Abstract
The extraction of zinc from zinc sulfate solution was investigated, using 20% saponified D2EHPA as an extractant and 260# sulfonate kerosene as a diluent. The solution was stirred for 8 min at phase ratio (V o/V a) of 1.0:1.0, initial pH of 2.0 and stirring speed of 200 r/min. The results show that 75% zinc can be extracted from the zinc sulfate solution when the concentration of zinc is 18.7 g/L after being settled for 10 min. 88.60% zinc can be stripped by 196 g/L sulfuric acid, and zinc ion can be separated from ferric ion.
Similar content being viewed by others
References
LAN Xing-hua. Solvent extraction of multiple nonferrous metals in the South Africa(IV) [J]. World Nonferrous Metals, 2007(1): 20–21.
ZHANG Xiao-juan, LI Xin-gang, CAO Hong-bin, ZHANG Yi. Separation of copper, iron (III), zinc and nickel from nitrate solution by solvent extraction using LK-C2 [J]. Separation and Purification Technology, 2010, 70(3): 306–313.
LIU Ge, ZHANG Jin-zhu. Recent advance for separation of zinc from cadmium [J]. Hydrometallurgy of China, 2005, 24: 221–225. (in Chinese)
LAN Xing-hua. Recent advance for solvent extraction of zinc [J]. World Nonferrous Metals, 2008(8): 28–32.
FU Weng, CHEN Qi-yuan, WU Qian, HU Hui-ping, BAI Lan. Solvent extraction of zinc from ammoniacal/ammonium chloride solutions by a sterically hindered β-liketone and its mixture with tri-n-octylphosphine oxide [J]. Hydrometallurgy, 2010, 100(3/4): 116–121.
WANG Sheng-dong, JIANG Xun-xiong, JIANG Kai-xi, FAN Yan-qing. Application of P204 in hydrometallurgy of ocean cobalt-rich crust [J]. Nonferrous Metals, 2006, 58(1): 69–71.
VAHIDI E, RASHCHI F, MORADKHANI D. Recovery of zinc from an industrial zinc leach residue by solvent extraction using D2EHPA [J]. Minerals Engineering, 2009, 22(2): 204–206.
CHEN Hao, ZHU Yun, HU Han. Zinc extraction with LIX54 in Zn-NH3-H2O system [J]. Nonferrous Metals, 2003, 55(3): 50–52.
MA Rong-jun. Research progress of solvent extraction in hydrometallurgy [M]. Beijing: Metallurgical Industry Press, 1979: 227–230. (in Chinese)
GAO Zi-li, SUN Si-xiu, SHEN Jing-lan. Solvent extraction chemistry [M]. Beijing: Science Press, 1991: 66–69. (in Chinese)
MELLAH A, BENACHOUR D. The solvent extraction of zinc, cadmium and chromium from phosphoric acid solutions by tri-n butyl phosphate in kerosene diluent [J]. Separation and Purification Technology, 2007, 56(2): 220–224.
GU H, CHANG C M. Preliminary design of a solvent extraction processing for the galvanic striping of iron from D2EHPA [J]. Mineral and Metallurgical Processing, 2000, 17(1): 16–22.
YANG Da-jin, XIE Gang, WANG Ji-kun. Study on solvent extraction of zinc sulfate solution [J]. Nonferrous Metals: Extractive Metallurgy, 2006(2): 9–24.
ZENG Ping, WEI Hong-mei. Studies on the properties of the extraction of vanadium(IV) by saponified P204 [J]. Journal of Xiangtan University: Natural Science, 1995, 17(4): 64–68. (in Chinese)
QIN Wen-qing, LI Wei-zhong, LAN Zhuo-yue, QIU Guan-zhou. Simulated small-scale pilot plant heap leaching of low-grade oxide zinc ore with integrated selective extraction of zinc [J]. Minerals Engineering, 2007, 20(7): 694–700.
Author information
Authors and Affiliations
Corresponding author
Additional information
Foundation item: Project(50774094) supported by the National Natural Science Foundation of China
Rights and permissions
About this article
Cite this article
Long, Hz., Chai, Ly., Qin, Wq. et al. Solvent extraction of zinc from zinc sulfate solution. J. Cent. South Univ. Technol. 17, 760–764 (2010). https://doi.org/10.1007/s11771-010-0553-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11771-010-0553-x