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Polymer nanocomposites: A small part of the story

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Abstract

Polymer nanocomposites are polymer matrix composites in which the fillers are less than 100 nm in at least one dimension. These composites have exhibited extraordinarily interesting properties. A defining feature of polymer nanocomposites is that the small size of the fillers leads to a dramatic increase in interfacial area as compared to traditional composites. This interfacial area creates a significant volume fraction of interfacial polymer with properties different from the bulk polymer even at low loadings. The properties and structure of this interfacial region are not yet known quantitatively, presenting a challenge both for controlling and predicting the properties of polymer nanocomposites. This paper provides a brief overview of polymer nanocomposites with emphasis on the impact of the interfacial region.

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References

  1. A.M. Bueche, Journal of Polymer Science, 25 (1957), p. 139.

    Article  CAS  Google Scholar 

  2. M.W. Rowell et al., Applied Physics Letters, 88 (2006), p. 233506.

    Article  CAS  Google Scholar 

  3. E. Barna et al., Composites Part A: Applied Science and Manufacturing, 36(4) (2005), pp. 473–474.

    Article  CAS  Google Scholar 

  4. M.H.G. Wichmann et al., Engineering Fracture Mechanics, 73(116) (2006), p. 2346.

    Article  Google Scholar 

  5. N.-M. Park, T.-S. Kim, and S.-J. Park, Applied Physics Letters, 78(17) (2001), p. 2575.

    Article  ADS  CAS  Google Scholar 

  6. T.S. Liu et al., Macromolecules, 37 (2004), p. 7214

    Article  CAS  Google Scholar 

  7. Z. Xia et al., Acta Materialia, 52 (2004), p. 931.

    Article  CAS  Google Scholar 

  8. B.J. Ash, R.W. Siegel, and L.S. Schadler, Macromolecules, 37 (2004), p. 1358.

    Article  CAS  Google Scholar 

  9. W. Naous et al., Journal of Polymer Science, Part B: Polymer Physics, 44 (2006), p. 1466.

    Article  CAS  Google Scholar 

  10. M. Roy et al., J. Materials Science, in press 2006.

  11. D.L. Ma et al., Journal of Materials Research, 19 (2004), p. 857.

    Article  CAS  Google Scholar 

  12. E. Ritzhaupt-Kleissl et al., Materials Science and Engineering C, 26 (2006), p. 1067.

    Article  CAS  Google Scholar 

  13. P.M. Ajayan, P.V. Braun, and L.S. Schadler, Nanocomposite Science and Technology (Weinham, Germany: Wiley-VCH Verlag GmbH&Co. KgaA, 2003), Chapter 2.

    Google Scholar 

  14. M.Z. Rong, M.Q. Zhang, and W.H. Ruan, Materials Science and Technology, 22(7) (2006), pp. 787–796.

    Article  CAS  Google Scholar 

  15. H.D. Wagner and R.A. Vaia, Materials Today, 7(11) (2004), pp. 38–42.

    Article  CAS  Google Scholar 

  16. M. Roy et al., IEEE Transactions on Dielectrics and Electrical Insulation, 12(4) (2005), pp. 629–642.

    Article  CAS  Google Scholar 

  17. J.K. Nelson and J.C. Fothergill, Nanotechnology, 15 (2004), pp. 586–595.

    Article  ADS  CAS  Google Scholar 

  18. J.N. Coleman et al., Polymer, 47 (2006), pp. 8556–8561.

    Article  CAS  Google Scholar 

  19. F.H. Gojny et al., Comp. Sci. Tech., 65(15–16) (2005), p. 2300.

    Article  CAS  Google Scholar 

  20. J.D. Fidelus et al., Composites Part a—Applied Science and Manufacturing, 36(11) (2005), p. 1555.

    Article  CAS  Google Scholar 

  21. T. Ramanathan, H. Liu, and L. C. Brinson, J. Poly. Sci.: Polym. Phys., 43 (2005), pp. 2269–2279.

    Article  CAS  Google Scholar 

  22. S. Ruan, P. Gao, and T.X. Yu, Polymer, 47 (2006), pp. 1604–1611.

    Article  CAS  Google Scholar 

  23. P.C. Irwin et al., Proc. 26th International Power Modulator Symposium and 2004 High Voltage Workshop of IEEE (Piscataway, NJ: IEEE, 2004).

    Google Scholar 

  24. H. Yang et al., Journal of Polymer Science, Part B: Polymer Physics, in press (2006).

  25. Z. Xiao et al., Journal of Polymer Science Part B: Polymer Physics, 44(7) (2006), pp. 1084–1095.

    Article  CAS  Google Scholar 

  26. T. Desia, P. Keblinski, and S.K. Kumar, Journal of Chemical Physics, 122(13) (2005), p. 134910.

    Article  CAS  Google Scholar 

  27. K. Gautam and A. Dhinojwala, Macromolecules, 34 (2001), pp. 137–113.

    Article  CAS  Google Scholar 

  28. A. Eitan, “Nanotube Polymer Composites: Tailoring the Interface for Improved Mechanical Properties” (Ph. D., Thesis Rensselaer Polytechnic Institute, 2003).

  29. A.-J. Zhu and S.S. Sternstein, Macromolecules, 35(19) 2002, pp. 7262–7273.

    Article  CAS  Google Scholar 

  30. T.J. Lewis, IEEE Trans. Dielec. Elec. Insul., 11 (2004), pp. 739–755.

    Article  CAS  Google Scholar 

  31. K.E. Atkinson and C. Jones, Journal of Adhesion, 56(1–4) (1996), pp. 247–260.

    CAS  Google Scholar 

  32. Y. Kojima et al., J. Mater. Res., 8 (1993), pp. 1185–1189.

    ADS  CAS  Google Scholar 

  33. Frank-Dieter Kuchta et al., Mat. Res. Soc. Symp. Proc., 576 (1999), pp. 363–368.

    CAS  Google Scholar 

  34. P. Bhimaraj et al., submitted to Wear (2006).

  35. D.L. Burris et al., Tribology of Polymeric Nanocomposites: Friction and Wear and Bulk Materials and Coatings, ed. K. Friedrich (New York: Elsevier, 2007 [in press]).

    Google Scholar 

  36. P. Bhimaraj et al., unpublished work (2003).

  37. P. Bhimaraj “Wear Behavior of Nanopartricle-filled Polyethylene Terephthalate” (Ph.D. Thesis, Rensselaer Polytechnic Institute, 2004).

  38. C.J. Ellison and J.M. Torkelson, Nature Materials, 2 (2003), p. 695.

    Article  PubMed  ADS  CAS  Google Scholar 

  39. A. Bansal et al., J. Polymer Science, Part B. Polymer Physics, 44(20) (2006), pp. 2944–2950.

    Article  CAS  Google Scholar 

  40. A. Eitan et al., J. Composite Science and Technology, 66(9) (2006), pp. 1159–1170.

    Google Scholar 

  41. B.J. Ash, L.S. Schadler, and R.W. Siegel, Materials Letters, 55(1–2) (2002), pp. 83–87.

    Article  CAS  Google Scholar 

  42. C. Becker, H. Krug, and H. Schmidt, Mat. Res. Soc. Symp. Proc., 435 (1996), p. 237.

    CAS  Google Scholar 

  43. J.A. Forrest and J. Mattsson, Physical Review E, 61 (2000), p. R53.

    Article  ADS  CAS  Google Scholar 

  44. P. Xiao, M. Xiao, and K. Gong, Polymer, 42 (2001), pp. 4813–4816.

    Article  CAS  Google Scholar 

  45. D.H. Droste and A.T. Dibenedetto, Journal of Applied Polymer Science, 13 (1968), p. 2149.

    Article  Google Scholar 

  46. L.S. Schadler et al., MRS Bulletin, in press (2007).

  47. H.D. Wagner, O. Lourie, and X.-F. Zhou, Composites: Part A, 30 (1999), pp. 59–66.

    Article  Google Scholar 

  48. Asa H. Barber et al., Advanced Materials, 18 (2006), pp. 83–87.

    Article  CAS  MathSciNet  Google Scholar 

  49. F.T. Fisher and L.C. Brinson, Handbook of Theoretical and Computational Nanoscience: Volume 8. Nanomechanics of Nanoreinforced Polymers, ed. M. Rieth and W. Schommers (Valencia, CA: American Scientific Publishers, 2006), pp. 253–360.

    Google Scholar 

  50. G.D. Smith et al., J. Chem. Phys., 117(20) (2002), p. 9478.

    Article  ADS  CAS  Google Scholar 

  51. F.W. Starr, T.B. Schroder, and S.C. Glotzer, Macromolecules, 35(11) (2002), p. 4481.

    Article  CAS  Google Scholar 

  52. T. Desai, P. Keblinski, and S.K. Kumar, Journal of Chemical Physics, 122(13) (2005), p. 134910.

    Article  PubMed  CAS  Google Scholar 

  53. V.A. Harmandaris, K.C. Daoulas, and V.G. Mavrantzas, Macromolecules, 38(13) (2005), p. 5796.

    Article  CAS  Google Scholar 

  54. E.K. Lin, W.I. Wu, and S.K. Satija, Macromolecules, 30(23) (1997), p. 7224.

    Article  CAS  Google Scholar 

  55. T. Desai et al., Journal of Chemical Physics, 124(8) (2006), p. 084904.

    Article  PubMed  CAS  Google Scholar 

  56. F.T. Fisher, R.D. Bradshaw, and L.C. Brinson, Applied Physics Letters, 80(24) (2002), p. 4647.

    Article  ADS  CAS  Google Scholar 

  57. F.T. Fisher, R.D. Bradshaw, and L.C. Brinson, Composite Science and Technology, 63(11) (2003), p. 1689.

    Article  CAS  Google Scholar 

  58. N. Sheng et al., Polymer, 45(2) (2004), p. 487.

    Article  CAS  Google Scholar 

  59. H. Liu and L.C. Brinson, Journal of Applied Mechanics-Transactions of the ASME, 73(5) (2006), p. 758.

    Article  MATH  CAS  Google Scholar 

  60. R.D. Bradshaw, F.T. Fisher, and L.C. Brinson, Composite Science and Technology, 63(11) (2003), p. 1705.

    Article  CAS  Google Scholar 

  61. F.T. Fisher, “Nanomechanics and the Viscoelastic Behavior of Carbon Nanotube-reinforced Polymers” (Ph.D. thesis, Northwestern University, 2002).

  62. H. Liu and L.C. Brinson, Journal of Applied Mechanics-Transactions of the ASME, 73(5) (2006), p. 758.

    Article  MATH  CAS  Google Scholar 

  63. G.M. Odegard et al., Composite Science and Technology, 62(14) (2002), p. 1869.

    Article  CAS  Google Scholar 

  64. G.M. Odegard et al., Composite Science and Technology, 63(11) (2003), p. 1671.

    Article  CAS  Google Scholar 

  65. G.M. Odegard, T.C. Clancy, and T.S. Gates, Polymer, 46(2) (2005), p. 553.

    Article  CAS  Google Scholar 

  66. C.Y. Li and T.W. Chou, Journal of Nanoscience and Nanotechnology, 3(5) (2003), p. 423.

    Article  PubMed  CAS  Google Scholar 

  67. S.J.V. Frankland and V.M. Harik, Surface Science, 525(1–3) (2003), p. L103.

    Article  CAS  Google Scholar 

  68. M. Wong et al., Polymer, 44(25) (2003), p. 7757.

    Article  CAS  Google Scholar 

  69. X. Chen, I.J. Beyerlein, and L.C. Brinson, Mechanics of Materials, to be submitted 2007.

  70. S.W. Xhang, Tribology International, 31 (1998), pp. 49–56.

    Article  Google Scholar 

  71. D.L. Burris and W.G. Sawyer, Wear, 260(7–8) (2006), pp. 915–918.

    Article  CAS  Google Scholar 

  72. D.L. Burris and W.G. Sawyer, Tribology Transactions, 48(2) (2005), pp. 147–153.

    Article  CAS  Google Scholar 

  73. W.G. Sawyer et al., Wear, 254(5–6) (2003), pp. 573–580.

    CAS  Google Scholar 

  74. E.S. Clark, Polymer, 40(16) (1999), p. 4659.

    Article  CAS  Google Scholar 

  75. E.N. Brown and D.M. Dattelbaum, Polymer, 46 (2005), pp. 3056–3068.

    Article  CAS  Google Scholar 

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Schadler, L.S., Brinson, L.C. & Sawyer, W.G. Polymer nanocomposites: A small part of the story. JOM 59, 53–60 (2007). https://doi.org/10.1007/s11837-007-0040-5

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