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Ionic liquid intercalated V2O5 nanorods: synthesis and characterization

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Abstract

In this work, ionic liquid (IL) intercalated V2O5 (IL-V2O5) nanorods have been synthesized through the IL-assisted hydrothermal method using imidazolium-based functionalized IL at 130 ∘C for 3 days. The structure and morphology of the obtained product was characterized using various techniques. X-ray diffraction pattern reveals the intercalation of IL at 2 𝜃=7∘ in orthorhombic V2O5. The Fourier transform infrared spectrum shows a band at 1044 cm−1, which could be assigned to stretching vibration of terminal vanadyl (V =O), sensitive to cation intercalation between vanadium oxide layers. UV–vis absorption spectrum of IL-V2O5 nanorods and calcined V2O5 nanoparticles show a maximum absorbance at 402 and 420 nm, respectively. The morphology of the product was investigated by scanning electron microscopy and transition electron microscopy (TEM). TEM analysis reveals the nanorods with thickness of 30–50 nm.

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References

  1. Schlesser R, Dalmau R, Zhuang D, Collazo R and Sitar Z 2005, J. Cryst. Growth 281 75

    Article  Google Scholar 

  2. Chandrappa G T, Chithaiah P, Ashoka S and Livage J 2011, Inorg. Chem. 50 7421

    Article  Google Scholar 

  3. Duan X, Niu C, Sahi V, Chen J, Parce J, Empedocles S and Goldman J 2003, Nature 425 274

    Article  Google Scholar 

  4. Zhong Z, Wang D, Cui Y, Bockrath M and Lieber C M 2003, Science 302 1377

    Article  Google Scholar 

  5. Livage J 1991, Chem. Mater. 3 578

    Article  Google Scholar 

  6. Moshfegh A Z and Ignatiev A 1991, Thin Solid Films 198 251

    Article  Google Scholar 

  7. Sphar M E, Stoschitzki B P, Nesper R, Hass O and Novak P 1999, J. Electrochem. Soc. 146 2780

    Article  Google Scholar 

  8. Cao J, Musfeldt J L, Mazumdar S, Chernova N A and Whittingham M S 2007, Nano Lett. 7 2351

    Article  Google Scholar 

  9. Barboux P, Baffier N, Morineau R, Livage J, Goodenough J B, Jensen J and Poiter A 1985 Solid state protonic conductors III (Paris: Odense University Press) p 173

  10. Livage J 1984, Mater. Res. Soc. Symp. Proc. 32 125

    Article  Google Scholar 

  11. Nagaraju G and Chandrappa G T 2012, Mater. Res. Bull. 47 3216

    Article  Google Scholar 

  12. Wang N, Chen W and Mail D Y 2008, J. Solid State Chem. 181 652

    Article  Google Scholar 

  13. Zoubi M A, Hala K F and Endres F. 2009, J. Mater. Sci. 44 1363

    Article  Google Scholar 

  14. Durupthy O, Steunou N, Coradin T, Maquet J, Bonhomme C and Livage J 2005, J. Mater. Chem. 15 1090

    Article  Google Scholar 

  15. Han W, Fan S, Li Q and Hu Y 1997, Science 277 1287

    Article  Google Scholar 

  16. Li Y D, Liao H W, Ding Y, Fan Y, Zhang Y and Qian Y T 1999 Inorg. Chem. 381

  17. Pinna N, Wild U, Urban J and Schlogl R 2003, Adv. Mater. 15 329

    Article  Google Scholar 

  18. Ribeiro W A C, Leite E R and Mastelaro V R 2009, Cryst. Growth Des. 9 3626

    Article  Google Scholar 

  19. Rothschild A, Sloan J and Tenne R 2000, J. Am. Chem. Soc. 122 5169

    Article  Google Scholar 

  20. Wang Y and Cao G 2006, Chem. Mater. 18 2787

    Article  Google Scholar 

  21. Zhou F, Zhao X, Yuan C and Li L 2008, Cryst. Growth Des. 8 7

    Google Scholar 

  22. Nagaraju G 2012, Z. Anorg. Allg. Chem. 638 2286

    Google Scholar 

  23. Zhou Y, Bao Q, Tang L L, Zhong Y and Loh K P 2009, Chem. Mater. 2 2950

    Article  Google Scholar 

  24. Dupont J, De Souza R F and Suarez P A Z 2002, Chem. Rev. 102 3667

    Article  Google Scholar 

  25. Dupont J and Jackson D S 2010, Chem. Soc. Rev. 39 1780

    Article  Google Scholar 

  26. Hu H, Yang H, Huang P, Cui D, Peng Y, Zhang J, Lu F, Lian J and Shi D 2010, Chem. Commun. 46 3866

    Article  Google Scholar 

  27. Cassol C C, Ebeling G, Ferrera B and Dupont J 2006, Adv. Synth. Catal. 348 243

    Article  Google Scholar 

  28. Israel E and Waches 2001 Raman spectroscopy of catalysis, Hand book of Raman spectroscopy (Pennsylvania: CRC Press, Lehigh University) p 799

  29. Nagaraju G, Ebeling G, Goncalves R V, Teixeira S R, Weibel D E and Dupont J 2013, J. Mol. Catal. A – Chem. 378 213

    Article  Google Scholar 

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Authors and Affiliations

  1. Centre for Nano and Materials Science, Jain University, Jakkasandra (P), Kanakapura, India

    K MANJUNATH, T RAMAKRISHNAPPA & G NAGARAJU

  2. Laboratory of Molecular Catalysis, Institute of Chemistry, UFRGS, Porto Alegre, Brazil, RS

    V D’SOUZA & J DUPONT

  3. Department of Chemistry, Siddaganga Institute of Technology, Tumkur, India

    G NAGARAJU

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  1. K MANJUNATH
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  2. V D’SOUZA
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  3. J DUPONT
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  4. T RAMAKRISHNAPPA
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  5. G NAGARAJU
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Correspondence to G NAGARAJU.

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MANJUNATH, K., D’SOUZA, V., DUPONT, J. et al. Ionic liquid intercalated V2O5 nanorods: synthesis and characterization. Bull Mater Sci 38, 1309–1313 (2015). https://doi.org/10.1007/s12034-015-1015-8

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  • DOI: https://doi.org/10.1007/s12034-015-1015-8

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