Conductivity studies of lithium zinc silicate glasses with varying lithium contents

Abstract

The electrical conductivity of lithium zinc silicate (LZS) glasses with composition, (SiO₂)_0.527 (Na₂O)_0.054(B₂O₃)_0.05(P₂O₅)_0.029(ZnO)_0.34−x (Li₂O) _x (x = 0.05, 0.08, 0.11, 0.18, 0.21, 0.24 and 0.27), was studied as a function of frequency in the range 100 Hz–15 MHz, over a temperature range from 546–637 K. The a.c. conductivity is found to obey Jonscher’s relation. The d.c. conductivity (σ _d.c.) and the hopping frequency (ω _h), inferred from the a.c. conductivity data, exhibit Arrhenius-type behaviour with temperature. The electrical modulus spectra show a single peak, indicating a single electrical relaxation time, τ, which also exhibits Arrhenius-type behaviour. Values of activation energy derived from σ _d.c., ω _h and τ are almost equal within the experimental error. It is seen that σ _d.c. and ω _h increase systematically with Li₂O content up to 21 mol% and then decrease for higher Li₂O content, indicating a mixed alkali effect caused by mobile Li⁺ and Na⁺ ions. The scaling behaviour of the modulus suggests that the relaxation process is independent of temperature but depends upon Li⁺ concentration.