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Erschienen in: Journal of Coatings Technology and Research 2/2017

25.01.2017

Effect of particle size distribution on stress development and microstructure of particulate coatings

verfasst von: Yan Wu, Lorraine F. Francis

Erschienen in: Journal of Coatings Technology and Research | Ausgabe 2/2017

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Abstract

The role of pigment particle size distribution on stress and microstructure development was studied for coatings prepared from aqueous suspensions of ground calcium carbonate (GCC) and latex binder. Stress development was monitored using a modified beam deflection technique under controlled environment. Microstructure was characterized by scanning electron microscopy (SEM) and cryogenic SEM. For coatings containing only GCC particles and no latex, a wide particle size distribution resulted in a significant particle size gradient in the cross-sectional microstructure and irregular stress development. With latex addition, uniform microstructures were observed in coatings with either wide or narrow GCC particle size distribution. GCC/latex coatings prepared using GCC with a wide particle size distribution developed a higher stress than those prepared using GCC with a similar average particle size but a narrow particle size distribution. The higher stress is related to the particle packing that results in smaller pore sizes and larger capillary pressures that drive compaction. In coatings prepared with the same GCC particles but different latex binders, the stress and cracking behavior of the coating depends on the latex properties.

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Metadaten
Titel
Effect of particle size distribution on stress development and microstructure of particulate coatings
verfasst von
Yan Wu
Lorraine F. Francis
Publikationsdatum
25.01.2017
Verlag
Springer US
Erschienen in
Journal of Coatings Technology and Research / Ausgabe 2/2017
Print ISSN: 1547-0091
Elektronische ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-016-9866-5

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