Abstract
An extensive soil investigation was conducted in different domains of Changchun to disclose the fractionations of Pb, Cu, Cd, Zn and Ni in urban soils. Meanwhile correlation analysis and multiple stepwise regressions were used to define relationships between soil properties and metal fractions and the chief factors influencing the fractionation of heavy metals in the soils. The results showed that Pb, Ni and Cu were mainly associated with the residual and organic forms; most of Cd was concentrated in the residual and exchangeable fractions. Zn in residual and carbonate fraction was the highest. The activities of the heavy metals probably declined in the following order: Cd, Zn, Pb, Cu and Ni. The chemical fractions of heavy metals in different domains in Changchun City were of significantly spatial heterogeneity. Soil properties had different influences on the chemical fractions of heavy metals to some extent and the main factors influencing Cd, Zn, Pb, Cu and Ni fractionation and transformation were apparently different.
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References
AVERY B W, BASCOMB C L, 1974. Soil Survey Laboratory Methods [M]. Tech. Monogr. No. 6. Harpenden: Soil Survey Press.
BELLINGER D, LEVITON A, SLOWMAN J, 1990. Antecedents and correlates of improved cognitive performance in children exposed in utero to low levels of lead [J]. Environmental Health Perspection, 89: 5–11.
BRUDER-HUBSCHER V, LAGARDE F, LEROY M J F, et al., 2002. Application of a sequential extraction procedure to study the release of elements from municipal solid waste incineration bottom ash [J]. Analytical Chimica Acta, 451: 285–295.
CHAPMAN H D, 1965. Cation exchangeable capacity [A]. In: BLACK C A (ed.). Methods of Soil Analysis. Agronomy, vol. 9. [C]. Madison: American Society of Agronomy, 891–901.
CHRISTENSEN T H, 1984. Cadmium soil sorption at low concentrations, II: reversibility, effect of changes in solute composition, and effect of soil aging [J]. Water, Air and Soil Pollution, 21: 115–125.
DE MIGUEL E, LLAMAS J F, CHACON E et al., 1997. Origin and patterns of distribution of trace elements in street dust: unleaded petrol and urban lead [J]. Atmospheric Environment, 31(17): 2733–2740.
DIETRICH K N, SUCCOP P A, BORNSCHEIN R et al., 1990. Lead exposure and neurobehavioral development in later infancy [J]. Environmental Health Perspection, 89: 13–19.
FAULKNER S P, PATRICK W H, GAMBRELL R P, 1989. Field techniques for measuring wetland soil parameters [J]. Soil Sci. Soc. Am. J., 53: 883–890.
GEE G W, BAUDER J W, 1986. Particle size analysis [A]. In: KLUTE A (ed.). Methods of Soil Analysis: Part I. Physical and Mineralogical Methods [C]. Madison: American Society of Agronomy, 383–411.
IMPERATO A M, ADAMOB P, NAIMOA M et al., 2003. Spatial distribution of heavy metals in urban soils of Naples city (Italy) [J]. Environmental Pollution, 124(2): 247–256.
KINGSTON H M, HASWELL S J, 1997. Microwave-Enhanced Chemistry [M]. Washington: American Chemical Society Press.
LI Xue-yuan, 2001. Soil Chemistry [M]. Beijing: Higher Education Press, 105. (in Chinese)
LU Ying, GONG Zi-tong, ZHANG Gan-lin, 2003. Concentrations and chemical speciations of Cu, Zn, Pb and Cr of urban soils in Nanjing, China [J]. Geoderma, 115(2): 101–111.
LUIS Madrid, ENCARNACIÓN Diaz-Barrjentos, FERNANDO Madrid, 2002. Distribution of heavy metal contents of urban soils in parks of Seville [J]. Chemosphere, 49(10): 1301–1308.
MA L Q, RAO G N, 1997. Chemical fractionation of cadmium, copper, nickel and zinc in contaminated soils [J]. Journal of Environmental Quality, 26(1): 259–264.
MIELKE H W, GONZALES C R, SMITH M K et al., 1999. The urban environment and children’s health: soils as an integrator of lead, zinc and cadmium in New Orleans, Louisiana [J]. Environmental Research, 81(2): 117–129.
MUSTAFA T, 2003. Determination of trace metals in the river Yesilirmak sediments in Tokat, Turkey using sequential extraction procedure [J]. Microchemical Journal, 74(1): 105–110.
SPOSITO G, 1989. The Chemistry of Soils [M]. USA: Oxford University Press, 277.
TESSIER A, CAMPBELL P G C, BLSSON M, 1979. Sequential extraction procedure for the speciation of particulate trace metals [J]. Analytical Chemistry, 51: 844–851.
ULRICH B, 1983. Soil acidity and its relations to acid deposition [A]. In: ULRICH B, PANKRA T H J (eds.). Effects of Accumulation of Air Pollutants on Forest Ecosystems [C]. Reidel: Dordrecht Press, 127–146.
WATT J, THORNTON I, COTTER-HOWELLS J, 1993. Physical evidence suggesting the transfer of soil Pb into young children via hand-to-mouth activity [J]. Applied Geochemistry, S2, 269–272.
WILCKE W, LILIENFEIN J, LIMA S D C et al., 1999. Contamination of highly weathered urban soils in Uberlandia, Brazil [J]. Journal of Plant Nutrition Soil and Soil Science, 162(5): 539–548.
WU Xin-min, LI Lian-qing, PAN Gen-xing et al., 2003. Soil pollution of Cu, Zn, Pb and Cd in different city zones of Nanjing [J]. Environmental Science, 24(3): 105–111. (in Chinese)
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Biography: GUO Ping (1972–), female, a native of Changchun of Jilin Province, Ph.D. candidate, lecture, specialized in environmental pollution chemistry and ecology. E-mail: guoping@email.jlu.edu.cn
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Guo, P., Xie, Zl., Li, J. et al. Relationships between fractionations of Pb, Cd, Cu, Zn and Ni and soil properties in urban soils of Changchun, China. Chin. Geograph.Sc. 15, 179–185 (2005). https://doi.org/10.1007/s11769-005-0013-y
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DOI: https://doi.org/10.1007/s11769-005-0013-y