Abstract
The study of volatile constituents in minerals has potential applications ranging from environmental studies to ore research to volcanic hazards. In this paper we present new data on the volatile (particularly CO2) content of a series of feldspathoids belonging to the cancrinite-sodalite group of minerals, in combination with other data collected over the last few years. The work has been essentially done using FTIR microspectroscopy to detect and characterize the speciation of H and C in the micropores of these minerals. We show that most cancrinite-sodalite group of minerals are able to trap CO2 in their structure in addition to other molecular and anionic species such as H2O, OH, F, Cl, SO4, SO3 etc. A combination of in situ and annealing heat-treatments shows that the different species in the cancrinite-sodalite group release CO2 at different temperatures, due to the different connectivity of their pores. Detailed FTIR microspectrometry mappings typically show non-homogeneous distributions of hydrogen and carbon across the samples, and suggest a possible use of these minerals as a tool for geothermometric modelling. The finding that most cancrinite-sodalite group minerals are able to trap carbon dioxide opens a new frontier in the design of materials having potential for carbon sequestration from the atmosphere.
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References
Aines RD, Rossman GR (1984) The high temperature behaviour of water and carbon dioxide in cordierite and beryl. Am. Mineral. 69: 319–327
Armbruster Th, Bloss FD (1980) Channel CO2 in cordierite. Nature 286: 140–141
Ballirano P, Bonaccorsi E, Merlino S, Maras A (1998) Carbonate groups in davyne: structural and crystal-chemical considerations. Can. Mineral. 36: 1285–1292
Ballirano P, Maras A, Buseck PR (1996) Crystal chemistry and IR spectroscopy of Cl− and SO −4 bearing cancrinite-like minerals. Am. Mineral. 81: 1003–1012
Bonaccorsi E, Comodi P, Merlino S (1995) Thermal behavior of davyne-group minerals. Phys. Chem. Minerals 22: 367–374
Bonaccorsi E, Della Ventura G, Bellatreccia F, Merlino S (2007) The thermal behaviour and dehydration of pitiglianoite, a mineral of the cancrinite group. Microporous Mesoporous Mater. 99: 225–235
Bonaccorsi E, Merlino S (2005) Modular microporous minerals: cancrinite-davyne group and C-S-H phases. In: Ferraris G, Merlino S (eds), Micro-and Mesoporous Mineral Phases. Reviews in Mineralogy and Geochemistry, Mineralogical Society of America 57: 241–290
Bonaccorsi E, Orlandi P (1996). Second occurrence of pitiglianoite, a mineral of the cancrinite-group. Atti Soc. Tosc. Sc. Nat., s. A. 103: 193–195
Brewer PG, Friederich GE, Peltzer ET, Orr FM Jr. (1999) Direct experiments on the ocean disposal of fossil fuel CO2. Science 284: 943–945
Cámara F, Bellatreccia F, Della Ventura G, Mottana A (2005) Farneseite, a new mineral of the cancrinite-sodalite group with a 14 layer stacking sequence: occurrence and crystal structure. Eur. J. Mineral. 17: 839–846
CestelliGuidi M, Piccinini M, Marcelli A, Nucara A, Calvani P, Burattini E (2005) Optical performances of SINBAD, the Synchrotron INfrared Beamline At Dafne. J. Opt. Soc.Am. A 22: 2810–2817
Deer WA, Howie RA, Wise WS, Zussman J (2004) Framework Silicates: Silica Minerals, Feldspathoids and the Zeolites. Geological Society, London
Della Ventura G, Bellatreccia F (2004) The channel constituents of cancrinite-group minerals. Micro-and Mesoporous Mineral Phases (Accademia Nazionale dei Lincei, Rome, December 6–7, 2004) Pre-Prints: 75–76
Della Ventura G, Bellatreccia F, Bonaccorsi E (2005) CO2 in minerals of the cancrinitesodalite group: pitiglianoite. Eur. J. Mineral. 17: 843–851
Della Ventura G, Bellatreccia F, Cámara F, Oberti R, Lorand J-P, Parodi GC, Carlier G, Di Domenico D (2006) Carbon-bearing cordierite from Allumiere (Tolfa volcanic center, Latium, Italy): Occurrence, crystal-structure and FTIR microspectroscopy. Per. Mineral. 75: 113–126
Della Ventura G, Bellatreccia F, Parodi GC, Cámara F, Piccinini M (2007) Single-crystal FTIR and X-ray study of vishnevite, ideally [Na6(SO4)][Na2(H2O)2](Si6Al6O24). Am. Mineral. 92: 713–721
Elliot S, Lackner KS, Dubey MK, Hanson HP, Barr S (2001) Compensation of atmospheric CO2 buildup through engineered chemical sinkage. Geophys. Res. Lett. 28: 1235–1238
Galitskii VYu, Grechushnikov BN, Sokolov YuA (1978) Form of water in cancrinite. Russ. J. Inorg. Chem. 23: 1749–1750
Gesing M, Buhl J-Ch (2000) Structure and spectroscopic properties of hydrogencarbonate containing alumosilicate sodalite and cancrinite. Z. Kristallogr. 215: 413–418
Hassan I, Grundy HD (1991) The crystal structure of haüyne at 293 and 153 K. Can. Mineral. 29: 123–130
Ihinger PD, Hervig RL, McMillan PF (1994) Analytical methods for volatile in glasses. In: Carroll MR, Holloway JR (eds), Volatiles in Magmas. Mineralogical Society of America, Reviews in Mineralogy, 30: 67–121
Johannes W, Schreyer W (1981) Experimental introduction of CO2 and H2O into Mg-cordierite. Am. J. Sci. 281: 299–317
Khomenko VM, Langer K (2005) Carbon oxides in cordierite channels: determination of CO2 isotopic species and CO by single crystal IR spectroscopy. Am. Mineral. 90: 1913–1917
King PL, Vennemann TW, Holloway JR, Hervig RL, Lowenstern JB, Forneris JF (2002) Analytical techniques for volatiles: a case study using intermediate (andesitic) glasses. Am. Mineral. 87: 1077–1089
Kolesov BA, Geiger CA (2003) Molecules in the SiO2-clathrate melanophlogite: a single-crystal Raman study. Am. Mineral. 88: 1364–1368
Lackner KS, Wendt CH, Butt DP, Joyce EL, Sharp DH (1995) Carbon dioxide disposal in carbonate minerals. Energy 20: 1153–1170
Mandarino JA, Back ME (2004) Fleischer’s glossary of mineral species. Mineralogical Record Inc., Tucson
Maurin G, Llewellyn PL, Bell RG (2005). Adsorption mechanism of carbon dioxide in faujasite: grand canonical Monte Carlo simulations and microcalorimetry measurements. J. Phys. Chem. B. 109: 16084–16091
McCusker LB, Liebau F, Engelhardt G (2001) Nomenclature of structural and compositional characteristics of ordered microporous and mesoporous materials with inorganic hosts (IUPAC Reccomandations 2001). Pure Appl. Chem. 73: 381–394
McMullan RK, Ghose S, Haga N, Schomaker V (1996) Sodalite, Na4Si3Al3O12Cl: structure and ionic mobility at high temperature by neutron diffraction. Acta Crystallogr. B52: 616–627
Merlino S, Mellini M, Bonaccorsi E, Pasero M, Leoni L, Orlandi P (1991) Pitiglianoite, a new feldspathoid from southern Tuscany, Italy: Chemical composition and crystal structure. Am. Mineral. 76: 2003–2008
O’Connor WK, Dahlin DC, Turner PC, Walters RP (2000) Carbon dioxide sequestration by ex-situ mineral carbonation. Technology, 7: 115–123
Rinaldi R (1982) More stacking variations in cancrinite-related minerals; how many more new minerals?. J. Microsc. Spectrosc. Electron. 7: 76a–77a
Rinaldi R, Wenk HR (1979) Stacking variations in cancrinite minerals. Acta Crystallogr. A35: 825–828
Rouquerol J, Avnir D, Fairbridge CW, Everett DH, Haynes JH, Pernicone N, Ramsay JD, Sing KSW., Unger KK (1994) IUPAC “Recommendations for the Characterization of Porous Solids”. Pure Appl. Chem. 66: 1739–1758
Sing KSW, Williams RT(2004) Review: the use of molecular probes for the characterization of nanoporous adsorbents. Part. Syst. Charact. 21: 71–79
Taylor D (1967) The sodalite group of minerals. Contrib. Mineral. Petrol. 16: 172–188
Van Peteghem JK, Burley BJ (1963) Studies on solid solution between sodalite, nosean and haüyne. Can. Mineral. 7: 808–813
Wood DL, Nassau K (1967) Infrared spectra of foreign molecules in beryl. J. Chem. Phys. 47: 2220–2228
Zhang M, Wang L, Hirai S, Redfern SAT, Salje EKD (2005) Dehydroxylation and CO2 incorporation in annealed mica (sericite): an infrared spectroscopic study. Am. Mineral. 87: 90, 173–180
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Della Ventura, G., Bellatreccia, F. & Piccinini, M. Channel CO2 in feldspathoids: New data and new perspectives. Rend. Fis. Acc. Lincei 19, 141–159 (2008). https://doi.org/10.1007/s12210-008-0008-6
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DOI: https://doi.org/10.1007/s12210-008-0008-6