Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Coatings Technology and Research
Erschienen in: Journal of Coatings Technology and Research 5/2020

08.06.2020

A facile strategy to fabricate an intumescent fire-retardant coating with improved fire resistance and water tolerance for steel structure

verfasst von: Siqi Huo, Cheng Wang, Qinghua Hu, Shi Liu, Qi Zhang, Zhitian Liu

Erschienen in: Journal of Coatings Technology and Research | Ausgabe 5/2020

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

An intumescent fire-retardant coating (IFRC) with improved fire resistance and water tolerance was prepared in this work, resulting from the introduction of microcapsuled ammonium polyphosphate (MFAPP) and zinc borate (MFBZ). The as-prepared coating exhibited great fire resistance and smoke suppression. In the cone calorimetry test, adding only 6 wt% MFBZ dramatically reduced the peak heat release rate, total heat release, and total smoke release by ~ 23.4%, ~ 54.7%, and ~ 81.1%, respectively. In addition, the water resistance and thermal stability of the coatings were also characterized. The char yield of IFRC noticeably increased to 41.7%, indicating good high-temperature stability. Besides, the IFRC showed a water contact angle of 90.1° and maintained good structure and fire resistance after being soaked by water, indicating great water resistance. The enhanced performance portfolio was mainly due to the synergistic effects of ammonium polyphosphate, pentaerythritol, melamine, and zinc borate, and the hydrophobicity of melamine–formaldehyde resin (MF). This work offers an effective approach for the preparation of waterborne intumescent fire-retardant coatings with great fire resistance and water tolerance.

Graphic abstract

Vorheriger Artikel Sol–gel hybrid films based on organosilanes with long alkyl chains
Nächster Artikel UV-curable superhydrophobic organosilicon/silica hybrid coating on cotton fabric for oil–water separation

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Anhänge
Nur mit Berechtigung zugänglich
Literatur
1.
Jeyasubramanian, K, Muthusankar, E, Hikku, GS, Selvakumar, N, “Improved Thermal and Fire Retardant Behavior of Polyvinyl Alcohol Matrix Using Nanocomposites.” Int. J. Nanosci., 18 1850025 (2019)CrossRef
2.
Gao, Y, Wang, Q, Lin, W, “Ammonium Polyphosphate Intercalated Layered Double Hydroxide and Zinc Borate as Highly Efficient Flame Retardant Nanofillers for Polypropylene.” Polymers (Basel), 10 1114 (2018)CrossRef
3.
Shen, M-Y, Chen, W-J, Kuan, C-F, Kuan, H-C, Yang, J-M, Chiang, C-L, “Preparation, Characterization of Microencapsulated Ammonium Polyphosphate and Its Flame Retardancy in Polyurethane Composites.” Mater. Chem. Phys., 173 205–212 (2016)CrossRef
4.
Sarabandi, K, Jafari, SM, Mohammadi, M, Akbarbaglu, Z, Pezeshki, A, Khakbaz Heshmati M, “Production of Reconstitutable Nanoliposomes Loaded with Flaxseed Protein Hydrolysates: Stability and Characterization.” Food Hydrocoll., 96 442–450 (2019)CrossRef
5.
Yang, S, Wang, J, Huo, S, Cheng, L, Wang, M, “Preparation and Flame Retardancy of an Intumescent Flame-Retardant Epoxy Resin System Constructed by Multiple Flame-Retardant Compositions Containing Phosphorus and Nitrogen Heterocycle.” Polymer Degrad. Stab., 119 251–259 (2015)CrossRef
6.
Muhoza, B, Xia, S, Zhang, X, “Gelatin and High Methyl Pectin Coacervates Crosslinked with Tannic Acid: The Characterization, Rheological Properties, and Application for Peppermint Oil Microencapsulation.” Food Hydrocoll., 97 105174 (2019)CrossRef
7.
Liu, Z, Dai, M, Hu, Q, Liu, S, Gao, X, Ren, F, Zhang, Q, “Effect of Microencapsulated Ammonium Polyphosphate on the Durability and Fire Resistance of Waterborne Intumescent Fire-Retardant Coatings.” J. Coat. Technol. Res., 16 135–145 (2018)CrossRef
8.
You, Y-l, Liu, C-m, Li, D-x, Liu, S-j, He, G-w, “Tribological and Flame Retardant Modification of Polyamide-6 Composite.” J. Central South Univ., 26 88–97 (2019)CrossRef
9.
Gillani, QF, Ahmad, F, Abdul Mutalib, MI, Megat-Yusoff, PSM, Ullah, S, Messet, PJ, Zia-ul-Mustafa, M, “Thermal Degradation and Pyrolysis Analysis of Zinc Borate Reinforced Intumescent Fire Retardant Coatings.” Prog. Org. Coat., 123 82–98 (2018)CrossRef
10.
Jiang, X, Li, C, Chi, Y, Yan, J, “TG-FTIR Study on Urea-Formaldehyde Resin Residue During Pyrolysis and Combustion.” J. Hazard. Mater., 173 205–210 (2010)CrossRef
11.
Wei, H, Li, L, Ma, YL, Liu, RX, Meng, SY, Niu, LT, Zhang, Z, Yang, ZW, “A Facile Method for Preparation of PGS@ZB-N and Gas-Sol Alternating Synergistic Effect for Fire Resistance of EVA.” Fire Mater. 43 868–879 (2019)CrossRef
12.
Savas, LA, Dogan, M, “Flame Retardant Effect of Zinc Borate in Polyamide 6 Containing Aluminum Hypophosphite.” Polymer Degrad. Stab., 165 101–109 (2019)CrossRef
13.
Kumar, V, Balasubramanian, K, “Progress Update on Failure Mechanisms of Advanced Thermal Barrier Coatings: A Review.” Prog. Org. Coat., 90 54–82 (2016)CrossRef
14.
Yan, L, Xu, Z, Wang, X, “Synergistic Flame-Retardant and Smoke Suppression Effects of Zinc Borate in Transparent Intumescent Fire-Retardant Coatings Applied on Wood Substrates.” J. Therm. Anal. Calorim., 136 1563–1574 (2018)CrossRef
15.
Li, M, Liu, N, Li, Q, “A Novel Core-Shell Epoxy High Performance Composite: Self-Lubricating, Heat-Resistant and Self-Repairing.” Prog. Org. Coat., 129 217–228 (2019)CrossRef
16.
Contri, G, Barra, GMO, Ramoa, SDAS, Merlini, C, Ecco, LG, Souza, FS, Spinelli, A, “Epoxy Coating Based on Montmorillonite-Polypyrrole: Electrical Properties and Prospective Application on Corrosion Protection of Steel.” Prog. Org. Coat., 114 201–207 (2018)CrossRef
17.
Huo, S, Liu, Z, Wang, J, “Thermal Properties and Flame Retardancy of an Intumescent Flame-Retarded Epoxy System Containing Phosphaphenanthrene, Triazine-Trione and Piperidine.” J. Therm. Anal. Calorim., 139 1099–1110 (2020)
18.
Huo, S, Liu, Z, Li, C, Wang, X, Cai, H, Wang, J, “Synthesis of a Phosphaphenanthrene/Benzimidazole-Based Curing Agent and Its Application in Flame-Retardant Epoxy Resin.” Polymer Degrad. Stab., 163 100–109 (2019)CrossRef
19.
Liu, S, Wang, C, Hu, Q, Huo, S, Zhang, Q, Liu, Z, “Intumescent Fire Retardant Coating with Recycled Powder from Industrial Effluent Optimized Using Response Surface Methodology.” Prog. Org. Coat., 140 105494 (2020)CrossRef
20.
Islam, MR, Beg, MDH, Jamari, SS, “Dispersion of Montmorillonite Nanoclays and Their Effects on the Thermomechanical, Structural and Drying Properties of Palm Oil Based Coating.” Prog. Org. Coat., 91 17–24 (2016)CrossRef
21.
Huo, S, Wang, J, Yang, S, Zhang, B, Chen, X, Wu, Q, Yang, L, “Synthesis of a Novel Reactive Flame Retardant Containing Phosphaphenanthrene and Piperidine Groups and Its Application in Epoxy Resin.” Polymer Degrad. Stab., 146 250–259 (2017)CrossRef
22.
Yang, S, Zhang, Q, Hu, Y, “Synthesis of a Novel Flame Retardant Containing Phosphorus, Nitrogen and Boron and Its Application in Flame-Retardant Epoxy Resin.” Polymer Degrad. Stab., 133 358–366 (2016)CrossRef
23.
Yang, S, Wang, J, Huo, S, Wang, M, Cheng, L, “Synthesis of a Phosphorus/Nitrogen-Containing Additive with Multifunctional Groups and Its Flame-Retardant Effect in Epoxy Resin.” Ind. Eng. Chem. Res., 54 7777–7786 (2015)CrossRef
24.
Yang, S, Wang, J, Huo, S, Wang, M, Wang, J, Zhang, B, “Synergistic Flame-Retardant Effect of Expandable Graphite and Phosphorus-Containing Compounds for Epoxy Resin: Strong Bonding of Different Carbon Residues.” Polymer Degrad. Stab., 128 89–98 (2016)CrossRef
25.
Lu, X, Jiang, H, “Recent Progress of Seismic Research on Tall Buildings in China Mainland.” Earthq. Eng. Eng. Vib., 13 47–61 (2014)CrossRef
26.
Li, XB, “Technical Progress and Product Development of TISCO Stainless Steel.” 19–26 (2011)
27.
Huo, S, Wang, J, Yang, S, Wang, J, Zhang, B, Zhang, B, Chen, X, Tang, Y, “Synthesis of a Novel Phosphorus-Nitrogen Type Flame Retardant Composed of Maleimide, Triazine-Trione, and Phosphaphenanthrene and Its Flame Retardant Effect on Epoxy Resin.” Polymer Degrad. Stab., 131 106–113 (2016)CrossRef
28.
Chen, X, Jiang, Y, Jiao, C, “Smoke Suppression Properties of Ferrite Yellow on Flame Retardant Thermoplastic Polyurethane Based on Ammonium Polyphosphate.” J. Hazard Mater., 266 114–121 (2014)CrossRef
29.
Huo, S, Wang, J, Yang, S, Zhang, B, Tang, Y, “A Phosphorus-Containing Phenolic Derivative and Its Application in Benzoxazine Resins: Curing Behavior, Thermal, and Flammability Properties.” J. Appl. Polym. Sci., 133 (2016)
30.
Camargo, Á, Ibañez, CM, “Initial Study of Micronized Zinc Borate as Flame Retardant in Eucalyptus Grandis from Uruguay.” MRS Adv., 3 3551–3556 (2018)CrossRef
31.
Song, J, Huang, Z, Qin, Y, Li, X, “Thermal Decomposition and Ceramifying Process of Ceramifiable Silicone Rubber Composite with Hydrated Zinc Borate.” Materials, 12 1591 (2019)CrossRef
32.
Gao, Y, Liu, S, Wang, Q, Wang, G, “Preparation of Melamine-Formaldehyde Resin Grafted by (3-Aminopropyl) Triethoxysilane for High-Performance Hydrophobic Materials.” J. Appl. Polym. Sci., 137 48664 (2020)CrossRef
33.
Savas, LA, Dogan, M, “Flame Retardant Effect of Zinc Borate in Polyamide 6 Containing Aluminum Hypophosphite.” Polymer Degrad. Stab., 165 101–109 (2019)CrossRef
34.
Gao, C, Moya, S, Lichtenfeld, H, Casoli, A, Fiedler, H, Donath, E, Möhwald, H, “The Decomposition Process of Melamine Formaldehyde Cores: The Key Step in the Fabrication of Ultrathin Polyelectrolyte Multilayer Capsules.” Macromol. Mater. Eng., 286 355–361 (2001)CrossRef
35.
Huang, G, Huo, S, Xu, X, Chen, W, Jin, Y, Li, R, Song, P, Wang, H, “Realizing Simultaneous Improvements in Mechanical Strength, Flame Retardancy and Smoke Suppression of ABS Nanocomposites from Multifunctional Graphene.” Compos. B Eng., 177 107377 (2019)CrossRef
36.
Huo, S, Yang, S, Wang, J, Cheng, J, Zhang, Q, Hu, Y, Ding, G, Zhang, Q, Song, P, “A Liquid Phosphorus-Containing Imidazole Derivative as Flame-Retardant Curing Agent for Epoxy Resin with Enhanced Thermal Latency, Mechanical, and Flame-Retardant Performances.” J. Hazardous Mater., 386 121984 (2020)CrossRef
37.
Fang, F, Huo, S, Shen, H, Ran, S, Wang, H, Song, P, Fang, Z, “A Bio-based Ionic Complex with Different Oxidation States of Phosphorus for Reducing Flammability and Smoke Release of Epoxy Resins.” Compos. Commun. 17 104–108 (2020)CrossRef
38.
L Yan, Z Xu, X Wang, “Synergistic Flame-Retardant and Smoke Suppression Effects of Zinc Borate in Transparent Intumescent Fire-Retardant Coatings Applied on Wood Substrates.” J. Thermal Anal. Calorim., 136 1563–1574 (2018)CrossRef
39.
Kang, FR, Wang, CP, Deng, J, Yang, K, Ma, L, Pang, QT, “Flame Retardancy and Smoke Suppression of Silicone Foams with Microcapsulated Aluminum Hypophosphite and Zinc Borate” Polym. Adv. Technol., 31 654–664 (2020)CrossRef
Metadaten
Titel
A facile strategy to fabricate an intumescent fire-retardant coating with improved fire resistance and water tolerance for steel structure
verfasst von
Siqi Huo
Cheng Wang
Qinghua Hu
Shi Liu
Qi Zhang
Zhitian Liu
Publikationsdatum
08.06.2020
Verlag
Springer US
Erschienen in
Journal of Coatings Technology and Research / Ausgabe 5/2020
Print ISSN: 1547-0091
Elektronische ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-020-00360-1

Weitere Artikel der Ausgabe 5/2020

Journal of Coatings Technology and Research 5/2020 Zur Ausgabe

OriginalPaper

Sol–gel hybrid films based on organosilanes with long alkyl chains

OriginalPaper

Adapted synthesis routes and healing evaluation of a self-healing anticorrosive coating

OriginalPaper

Oxidovanadium(V) dithiocarbamates as driers for alkyd binders

OriginalPaper

Stretchable strain sensors based on conductive coating cracks with improved interfacial adhesion by wet phase separation treatment

OriginalPaper

UV-curable superhydrophobic organosilicon/silica hybrid coating on cotton fabric for oil–water separation

OriginalPaper

The effect of bicarbonate additive on corrosion resistance and microstructure characteristics of the zirconium-based conversion coating on carbon steel

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise