Skip to main content
SpringerLink
Log in

A strategy to prepare internally plasticized PVC using a castor oil based derivative

  • Polymer, Industrial Chemistry
  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

Internally plasticized PVC was prepared via chemical reaction of azide PVC and alkynyl group containing castor oil methyl ester. The chemical structure of alkynyl group containing castor oil methyl ester and internally plasticized PVC was characterized with FT-IR and 1H NMR. Properties of internally plasticized PVC, including thermal stability, tensile tests and resistance to extraction in different solvents, was investigated. The results showed that alkynyl group containing castor oil methyl ester, as internal plasticizer of PVC, not only decreased the Tg of PVC from 84.6 °C to 41.6 °C efficiently, but also presented no plasticizer loss in five different solvents. The tensile tests showed that elongation at break and tensile strength of internally plasticized PVC was 353.8% and 18.1MPa. The internally plasticized PVC has potential application in replacing the traditional PVC material in PVC products with high durability.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Y. Zhou, N. Yang and S. Hu, Resour. Conserv. Recycl., (73, 33 (2013).

    Article  Google Scholar 

  2. Z. Qiu and P. Zhou, RSC Adv., 4, 51411 (2014).

    Article  CAS  Google Scholar 

  3. P. Jia, M. Zhang, L. Hu, J. Zhou, G. Feng and Y. Zhou, Polym. Degrad. Stab., (121, 292 (2015).

    Article  CAS  Google Scholar 

  4. M. G. A. Vieira, M. A. da Silva, L. O. dos Santos and M. M. Beppu, Eur. Polym. J., (47, 254 (2011).

    Article  CAS  Google Scholar 

  5. M. Rahman and C. S. Brazel, Prog. Polym. Sci., (29, 1223 (2004).

    Article  CAS  Google Scholar 

  6. P. Jia, M. Zhang, L. Hu and Y. Zhou, Korean J. Chem. Eng., (33, 1080 (2016).

    Article  CAS  Google Scholar 

  7. S. Benjamin, E. Masai, N. Kamimura, K. Takahashi, R. C. Anderson and P. A. Faisal, J. Hazard. Mater., 340, 360 (2017).

    Article  CAS  PubMed  Google Scholar 

  8. A. L. Perez, M. Liong, K. Plotkin, K. P. Rickabaugh and D. J. Paustenbach, Chemosphere, (167, 541 (2017).

    Article  CAS  PubMed  Google Scholar 

  9. J. H. Li and Y. C. Ko, Kaohsiung J. Med. Sci., 28, S17 (2012).

    Google Scholar 

  10. K. M. Gani, V. K. Tyagi and A. A. Kazmi, Environ. Sci. Pollut. R., (24, 17267 (2017).

    Article  CAS  Google Scholar 

  11. P. Jia, M. Zhang, L. Hu, G. Feng, C. Bo and Y. Zhou, ACS. Sustain. Chem. Eng., 3, 2187 (2015).

    Article  CAS  Google Scholar 

  12. J. Chen, X. Li, Y. Wang, K. Li, J. Huang, J. Jiang and X. Nie, J. Taiwan Inst. Chem. E., 65, 488 (2016).

    Article  CAS  Google Scholar 

  13. P. Jia, M. Zhang, C. Liu, L. Hu, G. Feng, C. Bo and Y. Zhou, RSC Adv., 5, 41169 (2015).

    Article  CAS  Google Scholar 

  14. B. W. Chieng, N. A. Ibrahim, Y. Y. Then and Y. Y. Loo, Polymers, (9, 204 (2017).

    Article  CAS  PubMed Central  Google Scholar 

  15. M. P Arrieta, M. D. Samper, M. Jiménez-López, M. Aldas and J. López, Ind. Crop. Prod., (99, 196 (2017).

    Article  CAS  Google Scholar 

  16. D. T. C. Ang, Y. K. Khong and S. N. Gan, J. Vinyl. Addit. Techn., 22, 80 (2016).

    Article  CAS  Google Scholar 

  17. S. Lee, M. S. Park, J. Shin and Y. W. Kim, Polym. Degrad. Stab., (147, 1 (2018).

    Article  CAS  Google Scholar 

  18. P. Jia, L. Hu, X. Yang, M. Zhang, Q. Shang and Y. Zhou, RSC Adv., 7, 30101 (2017).

    Article  CAS  Google Scholar 

  19. P. Jia, M. Zhang, L. Hu, F. Song, G. Feng and Y. Zhou, SCI REPUK, 8, 1589 (2018).

    Article  CAS  Google Scholar 

  20. P. Jia, M. Zhang, L. Hu, R. Wang, C. Sun and Y. Zhou, Polymers, (9, 621 (2017).

    Article  CAS  PubMed Central  Google Scholar 

  21. P. Jia, L. Hu, M. Zhang, G. Feng and Y. Zhou, Eur. Polym. J., (87, 209 (2017).

    Article  CAS  Google Scholar 

  22. R. Navarro, M. P. Perrino, C. García, C. Elvira, A. Gallardo and H. Reinecke, Macromolecules, (49, 2224 (2016).

    Article  CAS  Google Scholar 

  23. K. W. Lee, J. W. Chung and S. Y. Kwak, Macromol. Rapid Commun., (37, 2045 (2016).

    Article  CAS  PubMed  Google Scholar 

  24. J. Choi and S. Y. Kwak, Environ. Sci. Technol., (41, 3763 (2007).

    Article  CAS  PubMed  Google Scholar 

  25. B. Y. Yu, J. W. Chung and S. Y. Kwak, Environ. Sci. Technol., (42, 7522 (2008).

    Article  CAS  PubMed  Google Scholar 

  26. W. Choi, J. W. Chung and S. Y. Kwak, ACS Appl. Mater. Interfaces, 6, 11118 (2014).

    Article  CAS  PubMed  Google Scholar 

  27. C. Liu, J. Li, W. Lei and Y. Zhou, Ind. Crop. Prod., (52, 329 (2014).

    Article  CAS  Google Scholar 

  28. L. Zhang, M. Zhang, Y. Zhou and L. Hu, Polym. Degrad. Stab., (98, 2784 (2013).

    Article  CAS  Google Scholar 

  29. P. Jia, L. Hu, M. Zhang and Y. Zhou, J. Therm. Anal. Calorim., 124, 1331 (2016).

    Article  CAS  Google Scholar 

  30. P. Jia, R. Wang, L. Hu, M, Zhang and Y, Zhou, Pol. J. Chem. Technol., 19, 16 (2017).

    Article  CAS  Google Scholar 

  31. J. Lafarge, N. Kebir, D. Schapman, V. Gadenne and F. Burel, Cellulose, (20, 2779 (2013).

    Article  CAS  Google Scholar 

  32. B. Kiskan, G. Demiray and Y. Yagci, J. Polym. Sci. Pol. Chem., 46, 3512 (2008).

    Article  CAS  Google Scholar 

  33. H. Qu, X. Liu, J. Xu, H. Ma, Y. Jiao and J. Xie, Ind. Eng. Chem. Res., (53, 8476 (2014).

    Article  CAS  Google Scholar 

  34. S. V. Levchik and E. D. Weil, Polym. Adv. Technol., (15, 691 (2004).

    Article  CAS  Google Scholar 

  35. A. I. Balabanovich, T. A. Zevaco and W. Schnabel, Macromol. Mater. Eng., (289, 181 (2004).

    Article  CAS  Google Scholar 

  36. A. I. Balabanovich, Thermochim. Acta, (435, 188 (2005).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Envionment and Chemical Engineering, Yellow River Conservancy Technical Institute, Kaifeng Key Laboratory of Green Coating Materials, No. 1 Dongjing Avenue, Kaifeng 475004, Henan, P. R. China

    Hongying Chu & Jinju Ma

Authors
  1. Hongying Chu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jinju Ma
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Hongying Chu.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chu, H., Ma, J. A strategy to prepare internally plasticized PVC using a castor oil based derivative. Korean J. Chem. Eng. 35, 2296–2302 (2018). https://doi.org/10.1007/s11814-018-0118-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11814-018-0118-5

Keywords

Search

Navigation