Abstract
The adsorption of Cr (VI) from aqueous solution onto nanoparticles hematite (α-Fe2O3) of different morphologies synthesized by acid hydrolysis, transformation of ferrihydrite, sol gel methods has been investigated. The hematite particle sizes were in the range 15.69-85.84 nm and exhibiting different morphologies such as hexagonal, plate-like, nano-cubes, sub-rounded and spherical. The maximum adsorption capacity of Cr (VI) was found to be in the range 6.33–200 mgg−1 for all hematite samples. The kinetics of sorption was rapid, reaching equilibrium at 45–240 minutes. Sorption kinetics and equilibria followed pseudo-second order and Langmuir adsorption isotherm models. The rate constants were in the range 0.996–2.37×10−2 g/mg/min for all samples. The maximum adsorption was attained at pH 3.0, while adsorption decreased as the pH increased from pH 3.0 to 10.0. The study revealed that the hematite with plate-like morphology has the highest adsorption capacity. The sorption process has been found to be feasible following a chemisorption process, and adsorption of Cr (VI) onto hematite nanoparticles was by inner sphere surface complexation due to low desorption efficiency in the range 9.54–53.4%. However, the result of ionic strength revealed that the reaction was by outer sphere complexation. This study showed that morphologies play a vital role in the adsorption capacities of samples of hematite in the removal of Cr (VI) from aqueous solution.
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B. J Gao, Y. B. Li and Z. P. Chen, Chem. Eng. J., 150, 337 (2009).
E. M. N. Chirwa and Y. T. Wang, Environ. Sci. Technol., 31, 1446 (1997).
A. Barai and R. D. Engelken, Environ. Sci. Pollution., 5, 121 (2002).
L. E. Eary and D. Rai, Environ. Sci. Technol., 22, 972 (1988).
G. L. Ghurye, D. A. Clifford and A. R. Tripp, J. Am. Water Works Assoc., 91, 85 (1999).
D. A. Clifford, Adsorption and ion exchange, in: F.W. Pontius (Ed.), Water Quality and Treatment: A Handbook of Community Water Supplies, McGraw-Hill, New York, 561 (1990).
X. Wang, X. Chen, X. Ma, H. Zheng, M. Ji and Z. Zhang, Chem. Phys. Lett., 384, 391 (2004).
McGraw-Hill Encyclopedia of Science and Technology New York, 8, 185 (2002).
D. B. Singh, G. S. Gupta, G. Prasad and D. C. Rupainwar, J. Environ. Sci. Health, A28, 1813 (1993).
G. E. Brown Jr., S. A. Chambers, J. E. Amonette, J.R. Rustad, T. Kendelewicz, C. S. Doyle, D. Grolimund, N. S. Foster-Mills, S. A. Joyce and S. Thevuthasan, J. Conference Abstract, 5, 253 (2000).
O. Ajouyed, C. Hurel, M. Ammari, L. Ben Allal and N. Marmier, J. Hazard. Mater., 174, 616 (2010).
U. Schwertmann and R.M Cornell, Iron oxide in the laboratory: preparation and characterization, Wiley-VCH Weinheim, Germany, 1 (1991).
T. P. Raming, A. J. A. Winnubst, C. M. Van Kats and A. P. Philipse, J. Colloid Interface Sci., 249, 346 (2002).
T. Sugimoto, M.M. Khan and A. Muramatsu, Colloids Surf. A: Physicochem. Eng. Aspects, 70, 167 (1993).
International Institute of Tropical Agriculture (IITA), Selected Methods for Soil and Plant Analysis. Manual Series, 1, 3 (1979).
B. H. Hameed, R.R. Krishni and S. A. Sata, J. Hazard. Mater.., 162, 305 (2009).
J. S. Noh and J. Schwarz, J. Colloid Interface Sci., 130, 157 (1989).
M. Tadic, N. Citakovic, M. Panyam, Z. Stojanovic, D. Markoviv and V. Spasojevic, J. Alloys Compds, 509, 7639 (2011).
H. I. Adegoke and F. A. Adekola, Colloid J., 74, 420 (2012).
K. Goh, T. Lim, A. Bana and Z. Dong, J. Hazard. Mater., 179, 818 (2010).
Y. Mamindy-Pajany, C. Hurel, N. Marmier and M. Romeo, Desalination, 281, 93 (2011).
M. Kosmulski, J. Colloid Interface Sci., 253, 77 (2002).
M.V. Subbaiah, G. Yuvaraya, Y. Vijaya and A. Krishnaiah, J Taiwan List. Chem. Eng., 42, 965 (2011).
W. Qin, C. Yang, R. Yi and G. Gao, J. Nanomaterials, DOI:10.11555/2011/159259 (2011).
L. Wang and L. Gao, J. Colloid Interface Sci., 349, 519 (2010).
S. K. Apte, S. D. Naik, R. S. Sonawane and B. B. Kalew, J. Am. Ceram. Soc., 90, 412 (2007).
M. Gotic, S. Music, S. Popovic and L. Sekovanic, Croatica, Chem. Acta, 81, 569 (2008).
H. D. Ruan, R. I. Frost, J. T. Kloprogge and L. Duong, Spectrochimica Acta Part A., 58, 967 (2000).
J. E. Iglesias and C. J. Serna, Miner. Petrogr. Acta, 29A, 363 (1985).
K. Simeonidis, S. Tresintsi, C. Martinez-Boubeta, G. Vourlias, I. Tsiaoussis, G. Stavropoulos, M. Mitrakas and M. Angelakeris, Chem. Eng. J., 168, 1008 (2011).
J. Hu, I.M. C. Lo and G. Chen, Langmuir, 21, 11173 (2005).
J. Fang, Z. Gu, D. Gang, C. Liu, E. S. Ilton and B. Deng, Environ. Sci., 44, 4748 (2007).
A. Imai and E. F. Gloyna, Water Res., 24, 1143 (1990).
P. Srinivas, R. Shashikant and G. S. Munjunatha, J. Environ. Sci. Health, A27, 2227 (1992).
A. Ajmal, A. H. Khan, S. Ahmad and A. Ahmad, Water Res., 32, 3085 (1998).
B. Yu, Y.H. Zhang, A. Shukla, S. S. Shukla and K. L. Dorris, J. Hazard. Mater., 384, 83 (2001).
C. Namasivayam and R. T. Yamuna, Chemosphere, 30, 561 (1995).
D. Q. L. Oliveira, M. Goncalves, L. C. A. Oliveira and L. R. G. Guiherme, J. Hazard. Mater., 151, 280 (2008).
C. H. Weng, Y. C. Sharma and S. H. Chu, J. Hazard. Mater., 155, 65 (2008).
C. Namasivayam and M.V. Sureshkumar, Bioresour. Technol., 99, 2218 (2008).
Y. Arai, E. J. Elzinga and D. L. Sparks, J. Colloid Interface Sci., 235, 80 (2001).
N. Ouazen and M. N. Sahmoune, Int. J. Chem. Rea. Eng. Article, A151, 1 (2010).
U.M. Uysal and I. Arai, J. Hazard. Mater., 149, 482 (2007).
S. H. Chien and W. R. Clayton, Sci. Soc. Am. J., 44, 265 (1980).
S. Basha and Z.V. P. Murthy, Process Biochem., 42, 1521 (2007).
M. I. Temkin and V. Pyzhev, Acta Physiochemica, USSR 12, 327 (1940).
B. Hu, W. Cheng, H. Zhang and S. Yang, J. Nucl. Mater., 406, 263 (2010b).
T. S. Hsia, S. L. Lo, C. F. Lin and D. Y. Lee, Coll. Surf. A, 85, 1 (1994).
V. Pakade, E. Cukrowska, J. Darkwa, N. Torto and L. Chimuka, Water SA, 37, 529 (2011).
N. Goudarzian, P. Ghahramani and S. Hossini, Polym. Int., 36, 61 (1996).
F. A. Miller and C. H. Wilkins, Anal. Chem., 24, 1253 (1952).
D.G. Strawn and D.L. Sparks, Soc. Sci. Soc. Am. J., 64, 144 (2000).
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Adegoke, H.I., AmooAdekola, F., Fatoki, O.S. et al. Adsorption of Cr (VI) on synthetic hematite (α-Fe2O3) nanoparticles of different morphologies. Korean J. Chem. Eng. 31, 142–154 (2014). https://doi.org/10.1007/s11814-013-0204-7
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DOI: https://doi.org/10.1007/s11814-013-0204-7