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PbO as an efficient and reusable catalyst for one-pot synthesis of tetrahydro benzo pyrans and benzylidene malonitriles

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Abstract

PbO nanoparticles have been employed as an efficient catalyst for the solvent-free synthesis of tetrahydrobenzo pyrans (yields 81–91%) and benzylidene malonitriles (yields 90–96%) at room temperature using green chemistry approach. PbO nanoparticles were found to be highly efficient, eco-friendly and recyclable heterogeneous catalyst. PbO nanoparticles were prepared by hydrothermal method and characterized by IR, XRD, BET Surface area, SEM, EDAX and TEM with SAED techniques.

One-pot synthesis of tetrahydro benzo pyrans and benzylidene malonitriles using PbO nanoparticle under solvent-free condition at room temperature has been presented. PbO nanoparticles were found to be highly efficient, ecofriendly and recyclable catalyst.

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Acknowledgements

Authors thank the University Grants Commission (UGC), New Delhi, for financial support, University of Pune, Pune and Sophisticated Analytical Instrument Facility (SAIF) Panjab University, Chandigarh for providing spectral analysis facilities. Authors are also thankful to Prof. A G Gadhave for his helpful suggestions.

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Authors and Affiliations

  1. Department of Chemistry, Research Center, HPT Arts and RYK Science College, Nashik, 422 005, India

    ASHOK V BORHADE & DIPAK R TOPE

  2. Department of Chemistry, Research Center, PVP College, Pravaranagar (Loni Kd), 413 713, India

    BHAGWAT K UPHADE

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  1. ASHOK V BORHADE
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  2. BHAGWAT K UPHADE
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  3. DIPAK R TOPE
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Correspondence to ASHOK V BORHADE.

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Supplementary material

Supplementary material given as figures S1–S5 can be seen online www.ias.ac.in/chemsci website.

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BORHADE, A.V., UPHADE, B.K. & TOPE, D.R. PbO as an efficient and reusable catalyst for one-pot synthesis of tetrahydro benzo pyrans and benzylidene malonitriles. J Chem Sci 125, 583–589 (2013). https://doi.org/10.1007/s12039-013-0396-8

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  • DOI: https://doi.org/10.1007/s12039-013-0396-8

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