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Journal of Coatings Technology and Research
Erschienen in: Journal of Coatings Technology and Research 3/2012

01.05.2012

The effect of formulation variables on fouling-release performance of stratified siloxane–polyurethane coatings

verfasst von: Rajan B. Bodkhe, Stephanie E. M. Thompson, Carolyn Yehle, Nicholas Cilz, Justin Daniels, Shane J. Stafslien, Maureen E. Callow, James A. Callow, Dean C. Webster

Erschienen in: Journal of Coatings Technology and Research | Ausgabe 3/2012

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Abstract

The effects of formulation variables, such as type of polyol, solvent type and solvent content, and coating application method, on the surface properties of siloxane–polyurethane fouling-release coatings were explored. Fouling-release coatings allow the easy removal of marine organisms from a ship’s hull via the application of a shear force to the surface. Self-stratified siloxane–polyurethane coatings are a new approach to a tough fouling-release coating system. Combinatorial High Throughput Experimentation was employed to formulate and characterize 24 different siloxane–polyurethane coatings applied using drawdown and drop-casting methods. The resulting coatings were tested for surface energy using contact angle measurements. The fouling-release performance of the coatings was tested using a number of diverse marine organisms including bacteria (Halomonas pacifica and Cytophaga lytica), sporelings (young plants) of the green macroalga (Ulva linza), diatom ((microalga) Navicula incerta), and barnacle (Amphibalanus amphitrite). The performance of the majority of the coatings was found to be better than the silicone standards, Intersleek® and Silastic® T2. An increase in solvent content in the formulations increased the surface roughness of the coatings. Coatings made with polycaprolactone polyol appeared to be somewhat rougher compared to coatings made with the acrylic polyol. The adhesion strength of sporelings of Ulva increased with an increase in solvent content and increase in surface roughness. The adhesion strengths of Ulva sporelings, C. lytica, and N. incerta were independent of application method (cast or drawdown) in contrast to H. pacifica adhesion, which was dependent on the application method.
Nächster Artikel Critical role of particle/polymer interface in photostability of nano-filled polymeric coatings

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Literatur
1.
Yebra, DM, Kiil, S, Dam-Johansen, K, “Antifouling Technology-Past, Present and Future Steps towards Efficient and Environmentally Friendly Antifouling Coatings.” Prog. Org. Coat., 50 75–104 (2004)CrossRef
2.
Callow, ME, “Ship Fouling: Problems and Solutions.” Chem. Ind., 5 123–127 (1990)
3.
Callow, ME, Callow, JE, “Marine Biofouling: A Sticky Problem.” Biologist, 49 10–14 (2002)
4.
Schultz, MP, Bendick, JA, Holm, ER, Hertel, WM, “Economic Impact of Biofouling on a Naval Surface Ship.” Biofouling, 27 87–98 (2011)CrossRef
5.
Piola, RF, Dafforn, KA, Johnston, EL, “The Influence of Antifouling Practices on Marine Invasions.” Biofouling, 25 633–644 (2009)CrossRef
6.
Yamaguchi, T, Prabowo, RE, Ohshiro, Y, Shimono, T, Jones, D, Kawai, H, Otani, M, Oshino, A, Inagawa, S, Akaya, T, Tamura, I, “The Introduction to Japan of the Titan Barnacle, Megabalanus coccopoma (Darwin 1854) (Cirripedia: Balanomorpha) and the Role of Shipping in its Translocation.” Biofouling, 25 325–333 (2009)CrossRef
7.
Hopkins, GA, Forrest, BM, “A Preliminary Assessment of Biofouling and Non-Indigenous Marine Species Associated with Commercial Slow-Moving Vessels Arriving in New Zealand.” Biofouling, 26 613–621 (2010)CrossRef
8.
Kavanagh, CJ, Quinn, RD, Swain, GW, “Observations of Barnacle Detachment from Silicones Using High-Speed Video.” J. Adhes., 81 843–868 (2005)CrossRef
9.
Bullock, S, Johnston, EE, Willson, T, Gatenholm, P, Wynne, KJ, “Surface Science of a Filled Polydimethylsiloxane-Based Alkoxysilane-Cured Elastomer: RTV11.” J. Colloid Interf. Sci., 210 18–36 (1999)CrossRef
10.
Brady, RF, “Properties Which Influence Marine Fouling Resistance in Polymers Containing Silicon and Fluorine.” Prog. Org. Coat., 35 31–35 (1999)CrossRef
11.
Brady, RF, “A Fracture Mechanical Analysis of Fouling Release from Nontoxic Antifouling Coatings.” Prog. Org. Coat., 43 188–192 (2001)CrossRef
12.
Kohl, JG, Singer, IL, “Pull-off Behavior of Epoxy Bonded to Silicone Duplex Coatings.” Prog. Org. Coat., 36 15–20 (1999)CrossRef
13.
Adkins, JD, Mera, AE, Roe-Short, MA, Pawlikowski, GT, Brady, RF, “Novel Non-Toxic Coatings Designed to Resist Marine Fouling.” Prog. Org. Coat., 29 1–5 (1996)CrossRef
14.
Finnie, A, Williams, DN, “Paint and Coatings Technology for the Control of Marine Fouling.” In: Durr, S, Thomason, JC (eds.) Biofouling, p. 429. Wiley–Blackwell, Chichester, 2010
15.
Ekin, A, Webster, DC, Daniels, JW, Stafslien, SJ, Casse, F, Callow, JA, Callow, ME, “Synthesis, Formulation and Characterization of Siloxane–Polyurethane Coatings for Underwater Marine Applications Using Combinatorial High-Throughput Experimentation.” J. Coat. Technol. Res., 4 435–451 (2007)CrossRef
16.
Majumdar, P, Webster, DC, “High-Throughput Combinatorial Characterization of Thermosetting Siloxane–Urethane Coatings Having Spontaneously Formed Microtopographical Surfaces.” J. Coat. Technol. Res., 4 131–138 (2007)CrossRef
17.
Sommer, S, Ekin, A, Webster, DC, Daniels, JW, Stafslien, SJ, Vander Wal, L, Thompson, SEM, Callow, ME, Callow, JA, “A Preliminary Study on the Properties and Fouling-Release Performance of Siloxane–Polyurethane Coatings Prepared from PDMS Macromers.” Biofouling, 26 961–972 (2010)CrossRef
18.
Ekin, A, Webster, DC, “Library Synthesis and Characterization of 3-Aminopropyl-Terminated Poly(dimethylsiloxane)s and Poly(ε-caprolactone)-b-poly(dimethylsiloxane)s.” J. Polym. Sci. Part A: Polym. Chem., 44 4880–4894 (2006)CrossRef
19.
Ekin, A, Webster, DC, “Synthesis and Characterization of Novel Hydroxyalkyl Carbamate and Dihydroxyalkyl Carbamate Terminated Poly(dimethylsiloxane) Oligomers and Their Block Copolymers with Poly(ε-caprolactone).” Macromolecules, 39 8659–8668 (2006)CrossRef
20.
Ekin, A, Webster, DC, “Combinatorial and High-Throughput Screening of the Effect of Siloxane Composition on the Surface Properties of Crosslinked Siloxane–Polyurethane Coatings.” J. Comb. Chem., 9 178–188 (2007)CrossRef
21.
Pieper, RJ, Ekin, A, Webster, DC, Casse, F, Callow, JA, Callow, ME, “A Combinatorial Approach to Study the Effect of Acrylic Polyol Composition on the Properties of Crosslinked Siloxane–Polyurethane Fouling-Release Coatings.” J. Coat. Technol. Res., 4 453–461 (2007)CrossRef
22.
Bodkhe, RB, Thompson, SEM, Callow, ME, Callow, JA, Webster, DC, “Effect of Siloxane Molecular Weight and Content on Fouling-Release Performance of Siloxane–Polyurethane Coatings Using Combinatorial High Throughput Methods.” PMSE Preprints, 99 376–377 (2008)
23.
Bodkhe, RB, Thompson, SEM, Callow, ME, Callow, JA, Webster, DC, Fouling-Release Performance of Siloxane–Polyurethane Coatings using Combinatorial High-Throughput Methods. Materials Research Society (MRS), San Francisco, CA, 2009
24.
Owens, DK, Wendt, RC, “Estimation of the Surface Free Energy of Polymers.” J. Appl. Polym. Sci., 13 1741–1747 (1969)CrossRef
25.
Chisholm, BJ, Webster, DC, Bennett, JC, Berry, M, Christianson, D, Kim, J, Mayo, B, Gubbins, N, “Combinatorial Materials Research Applied to the Development of New Surface Coatings VII: An Automated System for Adhesion Testing.” Rev. Sci. Instrum., 78 072213 (2007)CrossRef
26.
Webster, DC, Chisholm, BJ, Stafslien, SJ, “Mini-Review: Combinatorial Approaches for the Design of Novel Coatings systems.” Biofouling, 23 179–192 (2007)CrossRef
27.
Webster, DC, “Combinatorial and High Throughput Methods in Macromolecular Materials Research and Development.” Macromol. Chem. Phys., 209 237–246 (2008)CrossRef
28.
Webster, DC, Bennett, J, Kuebler, S, Kossuth, MB, Jonasdottir, S, “High Throughput Workflow for the Development of Coatings.” J. Coat. Technol., 1 34–39 (2004)
29.
Webster, DC, “Radical Change in Research and Development: The Shift from Conventional Methods to High Throughout Methods.” JCT CoatingsTech, 2(15) 24–29 (2005)
30.
Chisholm, BJ, Christianson, DA, Webster, DC, “Combinatorial Materials Research Applied to the Development of New Surface Coatings: II. Process Capability Analysis of the Coating Formulation Workflow.” Prog. Org. Coat., 57 115–122 (2006)CrossRef
31.
Chisholm, B, Potyrailo, R, Cawse, J, Shaffer, R, Brennan, M, Molaison, C, Whisenhunt, D, Flanagan, B, Olson, D, Akhave, J, Saunders, D, Mehrabi, A, Licon, M, “The Development of Combinatorial Chemistry Methods for Coating Development: I. Overview of the Experimental Factory.” Prog. Org. Coat., 45 313–321 (2002)CrossRef
32.
Nasrullah, MJ, Webster, DC, “Parallel Synthesis of Polymer Libraries Using Atom Transfer Radical Polymerization (ATRP).” Macromol. Chem. Phys., 210 640–650 (2009)CrossRef
33.
Chisholm, BJ, Potyrailo, RA, Cawse, JN, Shaffer, RE, Brennan, M, Molaison, CA, “Combinatorial Chemistry Methods for Coating Development: V. The Importance of Understanding Process Capability.” Prog. Org. Coat., 47 120–127 (2003)CrossRef
34.
Stafslien, SJ, Bahr, JA, Daniels, JW, Vander Wal, L, Nevins, J, Smith, J, Schiele, K, Chisholm, B, “Combinatorial Materials Research Applied to the Development of New Surface Coatings VI: An Automated Spinning Water Jet Apparatus For the High-Throughput Characterization of Fouling-Release Marine Coatings.” Rev. Sci. Instrum., 78 1–6 (2007)CrossRef
35.
Casse, F, Stafslien, SJ, Bahr, JA, Daniels, JW, Finlay, JA, Callow, ME, Callow, JA, “Combinatorial Materials Research Applied to the Development of New Surface Coatings V: Application of a Spinning Water-jet for the Semi-high Throughput Assessment of Attachment Strength of Marine Fouling Algae.” Biofouling, 23 121–130 (2007)CrossRef
36.
Stafslien, SJ, Daniels, JW, Mayo, B, Christianson, DA, Chisholm, BJ, Ekin, A, Webster, DC, Geoffrey, S, “Combinatorial Materials Research Applied to the Development of New Surface Coatings IV A High-Throughput Bacterial Biofilm Retention and Retraction Assay for Screening Fouling-Release Performance of Coatings.” Biofouling, 23 45–54 (2007)CrossRef
37.
Ribeiro, E, Stafslien, SJ, Cassé, F, Callow, JA, Callow, ME, Pieper, RJ, Daniels, JW, Bahr, JA, Webster, DC, “Automated Image-Based Method for Laboratory Screening of Coating Libraries for Adhesion of Algae and Bacterial Biofilms.” J. Comb. Chem., 10 586–594 (2008)CrossRef
38.
Rittschof, D, Orihuela, B, Stafslien, S, Daniels, J, Chisholm, B, Christianson, D, Holm, E, “Barnacle Reattachment: A Tool for Studying Barnacle Adhesion.” Biofouling, 24 1–9 (2008)CrossRef
39.
Bennett, SM, Finlay, JA, Gunari, N, Wells, DD, Meyer, AE, Walker, GC, Callow, ME, Callow, JA, Bright, FV, Detty, MR, “The Role of Surface Energy and Water Wettability in Aminoalkyl/Fluorocarbon/Hydrocarbon-Modified Xerogel Surfaces in the Control of Marine Biofouling.” Biofouling, 26 235–246 (2010)CrossRef
40.
Holland, R, Dugdale, TM, Wetherbee, R, Brennan, AB, Finlay, JA, Callow, JA, Callow, ME, “Adhesion and Motility of Fouling Diatoms on a Silicone Elastomers.” Biofouling, 20 323–329 (2004)CrossRef
41.
Peng, J, Yu, X, Hanfu, W, Yuming, Y, Binyao, L, Yanchun, H, “Solvent-Induced Microphase Separation in Diblock Copolymer Thin Films with Reversibly Switchable Morphology.” J. Chem. Phys., 120 11163–11170 (2004)CrossRef
42.
Yılgör, E, Yılgör, I, “Hydrogen Bonding: A Critical Parameter in Designing Silicone Copolymers.” Polymer, 42 7953–7959 (2001)CrossRef
43.
Ku, C, Lee, Y, “Microphase Separation in Amorphous Poly(imide siloxane) Segmented Copolymers.” Polymer, 48 3565–3573 (2007)CrossRef
44.
Stefanis, E, Panayioto, C, “Prediction of Hansen Solubility Parameters with a New Group-Contribution Method.” Int. J. Thermophys., 29 568–585 (2008)CrossRef
45.
Majumdar, P, Webster, DC, “Surface Microtopography in Siloxane–Polyurethane Thermosets: The Influence of Siloxane and Extent of Reaction.” Polymer, 48 7499–7509 (2007)CrossRef
46.
Pike, JK, Ho, T, Wynne, KJ, “Water-Induced Surface Rearrangements of Poly(dimethylsiloxane–urea–urethane) Segmented Block Copolymers.” Chem. Mater., 8 856–860 (1996)CrossRef
Metadaten
Titel
The effect of formulation variables on fouling-release performance of stratified siloxane–polyurethane coatings
verfasst von
Rajan B. Bodkhe
Stephanie E. M. Thompson
Carolyn Yehle
Nicholas Cilz
Justin Daniels
Shane J. Stafslien
Maureen E. Callow
James A. Callow
Dean C. Webster
Publikationsdatum
01.05.2012
Verlag
Springer US
Erschienen in
Journal of Coatings Technology and Research / Ausgabe 3/2012
Print ISSN: 1547-0091
Elektronische ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-011-9362-x

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