Tang Y L, Ma Y Q. Controlling structural organization of binary phase-separating fluids through mobile particles. Journal of Chemical Physics, 2002, 116(17): 7719–7723

    Article  CAS  Google Scholar 

  23. Baschnagel J, Binder K. On the influence of hard walls on structural properties in polymer glass simulation. Macromolecules, 1995, 28(20): 6808–6818

    Article  CAS  Google Scholar 

  24. Kraus J, Müller-Buschbaum P, Kuhlmann T, Schubert D W, Stamm M. Confinement effects on the chain conformation in thin polymer films. Europhysics Letters, 2000, 49(2): 210–216

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Vishal Mathur.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mathur, V., Dixit, M., Rathore, K. et al. Morphological and mechanical characterization of a PMMA/CdS nanocomposite. Front. Chem. Sci. Eng. 5, 258–263 (2011). https://doi.org/10.1007/s11705-010-1014-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11705-010-1014-7

Keywords

Navigation