Abstract
The synthesis by the sol–gel method, structural and optical properties of ZnO, Zn0.99Al0.01O (AlZ), Zn0.9V0.1O (VZ) and Zn0.89Al0.01V0.1O (AlVZ) nanoparticles was reported. The approach was slow release of water for hydrolysis by esterification reaction followed by a supercritical drying in ethyl alcohol. After thermal treatment at 500∘C in air, the obtained nanopowders were characterized by various techniques such as transmission electron microscopy, X-ray diffraction and photoluminescence (PL) spectroscopy. The structural properties showed that the ZnO nanoparticles with an average particle size of 25 nm exhibit hexagonal wurtzite structure. From the optical studies, it was found that the optical band gap was located between 2.97 and 3.17 eV. The obtained electrical properties showed the potential application of the samples in optoelectronic devices. The powder of AlVZ presented a strong luminescence band in the visible range. The PL band energy position presented a small blue shift with the increase of measurement temperature. Different possible attributions of this emission band will be discussed.
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Kim Y M, Yoon M, Park I W, Park Y J and Lyou J H 2004 J. Solid State Commun. 129 175
El Mir L, El Ghoul J, Alaya S, Ben Salem M, Barthou C and von Bardeleben H J 2008 J. Phys. B: Condens. Matter 403 1770
El Mir L, Ben Ayadi Z, Saadoun M, Djessas K, von Bardeleben H J and Alaya S 2007 J. Appl. Surf. Sci. 254 570
El Ghoul J, Barthou C and El Mir L 2012 Physica E 44 1910
El Ghoul J, Barthou C and El Mir L 2012 J. Superlattices Microstruct. 51 942
El Ghoul J, Barthou C, Saadoun M and El Mir L 2010 J. Phys. B 405 597
Karmakar D, Mandal S K, Kadam R M, Paulose P L, Rajarajan A K, Nath T K, Das A K, Dasgupta I and Das G P 2007 J. Phys. Rev. B 75 144404
Khorsand Zak A, Abd. Majid W H, Abrishami M E, Yousefi R and Parvizi R 2012 J. Solid State Sci. 14 488
Nunes P, Fortunadeo E and Martins R 2001 Thin Solid Films 383 277
Jin B J, Im S and Lee S Y 2000 Thin Solid Films 366 107
Vanheusden K, Warren W L, Seager C H, Tallant D R, Voigt J A and Gnade B E 1996 J. Appl. Phys. 79 7983
Greene L E, Law M, Goldberger J, Kim F, Johnson J C, Zhang Y, Saykally R J and Yang P 2003 Angew. Chem. Int. Ed. 42 3031
Heo Y W, Norton D P and Pearton S J 2005 J. Appl. Phys. 98 1
Studenikin S A, Golego N and Cocivera M 1998 J. Appl. Phys. 84 2287
Liu X, Wu X, Cao H and Chang R P H 2004 J. Appl. Phys. 95 3141
Wang M, Kim E J, Chung J S, Shin E W, Hahn S H, Lee K E and Park C 2006 Phys. Status Solidi A 203 2418
Li L J, Deng H, Dai L P, Chen J J, Yuan Q L and Li Y 2008 Mater. Res. Bull. 43 1456
Fujihara S, Ogawa Y and Kasai A 2004 Chem. Mater. 16 2965
Lee J Y, Jang B R, Lee J H, Kim H S, Cho H K, Moon J Y, Lee W J and Baek J W 2009 Thin Solid Films 517 4086
Gong Y, Andelman T, Neumark G F, O’Brien S and Kuskovsky I L 2007 Nanoscale Res. Lett. 2 297
Ohashi N, Ebisawa N, Sekiguchi T, Sakaguchi I, Wada Y, Takenaka T and Haneda H 2005 Appl. Phys. Lett. 86 1
Nayak J, Kimura S, Nozaki S, Ono H and Uchida K 2007 Superlattices Microstruct. 42 438
El Mir L, Ben Ayadi Z, Saadoun M, von Bardeleben H J, Djessas K and Zeinert A 2007 Phys. Status Solidi (a) 204 3266
El Mir L, Ghribi F, Ben Ayadi Z, Djessas K, Cubukcu M and von Bardeleben H J 2011 Thin Solid Films 519 5787
Wang L, Meng L, Teixeira V, Song S, Xu Z and Xu X 2009 Thin Solid Films 517 3721
El Ghoul J, Bouguila N, Gómez-Lopera S A and El Mir L 2013 Superlattices Microstruct. 64 451
Cogan S F, Nguyen N M, Perrotti S J and Rauh R D 1989 J. Appl. Phys. 66 1333
Zhong Z Y and Zhang T 2013 Mater. Lett. 96 237
Kong Y C, Yu D P, Zhang B et al 2001, Appl. Phys. Lett. 78 407
El Ghoul J, Barthou C, Saadoun M and El Mir L 2010 Physica B 405 597
Jin B J, Im S and Lee S Y 2000 Thin Solid Films 366 107
Jeong S H, Kim B S and Lee B T 2003 Appl. Phys. Lett. 82 2625
Fu Z X, Guo C X, Lin B X and Liao G H 1998 Chim. Phys. Lett. 15 457
Teke A, Ozgur U, Dogan S, Gu X, Morkoç H, Nemeth B, Mause J and Everitt H O 2004 Phys. Rev. B 70 195207
Wang M, Lee K E, Hahn S H, Kim E J, Kim S, Chung J S, Shin E W and Park C 2007 Mater. Lett. 61 1118
Leroux M, Grandjean N, Beaumont B, Nataf G, Semond F, Massies J and Gibart P 1999 J. Appl. Phys. 86 3721
Wang Y, Hao Y and Yuwen L 2006 J. Alloys Compd. 425 339
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EL GHOUL, J. Synthesis, structural and optical properties of nanoparticles (Al, V) co-doped zinc oxide. Bull Mater Sci 39, 7–12 (2016). https://doi.org/10.1007/s12034-015-1139-x
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DOI: https://doi.org/10.1007/s12034-015-1139-x