Abstract
For the past century, tungsten has been exploited for numerous applications due to its unique properties, including its extremely high melting point, mass density, and mechanical strength. One specific potential application of tungsten (owing to its high mass density and strength) is the replacement of depleted uranium within kinetic energy antiarmor penetrators. Strenuous efforts in this direction have had limited success. However, nanoengineering has been applied recently to tailor the microstructure and properties of tungsten, leading to dramatic improvement with regard to this application. This paper provides some recent results on nanoengineered tungsten and discusses the underlying principles. It appears that nanoengineering is opening a new era for tungsten.
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References
R.P. Feynman, “There is Plenty of Roomat the Bottom”, Engineering & Science (Pasadena, CA: Caltech Public Relations, 1959), cited 2006; www.zyvex.com/nanotech/feynman.html.
E.O. Hall, “The Deformation and Ageing of Mild Steel: III. Discussion of Results”, P. Phys. Soc. B., 64 (1951), pp. 747–753.
N.J. Petch, “The Cleavage Strength of Polycrystals,” J. Iron and Steel Institute, 174 (1953), pp. 25–28.
C.C. Koch, “Optimization of Strength and Ductillity in Nanocrystalline and Ultrafine Grained Metals,” Scripta Mater., 49 (2003), pp. 657–662.
E. Ma, “Instabilities and Ductility of Nanocrystalline and Ultrafine-Grained Metals,” Scripta Mater. 49 (2003), pp. 663–668.
E. Ma, “Controlling Plastic Instability,” Nature Materials, 2 (2003), pp. 7–8.
K.M. Youssef et al., “Ultratough Nanocrystalline Copper with a Narrow Grain Size Distribution,” Appl. Phys. Lett., 85 (6) (2004), pp. 929–931.
K.M. Youssef et al., “Ultrahigh Strength and High Ductility of Bulk Nanocrystalline Copper,” Appl. Phys. Lett., 87 (9) (2005), p. 091904.
S. Cheng et al., “Tensile Properties of In Situ Consolidated Nanocrystalline Cu,” Acta Mater., 53 (5) (2005), pp. 1521–1533.
Y.M. Wang and E. Ma, “Three Strategies to Achieve Uniform Tensile Deformation in a Nanostructured Metal,” Acta Mater., 52 (2004), pp. 1699–1709.
Y.M. Wang et al., “High Tensile Ductility in a Nanostructured Metal, Nature, 419 (2002), pp. 912–915.
E. Ma, “Eight Routes to Improve the Tensile Ductility of Bulk Nanostructured Metals and Alloys,” JOM, 58 (4) (2006), pp. 49–53.
C.C. Koch and J. Naraya, “The Inverse, Hall-Petch Effect—Factor Artifact?” Structure and Mechanical Properties of Nanophase Materials—Theory and Computer Simulations vs. Experiments (Warrendale, PA, MRS, 2001), ID#37343.
R.Z. Valiev, R.K. Islamgaliev, and I.V. Alexandrov, “Bulk Nanostructured Materials from Severe Plastic Deformation,” Prog. Mater. Sci., 45 (2000), pp. 103–189.
D.B. Witkin and E.J. Lavernia, “Synthesis and Mechanical Behavior of Nanostructured Materials via Cryomilling,” Prog. Mater. Sci., 51 (2006), pp. 1–60.
K.S. Kumar, H. Van Swygenhoven, and S. Suresh, “Mechanical Behavior of Nanocrystalline Metals and Alloys,” Acta Mater., 51 (2003), pp. 5743–5774.
Q. Wei et al., “Evolution and Microstructure of Shear Bands in Nanostructured Fe” Appl. Phys. Lett., 81 (7) (2002), pp. 1240–1242.
Q. Wei et al., “Microstructure and Mechanical Properties of Tantalum after Equal Channel Angular Extrusion (ECAE),” Mater Sci. Eng. A, 358 (1–2) (2003), pp. 266–272.
Q. Wei et al., “Adiabatic Shear Banding in Ultrafine Grained Fe Processed by Severe Plastic Deformation,” Acta Mater. 52 (7) (2004), pp. 1859–1869.
Q. Wei et al., “Nano-Structured Vanadium: Processing and Mechanical Properties under Quasi-Static and Dynamic Compression,” Scripta Materialia, 50 (3) (2004), pp. 359–364.
Q. Wei et al., “Effect of Nanocrystalline and Ultrafine Grain Sizes on the Strain Rate Sensitivity and Activation Volume: fcc versus bcc Metals,” Mater. Sci. Eng. A, 381 (1–2) (2004), pp. 71–79.
Y.J. Wei and L. Anand, “Grain Boundary Sliding and Separation in Polycrystalline Metals: Application to Nanocrystalline fcc Metals,” J. Mechanics and Physics of Solids, 52 (2004), pp. 2584–2616.
Q. Wei et al., “Plastic Flow Localization in Bulk-Tungsten with Ultrafine Microstructure,” Appl. Phys. Lett., 86 (10) (2005), p. 101907.
Q. Wei et al., “Mechanical Behavior and Dynamic Failure of High-Strength Ultrafine Grained Tungsten under Uniaxial Compression,” Acta Mater., 54 (1) (2006), pp. 77–87.
T.R. Malow and C.C. Koch, “Mechanical Properties in Tension of Mechanically Attrited Nanocrystalline Iron by the Use of Miniaturized Disk Bend Test,” Acta Mater., 46 (18) (1998), pp. 6459–6473.
T.R. Malow et al., “Compressive Mechanical Behavior of Nanocrystalline Fe Investigated with an Automated Ball Indentation Technique,” Mater. Sci. Eng. A., 252 (1998), pp. 36–43.
J.E. Carsley et al., “Mechanical Behavior of Bulk Nanostructured Iron Alloy,” Metall. Mater. Trans. A, 29A (1998), pp. 2261–2271.
D. Jia, K.T. Ramesh, and E. Ma, “Failure Mode and Dynamic Behavior of Nanophase Iron under Compression,” Scripta Mater., 42 (2000), pp. 73–78.
D. Jia, K.T. Ramesh, and E. Ma, “Effects of Nano-crystalline and Ultrafine Grain Sizes on Constitutive Behavior and Shear Bands in Iron,” Acta Mater., 51 (2), (2003), pp. 3495–3590.
L.S. Magness, “An Overview of the Penetration Performances of Tungsten and Depleted Uranium Alloy Penetrators: Ballistic Performances and Metallographic Examinations, Ballistics 2000 (Lancaster, PA: DEStech Publications Inc., 2002), CD-ROM.
E. Lassner and W.-D. Schubert, Tungsten-Properties, Chemistry, Technology of the Element, Alloys and Chemical Compounds (Dordrecht, the Netherlands: Kluwer-Academic/Plenum Publishers, 1998).
B.C. Allen, D.J. Maykuth, and R.I. Jaffee, “The Recrystallization and Ductile-Brittle Transition Behavior of Tungsten,” J. Institute of Metals, 90 (1961), pp. 120–128.
Q. Wei et al., “Microstructure and Mechanical Properties of Super-Strong Nanocrystalline Tungsten Processed by High-Pressure Torision” Acta Mater., 54 (2006), in press.
A.P. Zhilyaev et al., “Experimental Parameters Influencing Grain Refinement and Microstructural Evolution during High-Pressure Torsion,” Acta Mater., 51 (2003), pp. 753–765.
P.S. Follansbee, “High Strain Rate Compression Testing,” ASM Metals Handbook (Metals Park, OH, American Society of Metals, 1985), p. 190.
D. Jia and K.T. Ramesh, “A Rigo rous Assessment of the Benefits of Miniaturization in the Kolsky Bar System” Experimental Mechanics, 44 (5) (2004), pp. 445–454.
R.Z. Valiev, V.Y. Gertsman, and R. Kaibyshev, “Grain Boundary Structure and Properties under External Influence,” Physica Status Solidi A, 97 (1986), pp. 11–56.
R.Z. Valiev, “Nanomaterial Advantage,” Nature, 419 (2002), pp. 887–889.
A.A. Nazarov, A.E. Romanov, and R.Z. Valiev, “On the Structure, Stress Fields and Energy of Nonequilibrium Grain Boundaries,” Acta Metall. Mater., 41 (4) (1993), pp. 1033–1040.
J.W. Christian, “Some Surprising Features of the Plastic-Deformation of Body-Centered Cubic Metals and Alloys,” Metall. Trans. A, 14A (1983), p. 1237.
P.J. Blau, R.L. Martin, and E.S. Zanoria, “Effects of Surface Grinding Conditions on the Reciprocating Friction and Wear Behavior of Silicon Nitride,” Wear, 203 (1997), pp. 648–657.
D. Tabor, The Hardness of Metals, (Oxford, U.K.: Clarendon Press, 1951).
A.M. Lennon and K.T. Ramesh, “The Thermoviscoplastic Response of Polycrystalline Tungsten in Compression,” Mater. Sci. Eng. A., 276 (2000), pp. 9–21.
A.S. Argon and S.R. Maloof, “Plastic Deformation of Tungsten Single Crystals at Low Temperature,” Acta Metallurgica, 14 (1966), pp. 1449–1462.
T. Watanabe, “An Approach to Grain Boundary Design for Strong and Ductile Polycrystals,” Res. Mechanica, 11 (1984), pp. 47–84.
R.Z. Valiev et al., “Paradox of Strength and Ductility in Metals Processed by Severe Plastic Deformation” J. Mater. Res., 17 (1) (2002), pp. 5–8.
P. Gumbsch et al., “Controlling Factors for the Brittleto-Ductile Transition in Tungsten Single Crystals,” Science, 282 (5392) (1998), pp. 1293–1295.
T.W. Wright, The Physics and Mathematics of Adiabatic Shear Bands (Oxford, U.K.: Cambridge Press, 2002).
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Wei, Q., Ramesh, K.T., Schuster, B.E. et al. Nanoengineering opens a new era for tungsten as well. JOM 58, 40–44 (2006). https://doi.org/10.1007/s11837-006-0081-1
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DOI: https://doi.org/10.1007/s11837-006-0081-1