Abstract
Production of ultrahigh-manganese steels is expected to result in significant increase in demand for low-carbon (LC) ferromanganese (FeMn) and silicomanganese (SiMn). Current manganese processing techniques are energy intensive and typically yield a high-carbon product. The present work therefore reviews available literature regarding carbothermic reduction of Mn oxides and ores, with the objective of identifying opportunities for future process development to mitigate the cost of LC FeMn and SiMn. In general, there is consensus that carbothermic reduction of Mn oxides and ores is limited by gasification of carbon. Conditions which enhance or bypass this step (e.g., by application of CH4) show higher rates of reduction at lower temperatures. This phenomenon has potential application in solid-state reduction of Mn ore. Other avenues for process development include optimization of the prereduction step in conventional FeMn production and metallothermic reduction as a secondary reduction step.
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References
R. Elliott, K. Coley, S. Mostaghel, and M. Barati, JOM (2018). https://doi.org/10.1007/s11837-018-2769-4.
G.J.W. Kor, Metall. Trans. B 9B, 307 (1978).
W.J. Rankin and J.S.J. van Deventer, J. South Afr. Inst. Min. Metall. 2, 239 (1980).
J.S.J. van Deventer, Thermochim. Acta 112, 365 (1987).
J.S.J. van Deventer, Thermochim. Acta 125, 107 (1988).
M.A. Reuter and J.S.J. van Deventer, Thermochim. Acta 125, 99 (1988).
K. Terayama and M. Ikeda, Trans. Jpn. Inst. Metals 26, 108 (1985).
R. Kononov, O. Ostrovski, and S. Ganguly, Metall. Mater. Trans. B 39, 662 (2008).
H.K. Shin, B.D. Lee, H.S. Lee, and Y.E. Lee, in Conference paper from the Thirteenth International Ferroalloys Congress (Almaty, Kazakhstan, 2013).
C.H. Eom and D.J. Min, Met. Mater. Int. 22, 129 (2016).
D. Kim and S. Jung, ISIJ Int. 56, 71 (2016).
W.D. Grimsley, J.B. See, and R.P. King, J. South Afr. Inst. Min. Metall. 78, 51 (1977).
R.H. Eric and E. Burucu, Miner. Eng. 5, 795 (1992).
G. Akdogan and R.H. Eric, Miner. Eng. 7, 633 (1994).
G. Akdogan and R.H. Eric, Metall. Mater. Trans. B 26, 13 (1995).
O.I. Ostrovski and T.J.M. Webb, ISIJ Int. 35, 331 (1995).
M. Yastreboff, O. Ostrovski, and S. Ganguly, ISIJ Int. 43, 161 (2003).
M. Kumar, S. Ranganathan, and S.N. Sinha, in INFACON XI (2007), pp. 241–246.
R.S. Braga, C. Takano, and M.B. Mourão, Ironmak. Steelmak. 34, 279 (2007).
R. Kononov, O. Ostrovski, and S. Ganguly, in INFACON XI (New Delhi, India, 2007), pp. 256–267.
K. Ohler-Martins and D. Senk, Steel Res. Int. 79, 811 (2008).
R. Kononov, O. Ostrovski, and S. Ganguly, ISIJ Int. 49, 1099 (2009).
R. Kononov, O. Ostrovski, and S. Ganguly, ISIJ Int. 49, 1107 (2009).
R. Kononov, O. Ostrovski, and S. Ganguly, ISIJ Int. 49, 1115 (2009).
K.S. Abdel Halim, M. Bahgat, M.B. Morsi, and K. El-Barawy, Ironmak. Steelmak. 38, 279 (2011).
W.J. Rankin and J.R. Wynnyckyj, Metall. Mater. Trans. B 28, 307 (1997).
E.T. Turkdogan and J.V. Vinters, Carbon N. Y. 7, 101 (1969).
R.H. Tien and E.T. Turkdogan, Carbon N. Y. 8, 607 (1970).
K. Terayama and T. Shimazaki, Netsu Sokutei 27, 13 (1999).
N. Anacleto, O. Ostrovski, and S. Ganguly, ISIJ Int. 44, 1480 (2004).
N. Anacleto, O. Ostrovski, and S. Ganguly, ISIJ Int. 44, 1615 (2004).
A. Bhalla, and R.H. Eric, in 14th International Ferroalloys Congress (Kiev, Ukraine, 2015), pp. 461–469.
R.H. Eric, A. Bhalla, P. Halli, and P. Taskinen, in Applications of Process Engineering Principles in Materials Processing, Energy and Environmental Technologies (2017), pp. 307–318. https://doi.org/10.1007/978-3-319-51091-0_29.
O. Ostrovski and G. Zhang, AIChE J. 52, 300 (2006).
E.T. Turkdogan, V. Koump, J.V. Vinters, and T.F. Perzak, Carbon N. Y. 6, 467 (1968).
J.D. Blackwood and A.J. Ingeme, Aust. J. Chem. 13, 194 (1960).
T.F. Wall, G.S. Liu, H.W. Wu, D.G. Roberts, K.E. Benfell, S. Gupta, J.A. Lucas, and D.J. Harris, Prog. Energy Combust. Sci. 28, 405 (2002).
E.T. Turkdogan and J.V. Vinters, Carbon N. Y. 8, 39 (1970).
A. Koursaris, A.S.E. Kleyenstuber, and C.W.P. Finn, Spec. Publ. Geol. Soc. South Afr. 7, 375 (1983).
A. Koursaris and J.B. See, J. South Afr. Inst. Min. Metall. 79, 149 (1979).
A. Koursaris and J. See, J. South. Afr. Inst. Min. Metall. 80, 229 (1980).
M. Tangstad, Manganese Ferroalloys Technology, 12th ed. (Amsterdam: Elsevier, 2013).
T.-A. Skjervheim and S.E. Olsen, in INFACON 7 (1995), pp. 631–640.
W. Ding and S.E. Olsen, ISIJ Int. 40, 850 (2000).
S. Gaal, K. Berg, G. Tranell, S.E. Olsen, and M. Tangstad, in VII International Conference on Molten Slags, Fluxes and Salts (2004), p. 651.
J. Safarian, O. Grong, L. Kolbeinsen, and S.E. Olsen, ISIJ Int. 46, 1120 (2006).
J. Safarian, G. Tranell, L. Kolbeinsen, M. Tangstad, S. Gaal, and J. Kaczorowski, Metall. Mater. Trans. B 39, 702 (2008).
J. Safarian and L. Kolbeinsen, ISIJ Int. 48, 395 (2008).
J. Safarian, L. Kolbeinsen, M. Tangstad, and G. Tranell, Metall. Mater. Trans. B Process. Metall. Mater. Process. Sci. 40, 929 (2009).
E. Ringdalen, S. Gaal, M. Tangstad, and O. Ostrovski, Metall. Mater. Trans. B 41, 1220 (2010).
H. Sun, M.Y. Lone, S. Ganguly, and O. Ostrovski, ISIJ Int. 50, 639 (2010).
A. Blagus, J.R. Dankwah, and V. Sahajwalla, ISIJ Int. 53, 41 (2013).
M. Zaki, M. Hasan, L. Pasupulety, and K. Kumari, Thermochim. Acta 311, 97 (1998).
P. Perreault and G.S. Patience, Chem. Eng. J. 295, 227 (2016).
A.A. El-Geassy, M.I. Nasr, M.A. Yousef, M.H. Khedr, and M. Bahgat, Ironmak. Steelmak. 27, 117 (2000).
Y. Gao, M. Olivas-Martinez, H.Y. Sohn, H.G. Kim, and C.W. Kim, Metall. Mater. Trans. B 43, 1 (2012).
Y.B. Gao, H.G. Kim, and H.Y. Sohn, Trans. Inst. Min. Metall. Sect. C Miner. Process. Extr. Metall. 121, 109 (2012).
K. Turkova, D. Slizovskiy, and M. Tangstad, ISIJ Int. 54, 1204 (2014).
K.L. Berg and S.E. Olsen, Metall. Mater. Trans. B 31, 477 (2000).
R.J. Ishak and T. Lindstad, in Yazawa International Symposium on Metallurgical and Materials Processing: Principles and Technologies (2003), pp. 63–73.
M. Tangstad, M. Sibony, S. Wasb, and R. Tronstad, in INFACON 9 (2001), pp. 202–207.
H.H.A. El-Gawad, M.M. Ahmed, N.A. El-Hussiny, and M.E.H. Shalabi, OALib 1, 1 (2014).
A.M. Ahmed, A.A. El-Geassy, and M.L. Mishreky, Ironmak. Steelmak. 42, 161 (2015).
E.R. Stobbe, B.A. de Boer, and J.W. Geus, Catal. Today 47, 161 (1999).
B. Khoshandam, R.V. Kumar, and E. Jamshidi, Can. Metall. Q. 46, 365 (2007).
O. Ostrovski, N. Anacleto, and S. Ganguly, in Proceedings of the 10th International Ferroalloys Congress (2004), p. 173.
H.F. Abbas and W.M.A. Wan, Daud. Int. J. Hydrogen Energy 35, 1160 (2010).
A. Abánades, E. Ruiz, E.M. Ferruelo, F. Hernández, A. Cabanillas, J.M. Martínez-Val, J.A. Rubio, C. López, R. Gavela, G. Barrera, C. Rubbia, D. Salmieri, E. Rodilla, and D. Gutiérrez, Int. J. Hydrogen Energy 36, 12877 (2011).
A.M. Dunker and J.P. Ortmann, Int. J. Hydrogen Energy 31, 1989 (2006).
D.B. Wellbeloved, P.M. Craven, and J.W. Waudby, Ullmann’s Encycl. Ind. Chem. (2000). https://doi.org/10.1002/14356007.a16_077.
R. Kavitha and J.R. McDermid, Surf. Coat. Technol. 212, 152 (2012).
P. Petrov, M. Marinov, and R. Paunova, J. Univ. Chem. Technol. Metall. 45, 431 (2010).
H. Sarangi, B. Sarangi, and A. Ray, ISIJ Int. 36, 35 (1996).
J.T. Torres, A.F. Valdés, and J.M.A. Robles, Mater. Today Proc. 2, 4963 (2015).
B. Jamieson and K. Coley, Metall. Mater. Trans. B, 48, 1613 (2017). https://doi.org/10.1007/s11663-017-0967-z.
W.L. Daines and R.D. Pehlke, Trans. Met. Soc. AIME 242, 565 (1968).
E. Shibata, H. Sun, and K. Mori, Metall. Mater. Trans. B 30, 279 (1999).
J.H. Heo, Y. Chung, and J.H. Park, Metall. Mater. Trans. B 46, 1154 (2015).
H. Sohn, Z. Chen, and W. Jung, Steel Res. 71, 145 (2000).
Acknowledgements
The authors gratefully acknowledge financial support from the Natural Science and Engineering Research Council of Canada (NSERC, STPGP463252-14). Additional thanks go to ArcelorMittal Dofasco, Stelco, Praxair, and Hatch Ltd. for in-kind support and technical expertise.
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Elliott, R., Coley, K., Mostaghel, S. et al. Review of Manganese Processing for Production of TRIP/TWIP Steels, Part 2: Reduction Studies. JOM 70, 691–699 (2018). https://doi.org/10.1007/s11837-018-2773-8
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DOI: https://doi.org/10.1007/s11837-018-2773-8