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Erschienen in: Journal of Coatings Technology and Research 3/2016

25.03.2016

Drying activity of oxovanadium(IV) 2-ethylhexanoate in solvent-borne alkyd paints

verfasst von: Ondřej Preininger, Jan Honzíček, Petr Kalenda, Jaromír Vinklárek

Erschienen in: Journal of Coatings Technology and Research | Ausgabe 3/2016

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Abstract

Oxovanadium(IV) 2-ethylhexanoate was established as a new primary drier for alkyd-based paints. A series of experiments has demonstrated an excellent drying activity toward solvent-borne alkyd resins of different oil length at considerably lower metal concentration than optimal for commercial cobalt(II) 2-ethylhexanoate. The behavior in real paint was simulated on formulations bearing inhibitor of autooxidation. The detailed studies of the drying process have shown that the relatively slow initial step of autooxidation reaction, when compared with cobalt compounds, is compensated for by the absence of the induction times. Furthermore, the active oxovanadium(IV) species are not consumed during the drying processes as evidenced by EPR spectroscopic measurements.

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Metadaten
Titel
Drying activity of oxovanadium(IV) 2-ethylhexanoate in solvent-borne alkyd paints
verfasst von
Ondřej Preininger
Jan Honzíček
Petr Kalenda
Jaromír Vinklárek
Publikationsdatum
25.03.2016
Verlag
Springer US
Erschienen in
Journal of Coatings Technology and Research / Ausgabe 3/2016
Print ISSN: 1547-0091
Elektronische ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-015-9779-8

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