Skip to main content
SpringerLink
Log in

A review on UV/TiO2 photocatalytic oxidation process (Journal Review)

  • Energy and Environmental Engineering
  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

Advanced oxidation processes (AOPs) with UV irradiation and photocatalyst titanium dioxide (TiO2) are gaining growing acceptance as an effective wastewater treatment method. A comprehensive review of the UV-TiO2 photocatalytic oxidation process was conducted with an insight into the mechanism involved, catalyst TiO2, irradiation sources, types of reactors, comparison between effective modes of TiO2 application as immobilized on surface or as suspension, and photocatalytic hybrid membrane system. Photocatalytic degradation technique with titanium dioxide is generally applied for treating wastewater containing organic contaminants due to its ability to achieve complete mineralization of the organic contaminants under mild conditions such as ambient temperature and ambient pressure. Recently, photocatalysis studies using TiO2 have been gaining attention for the degradation of persistent organic pollutants and other organic chemicals which are known to be endocrine disruptors. Treatment of wastewater in a titanium dioxide-suspended slurry reactor has been widely utilized due to its simplicity and enhanced degradation efficiency. However, this system requires separation of TiO2 from water after the photocatalytic process. The final section of the manuscript focuses on the removal of TiO2 using a membrane hybrid system. A two-stage coagulation and sedimentation process coupled with microfiltration hollow-fibre membrane process was found to achieve complete removal of TiO2, and the recovered TiO2 can be reused for a photocatalytic process after regeneration.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. S. N. Frank and A. J. Bard, J. Phys. Chem., 81, 1484 (1977).

    Article  CAS  Google Scholar 

  2. A. L. Pruden and D. F. Ollis, J. Catal., 82, 404 (1983).

    Article  CAS  Google Scholar 

  3. C.-Y. Hsiao, C.-L. Lee and D. F. Ollis, J. Catal., 82, 418 (1983).

    Article  CAS  Google Scholar 

  4. D. F. Ollis, C.Y. Hsiao, L. Budiman and C. L. Lee, J. Catal., 88, 89 (1984).

    Article  CAS  Google Scholar 

  5. D. F. Ollis, Environ. Sci. & Technol., 19, 480 (1985).

    Article  CAS  Google Scholar 

  6. S. Sappideen, PhD Dissertation, UNSW (2000).

  7. J.W. Tang, Z.G. Zou, J. Yin and J. Ye, Chem. Phy. Let., 382, 175 (2003).

    Article  CAS  Google Scholar 

  8. N. Serpone and E. Pelizzetti, Photocatalysis: Fundamentals and applications, John Wiley & Sons, New York (1989).

    Google Scholar 

  9. M. Schiavello and A. Sclafani, Thermodynamics and kinetic aspects in photocatalysis, Photocatalysis: Fundamentals and applications, John Wiley & Sons, Canada (1989).

    Google Scholar 

  10. S. Sakthivel, B. Neppolian, B. Arabindoo, M. Palanichamy and V. Murugesan, J. Sci. Ind. Res., 59, 556 (2000).

    CAS  Google Scholar 

  11. K. Okomoto, Y. Yamamoto, H. Tanaka and A. Itaya, Bull. Chem. Soc. Jpn., 58, 2023 (1985).

    Article  Google Scholar 

  12. K. Okomoto, Y. Yamamoto, H. Tanaka and A. Itaya, Bill. Chem. Soc. Jpn., 58, 2015 (1985).

    Article  Google Scholar 

  13. V. Augugliaro, L. Palmisano and A. Sclafani, Tox. Environ. Chem., 16, 89 (1988).

    Article  CAS  Google Scholar 

  14. M. Trillas, M. Pujol and X. Domenech, J. Chem. Tech. Biotechnol., 55, 85 (1992).

    CAS  Google Scholar 

  15. M. Kaneko and N. Okuru, Photocatalysis: Science and technology, Kodansha Ltd, Japan. 356 (2002).

    Google Scholar 

  16. P. R. Gogate and A. B. Pandit, Adv. Environ. Res., 8, 501 (2004).

    Article  CAS  Google Scholar 

  17. C. H. Wu, Chemos., 57, 601 (2004).

    Article  CAS  Google Scholar 

  18. A. P. Rivera, K. Tanaka and T. Hisanaga, App. Catal. B: Environ., 3, 37 (1993).

    Article  CAS  Google Scholar 

  19. E. Pelizzetti and C. Minero, Elect. Acta., 38, 47 (1993).

    Article  CAS  Google Scholar 

  20. P. H. Chen and C. H. Jeng, Water. Sup., 13, 29 (1995).

    CAS  Google Scholar 

  21. X. S. Ye, J. Sha, Z. K. Jiao and L. D. Zhang, Nanostruct. Mater., 8, 919 (1997).

    Article  CAS  Google Scholar 

  22. B. Sun and P. G. Smirniotis, Catal. Today, 88, 49 (2003).

    Article  CAS  Google Scholar 

  23. T. Weng, Photocatalytic purification and treatment of water and air, Elsevier Publishers, Amsterdam (1993).

    Google Scholar 

  24. J. R. Smyth and D. L. Bish, Crystal structures and cation sites of the rock-forming minerals, Allen & Unwin, London (1988).

    Google Scholar 

  25. R. I. Bickley, T. Gonzalez-Carreno, J. S. Lees, L. Palmisano and R. J. D. Tilley, J. Sol. St. Chem., 92, 178 (1991).

    Article  CAS  Google Scholar 

  26. P. Reeves, R. Ohlhausen, D. Sloan, K. T. Scoggins, C. Clark, B. Hutchinson and D. Green, Sol. Ene., 48, 413 (1992).

    Article  CAS  Google Scholar 

  27. R. R. Beska and J. Kiwi, App. Catal. B: Environ., 16, 19 (1998).

    Article  Google Scholar 

  28. S. Yamazaki, S. Matsunaga and K. Hori, Water Res., 35, 1022 (2001).

    Article  CAS  Google Scholar 

  29. N. Xu, Z. Shi, Y. Fan, J. Dong, J. Shi and M. Z.-C. Hu, Ind. Eng. Chem. Res., 38, 373 (1999).

    Article  CAS  Google Scholar 

  30. O. Legrini, E. Oliveros and A.M. Braun, Chem Rev., 93, 671 (1993).

    Article  CAS  Google Scholar 

  31. M. R. Hoffmann, S. T. Martin, W. Choi and D.W. Behnemann, Chem. Rev., 93, 69 (1995).

    Article  Google Scholar 

  32. O. M. Alfano, D. Bahnemann, A. E. Cassano, R. Dillert and R. Goslich, Catal. Today, 58, 199 (2000).

    Article  CAS  Google Scholar 

  33. R.W. Matthews and S. R. McEvoy, J. Photochem. Photobiol. A: Chem., 64, 231 (1992).

    Article  CAS  Google Scholar 

  34. G. L. Puma and P. L. Yue, Ind. Eng. Chem. Res., 38, 3238 (1999).

    Article  CAS  Google Scholar 

  35. K Demeestere, J. Dewulf and B. De Witte, App. Catal. B: Environ., 60, 93 (2005).

    Article  CAS  Google Scholar 

  36. A. K. Tod, Catal., 44, 357 (1998).

    Google Scholar 

  37. A. K. Ray and A. A. C. M. Beenackers, AIChE J., 44, 477. 40, 73 (1998).

    Article  CAS  Google Scholar 

  38. C. Tang and V. Chen, Water Res., 38, 2775 (2004).

    Article  CAS  Google Scholar 

  39. H. Shon, Ultrafiltration and nanofiltration hybrid systems in wastewater treatment and reuse, PhD Dissertation. UTS (2005).

  40. A. Haarstrick, O. M. Kut and E. Heinzle, Environ. Sci. Technol., 30, 817 (1996).

    Article  CAS  Google Scholar 

  41. R. Thiruvenkatachari, T. O. Kwon and I. S. Moon, Sep. Sci. Technol., 40, 2871 (2005).

    Article  CAS  Google Scholar 

  42. P. L. Yue, Water Sci. Technol., 35, 189 (1997).

    CAS  Google Scholar 

  43. J. C. Lee, M. S. Kim, C. K. Kim, C. H. Chung, S.M. Cho, G.Y. Han, K. J. Yoon and B.W. Kim, Korean J. Chem. Eng., 20, 862 (2003).

    Article  CAS  Google Scholar 

  44. Y. S. Na, D.H. Kim, C. H. Lee, S.W. Lee, Y. S. Park, Y. K. Oh, S. H. Park and S. K. Song, Korean J. Chem. Eng., 21, 430 (2004).

    Article  CAS  Google Scholar 

  45. C. S. Turchi. J. F. Klausner and E. Marchand, Field test results for the solar photocatalysis detoxification of fuel-contaminated groundwater, Chemical Oxidation: Technology for the Nineties, 3rd International Symposium (1993).

  46. R. Dillerst, S. Vollmer, M. Schober, J. Theurich, D. Bahnemann, H. J. Arntz, K. Pahlmann, J. Wienefeld, T. Schmedding and G. Sager, Chem. Eng. Technol., 22, 931 (1999).

    Article  Google Scholar 

  47. I. Arslan, I. A. Balcioglu and D.W. Bahnemann, Water Sci. Technol., 44, 171 (2001).

    CAS  Google Scholar 

  48. D. Y. Goswami, J. Sol. Ene. Eng., 119, 101 (1997).

    Article  CAS  Google Scholar 

  49. H. Freudenhammer, D. Bahnemann, L. Bousselmi, S. U. Geissen, A. Ghrabi, F. Saleh, A. Si-Salah, U. Siemon and A. Vogelpohl, Water Sci. Technol., 35, 149 (1997).

    Article  CAS  Google Scholar 

  50. C. Guillard, H. Lachheb, A. Houas, M. Ksibi, E. Elaloui and J.-M. Herrmann, J. Photochem. Photobiol. A: General, 158, 27 (2003).

    Article  CAS  Google Scholar 

  51. M. A. Anderson, S. Tunesi and Q. Xu, US patent 5035784 (1991).

  52. G. A. Cooper, US Patent 4888101 (1989).

  53. J. Oonada, JP Patent 06071256, (1994).

  54. M. Bideau, B. Claudel, C. Dubien, L. Faure and H. Karzouan, J. Photochem. Photobiol. A. Chem., 91, 137 (1995).

    Article  CAS  Google Scholar 

  55. A.M. Braun, In photochemical conversion and storage of solar energy, 8th International Conference on Photochemical Conversion and Storage of Solar Energy, Palermo, Italy (1990).

  56. K. Hofstadler, R. Bauer, S. Novalic and G. Heisler, Environ. Sci. Technol., 28, 670 (1994).

    Article  CAS  Google Scholar 

  57. J. Arana, J. A. H. Melian, J.M. D. Rodriguez, O.G. Diaz, A. Viera, J. P. Pena, P. M. M. Sosa and V. E. Jimenez, Catal. Today, 76, 279 (2002).

    Article  CAS  Google Scholar 

  58. J. Arana, J. M. Dona-Rodriguez, R. E. Tello, I. Garriga, C. Cabo, O. Gonzalez-Diaz, J. A. Herrera-Melian, J. Perez-Pena, G. Colon and J. A. Navio, App. Catal. B: Environ., 44, 161 (2003).

    Article  CAS  Google Scholar 

  59. W. Xi and S.-U. Geissen, Wat. Res., 35, 1256 (2001).

    Article  CAS  Google Scholar 

  60. R. Molinari, M. Mungari, E. Drioli, A. Di Paola, V. Loddo, L. Palmisano and M. Schiavello, Catal. Today, 55, 71 (2000).

    Article  CAS  Google Scholar 

  61. R. Molinari, L. Palmisano, E. Drioli and M. Schiavello, J. Mem. Sci., 206, 399 (2002).

    Article  CAS  Google Scholar 

  62. R. Molinari, F. Pirillo, M. Falco, V. Loddo and L. Palmisano, Chem. Eng. Pro., 43, 1103 (2004).

    Article  CAS  Google Scholar 

  63. R. Thiruvenkatachari, T.O. Kwon and I. S. Moon, Korean J. Chem. Eng., 22, 938 (2005).

    Article  CAS  Google Scholar 

  64. S. Kagaya, K. Shimizu, R. Arai and K. Hasegawa, Wat. Res., 33, 1753 (1999).

    Article  CAS  Google Scholar 

  65. K. Sopajaree, S. A. Qasim, S. Basak and K. Rajeshwar, J. Appl. Electrochem., 29, 533 (1999).

    Article  CAS  Google Scholar 

  66. K. Sopajaree, S. A. Qasim, S. Basak and K. Rajeshwar, J. Appl. Electrochem., 29, 1111 (1999).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Engineering, University of Technology, P.O. Box 123, Sydney, Broadway, NSW, 2007, Australia

    Ramesh Thiruvenkatachari, Saravanamuthu Vigneswaran & Il Shik Moon

  2. Faculty of Engineering, Sunchon National University, 315 Maegok Dong, Suncheon, Chonnam, 540-742, Korea

    Il Shik Moon

Authors
  1. Ramesh Thiruvenkatachari
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Saravanamuthu Vigneswaran
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Il Shik Moon
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Saravanamuthu Vigneswaran.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Thiruvenkatachari, R., Vigneswaran, S. & Moon, I.S. A review on UV/TiO2 photocatalytic oxidation process (Journal Review). Korean J. Chem. Eng. 25, 64–72 (2008). https://doi.org/10.1007/s11814-008-0011-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11814-008-0011-8

Key words

Search

Navigation