Abstract
We have fabricated ∼143 nm Fe3O4 thin films on Si(100) substrates at 450°C and then annealed them at the same temperature for 30, 60 and 90 min under a vacuum of 10 − 6 torr with pulsed laser deposition. We studied the effects on the structural and magnetic properties of Fe3O4 thin films. The films have been characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and vibrating sample magnetometry (VSM). XRD studies showed pure single phase spinel cubic structure of Fe3O4 with a preferential [111] orientation, independent of substrate orientation at 90 min annealing. Higher magnetization was obtained up to 60 min annealing due to Fe phase but at 90 min, we obtained reduced magnetization of 335 emu/cc. This is attributed to the formation of antiphase boundaries between substrate and film.
Similar content being viewed by others
References
Brabers V A M 1995 Handbook of magnetic materials (ed) K H J Buschow (Amsterdam: Elsevier Science) Vol. 8
Coey J M D and Venkatesan M 2002 J. Appl. Phys. 91 8345
Dediu V, Arisi E, Bergenti I, Riminucci A, Solzi M, Pernechele C and Natali M 2007 J. Magn. Magn. Mater. 316 e721
Dong C 1999 J. Appl. Cryst. 32 838
Fabian Z J and Das Sarma S 2004 Rev. Mod. Phys. 76 323
Ferhat M and Yoh K 2007 Appl. Phys. Lett. 90 112501
Gong G Z, Gupta A, Xiao G, Qian W and Draivid V P 1997 Phys. Rev. B56 5096
Liu H, Jiang E Y, Bai H L, Zheng R K, Wei H L and Zhang X X 2003 Appl. Phys. Lett. 83 3531
Lochner E, Shaw K A, DiBari R C, Portwine W, Stoyanov P, Berry S D and Lind D M 1994 IEEE Trans. Magn. 30
Magulies D T, Parker F T, Spada F E, Goldman R S, Li J, Sinclair R and Berkowitz A E 1996 Phys. Rev. B53 9175
Parames M L, Mariano J, Viskadourakis Z, Popovoco N, Rogalski M S, Giapintzakis J and Conde O 2006 Appl. Surf. Sci. 252 4610
Park C, Shi Y, Peng Y, Barmak K, Zhu J-G, Laughlin D E and White R M 2003 IEEE Trans. Magn. 39 2806
Sensor P, Fert A, Maurice J-L, Montaigne F, Petroff F and Vauress A 1999 Appl. Phys. Lett. 74 4017
Tiwari S, Choudhary R J, Prakash R and Phase D M 2007a J. Phys.: Condens. Matter 19 176002
Tiwari S, Prakash R, Choudhary R J and Phase D M 2007b J. Phys. D40 4943
Versluijs J J, Bari M A and Coey J M D 2001 Phys. Rev. Lett. 87 026601
Voogt F C, Palstra T T M, Niesen L, Rogojanu O C, James M A and Hibma T 1998 Phys. Rev. B57 R8107
Voogt F C, Fujii T, Smulders P J M, Niesen L, James M A and Hibma T 1999 Phys. Rev. B60 11193
Williamson G K and Hall W H 1953 Acta Metall. 1 22
Wolf S A, Awschalom D D, Buhrman R A, Daughton J M, von Molnár S, Roukes M L, Chtchelkanova A Y and Treger D M 2001 Science 294 1488
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
RAMAY, S.M., SIDDIQI, S.A., ANWAR, M.S. et al. Effect of annealing time on structural and magnetic properties of laser ablated oriented Fe3O4 thin films deposited on Si(100). Bull Mater Sci 35, 501–503 (2012). https://doi.org/10.1007/s12034-012-0318-2
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12034-012-0318-2