Abstract
An electrically conductive polypyrrole–tungsten disulphide (\({\hbox {PPy/WS}}_{2}\)) composite was synthesized by a chemical polymerization technique. The composite was characterized by field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR) and energy dispersive X-ray spectroscopy (EDX). FESEM images showed the grainy morphology with permeable nature. XRD and FTIR characteristic peak analysis exhibited semi-crystalline behaviour and confirming the interfacial interaction of the as-synthesized composite. EDX confirmed the presence of carbon, nitrogen, oxygen, tungsten and sulphur in the composite. The humidity sensing property of the \({\hbox {PPy/WS}}_{2}\)-50% composite was tested and an approximate linear decrease in resistance was observed with an increase in relative humidity, along with a maximum sensing response of 97% and a response-recovery time of 52 and 58 s, respectively. The sensing ability of the composite was observed to be stable, when monitored for a period of two months.
Similar content being viewed by others
References
Hatchett D W and Josowicz M 2008 Chem. Rev. 108 746
Farahani H, Wagiran R and Hamidon M N 2014 Sensors 14 7881
Manjunatha S, Sunilkumar A and Machappa T 2018 AIP Conf. Proc. 1953 030019-1
Vishnoi P, Rajesh S, Manjunatha S, Bandyopadhyay A, Barua M and Pati S K 2017 ChemPhysChem18 2985
Rao C N R, Gopalakrishnan K and Maitra U 2015 ACS Appl. Mater. Interfaces 7 7809
Manjunatha S, Rajesh S, Vishnoi P and Rao C N R 2017 J. Mater. Res. 32 2984
Manjunatha S, Chethan B, Ravikiran Y T and Machappa T 2018 AIP Conf. Proc. 1953 030096-1
Manjunatha S, Machappa T, Ravikiran Y T, Chethan B and Sunilkumar A 2019 Physica B Phys. Condens. Matter. 561 170
Chaluvaraju B V, Ganiger S K and Murugendrappa M V 2016 J. Mater. Sci.: Mater. Electron. 27 1044
Suri K, Annapoorni S, Sarkar A K and Tandon R P 2002 Sens. Actuators B Chem. 81 277
Raj A M E S, Magdalane C M and Nagaraja K S 2002 Phys. Stat. Sol. (A) 234 230
Su P and Huang L 2007 Sens. Actuators B Chem. 123 501
Sajjan K C, Faisal M, Kumari S C V, Ravikiran Y T and Khasim S 2013 AIP Conf. Proc. 289 289
Wang L, He Y, Hu J, Qi Q and Zhang T 2011 Sens. Actuators B Chem. 153 460
Machappa T and Prasad M V N A 2012 Bull. Mater. Sci. 35 75
Machappa T, Sasikala M, Anilkumar K R and Prasad M V N A 2009 Sens. Transducers 107 77
Chethan B, Raj Prakash H G, Ravikiran Y T, Vijaya Kumari S C, Ramana C H V V and Thomas S 2019 Talanta 196 337
Sun A, Li Z, Wei T, Li Y and Cui P 2009 Sens. Actuators B Chem. 142 197
Patil S N, Pawar A M, Tilekar S K and Ladgaonkar B P 2016 Sens. Actuators A Phys. 244 35
Suhada N, Tahiruddin M, Daik R and Selangor B 2015 Sch. Res. Libr. 7 159
Vishnuvardhan T K, Kulkarni V R, Basavaraja C and Raghavendra S C 2006 Bull. Mater. Sci. 29 77
Park K and Noida G 2016 Int. J. Sci. Eng. Stud. 3 7
Mane A T, Navale S T, Pawar R C, Lee C S and Patil V B 2015 Synth. Met. 199 187
Kotresh S, Ravikiran Y T, Vijay Kumari S C, Chandrasekhar T, Ramana C H V V and Thomas S 2016 Mater. Manuf. Process31 1976
Lin W, Chang H and Wu R 2013 Sens. Actuators B Chem. 181 326
Manjunatha S, Machappa T, Sunilkumar A and Ravikiran Y T 2018 J. Mater. Sci. Mater. Electron. 29 11581
Chougule M A, Dalavi D S, Patil P S, Moholkar A V, Agawane G L and Kim J H 2012 Measurement45 1989
Walter C, Kummer K, Vyalikh D and Quade A 2012 J. Electrochem. Soc. 159 560
Tandon R P, Tripathy M R, Arora A K and Hotchandani S 2006 Sens. Actuators B114 768
Acknowledgements
All the authors thank Dr Yashvanth Bhupal, Director, Ballari Institute of Technology and Management, Ballari, for his support. S Manjunatha thanks Sri D K Mohan, Chairman and Dr L Suresh, Principal of Cambridge Institute of Technology, Bengaluru for their encouragement.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Sunilkumar, A., Manjunatha, S., Machappa, T. et al. A tungsten disulphide–polypyrrole composite-based humidity sensor at room temperature. Bull Mater Sci 42, 271 (2019). https://doi.org/10.1007/s12034-019-1955-5
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s12034-019-1955-5