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Microstructure and Physical–Mechanical Properties of (TiAlSiY)N Nanostructured Coatings Under Different Energy Conditions

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Abstract

Nanostructured multicomponent (TiAlSiY)N coatings were fabricated by the cathodic-arc physical vapor deposition (CA-PVD). In this study, a bias potential applied to the substrate was − 200 and − 500 V, and changes in structure and properties of coatings were investigated. Samples had a single-phase state with a face-centered cubic (FCC) lattice. Small crystallites of about 7.5 nm and texture with [110] axis were observed at − 500 V. However, lower bias potential resulted in the formation of crystallites of about 41.6 nm with [111] preferred orientation. Moreover, coatings were characterized by superhard state and demonstrated low wear, high abrasion and crack resistance. The testing of the polycrystalline cubic boron nitride (PCBN) cutting inserts covered with (TiAlSiY)N revealed an increase in the tool life coefficient during cutting by 1.66 times in comparison with the base tool material. Therefore, (TiAlSiY)N coating is a perspective material for application as a protective layer in cutting tools.

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References

  1. A.D. Pogrebnjak, D. Eyidi, G. Abadias, O.V. Bondar, V.M. Beresnev, O.V. Sobol, Int. J. Refract. Met. Hard Mater. 48, 222–228 (2015)

    Article  Google Scholar 

  2. A.D. Pogrebnjak, A.A. Bagdasaryan, A. Pshyk, K. Dyadyura, Phys.-Usp. 60, 586–607 (2017)

    Article  Google Scholar 

  3. A.D. Pogrebnjak, V.M. Beresnev, K.V. Smyrnova, Y.O. Kravchenko, P.V. Zukowski, G.G. Bondarenko, Mater. Lett. 211, 316–318 (2018)

    Article  Google Scholar 

  4. A.D. Pogrebnjak, A.A. Bagdasaryan, I.V. Yakushchenko, V.M. Beresnev, Russ. Chem. Rev. 83, 1027–1061 (2014)

    Article  Google Scholar 

  5. C.T. Lynch, Handbook of Materials Science, Volume III: Nonmetallic Materials & Applications (CRC Press, Boca Raton, FL, 1988)

    Google Scholar 

  6. A. Shypylenko, A.V. Pshyk, B. Grześkowiak, K. Medjanik, B. Peplinska, K. Oyoshi, A. Pogrebnjak, S. Jurga, E. Coy, Mater. Des. 110, 821–829 (2016)

    Article  Google Scholar 

  7. A. Pogrebnjak, V. Rogoz, V. Ivashchenko, O. Bondar, V. Shevchenko, S. Jurga, E. Coy, J. Alloys Compd. 718, 260–269 (2017)

    Article  Google Scholar 

  8. L.-H. Zhu, C. Song, W.-Y. Ni, Y.-X. Liu, Trans. Nonferrous Met. Soc. China 26, 1638–1646 (2016)

    Article  Google Scholar 

  9. M. Pfeiler, J. Zechner, M. Penoy, C. Michotte, C. Mitterer, M. Kathrein, Surf. Coat. Technol. 203, 3104–3110 (2009)

    Article  Google Scholar 

  10. I.A. Svito, O.V. Korolik, A.V. Mazanik, A.K. Fedotov, A.M. Saad, V.G. Luhin, T.N. Koltunowicz, P. Zukowski, J. Alloys Compd. 726, 417–423 (2017)

    Article  Google Scholar 

  11. T. Chen, Z. Xie, F. Gong, Z. Luo, Z. Yang, Appl. Surf. Sci. 314, 735–745 (2014)

    Article  Google Scholar 

  12. I. Svito, A.K. Fedotov, A. Saad, P. Zukowski, T. Koltunowicz, J. Alloys Compd. 699, 818–823 (2017)

    Article  Google Scholar 

  13. M. Li, R. Wang, Y. Fan, L. Wang, Mater. Res. Innov. 19, 190–194 (2015)

    Google Scholar 

  14. Y. Kravchenko, V. Borysiuk, A. Pogrebnjak, M. Kylyshkanov, I. Iatsunskyi, K. Smyrnova, in 2017 IEEE 7th International Conference Nanomaterials: Application & Properties (NAP), 01FNC02-01-01FNC02-04

  15. K. Zhang, J. Deng, Y. Xing, S. Li, H. Gao, Appl. Surf. Sci. 326, 107–118 (2015)

    Article  Google Scholar 

  16. A.D. Pogrebnjak, I.V. Yakushchenko, O.V. Bondar, V.M. Beresnev, K. Oyoshi, O.M. Ivasishin, H. Amekura, Y. Takeda, M. Opielak, C. Kozak, J. Alloys Compd. 679, 155–163 (2016)

    Article  Google Scholar 

  17. V. Belous, V. Vasyliev, A. Luchaninov, V. Marinin, E. Reshetnyak, V. Strel’nitskij, S. Goltvyanytsya, V. Goltvyanytsya, Surf. Coat. Technol. 223, 68–74 (2013)

    Article  Google Scholar 

  18. Y. Xie, X. Zheng, X. Liu and C. Ding, in Thermal Spray 2007: Global Coating Solutions: Proceedings of the 2007 International Thermal Spray Conference, ed. by B.R. Marple, M.M. Hyland, Y.-C. Lau, C.-J. Li, R.S. Lima, G. Montavon), 389-392, ASM International, Ohio, USA

  19. W. Zhou, J. Liang, F. Zhang, J. Mu, H. Zhao, Appl. Surf. Sci. 313, 10–18 (2014)

    Article  Google Scholar 

  20. V.M. Beresnev, A.D. Pogrebnjak, P.V. Turbin, S.V. Litovchenko, Tech. Phys. 55, 871–873 (2010)

    Article  Google Scholar 

  21. O. Boiko, T.N. Koltunowicz, P. Zukowski, A.K. Fedotov, A.V. Larkin, Ceram. Int. 43, 2511–2516 (2017)

    Article  Google Scholar 

  22. S. Veprek, M. Jilek, Vacuum 67, 443–449 (2002)

    Article  Google Scholar 

  23. J. Musil, Surf. Coat. Technol. 207, 50–65 (2012)

    Article  Google Scholar 

  24. A.O. Demenok, A.A. Ganeev, O.B. Demenok, B.A. Kulakov, Bull. South Ural State Univ. Ser. “Metall.” 13, 95–102 (2013)

    Google Scholar 

  25. L. Chen, S.Q. Wang, Y. Du, S.Z. Zhou, T. Gang, J.C. Fen, K.K. Chang, Y.W. Li, X. Xiong, Surf. Coat. Technol. 205, 582–586 (2010)

    Article  Google Scholar 

  26. S. Carvalho, E. Ribeiro, L. Rebouta, C. Tavares, J.P. Mendonça, A. Caetano Monteiro, N.J.M. Carvalho, J.T.M. De Hosson, A. Cavaleiro, Surf. Coat. Technol. 177, 459–468 (2004)

    Article  Google Scholar 

  27. S. Sveen, J.M. Andersson, R. M’Saoubi, M. Olsson, Wear 308, 133–141 (2013)

    Article  Google Scholar 

  28. J.C. Camargo, D.S. Dominguez, E.O. Ezugwu, Á.R. Machado, Int. J. Refract. Met. Hard Mater. 47, 61–70 (2014)

    Article  Google Scholar 

  29. R. Ramadoss, N. Kumar, R. Pandian, S. Dash, T.R. Ravindran, D. Arivuoli, A.K. Tyagi, Tribol. Int. 66, 143–149 (2013)

    Article  Google Scholar 

  30. S.C. Vettivel, R. Jegan, J. Vignesh, S. Suresh, Surf. Interfaces 6, 1–10 (2017)

    Article  Google Scholar 

  31. M. Tkadletz, C. Mitterer, B. Sartory, I. Letofsky-Papst, C. Czettl, C. Michotte, Surf. Coat. Technol. 257, 95–101 (2014)

    Article  Google Scholar 

  32. D. Philippon, V. Godinho, P.M. Nagy, M.P. Delplancke-Ogletree, A. Fernández, Wear 270, 541–549 (2011)

    Article  Google Scholar 

  33. J.K. Chen, C.L. Chang, Y.N. Shieh, K.J. Tsai, B.H. Tsai, Procedia Eng. 36, 335–340 (2012)

    Article  Google Scholar 

  34. C.E.H. Ventura, J. Köhler, B. Denkena, CIRP J. Manufact. Sci. Technol. 6, 246–253 (2013)

    Article  Google Scholar 

  35. X. Huang, I. Etsion, T. Shao, Wear 338, 54–61 (2015)

    Article  Google Scholar 

  36. A. Pogrebnjak, V. Ivashchenko, O. Bondar, V. Beresnev, O. Sobol, K. Załęski, S. Jurga, E. Coy, P. Konarski, B. Postolnyi, Mater. Charact. 134, 55–63 (2017)

    Article  Google Scholar 

  37. K. V. Smyrnova, O. V. Bondar, S. O. Borba-Pogrebnjak, Y. O. Kravchenko, V. M. Beresnev, B. Zhollybekov, L. Baimoldanova, in 2017 IEEE 7th International Conference Nanomaterials: Application & Properties (NAP), 01FNC13-01-01FNC13-04

  38. N. Ravi, R. Markandeya, S.V. Joshi, Mater. Today Proc. 3, 3002–3011 (2016)

    Article  Google Scholar 

  39. L. Chen, K.K. Chang, Y. Du, J.R. Li, M.J. Wu, Thin Solid Films 519, 3762–3767 (2011)

    Article  Google Scholar 

  40. A.D. Pogrebnjak, V.I. Ivashchenko, P.L. Skrynskyy, O.V. Bondar, P. Konarski, K. Załęski, S. Jurga, E. Coy, Compos. B 142, 85–94 (2018)

    Article  Google Scholar 

  41. T. Sprute, W. Tillmann, D. Grisales, U. Selvadurai, G. Fischer, Surf. Coat. Technol. 260, 369–379 (2014)

    Article  Google Scholar 

  42. I.I. Aksenov, A.A. Andreev, V.A. Belous, V.E. Strelnitskiy, V.M. Horoshih, Vacuum Arc: Plasma Sources, Coating Deposition, Surface Modification, vol. 727 (Naukova dumka, Kiev, 2012). (in Russian)

    Google Scholar 

  43. Y. Prabhu, K. Rao, V. Kumar, B. Kumari, World J. Nano Sci. Eng. 4, 21–28 (2014)

    Article  Google Scholar 

  44. P. Muhammed Shafi, A. Chandra Bose, AIP Adv. 5, 057137 (2015)

    Article  Google Scholar 

  45. A. Monshi, M.R. Foroughi, M.R. Monshi, World J. Nano Sci. Eng. 2, 154–160 (2012)

    Article  Google Scholar 

  46. B. Postolnyi, V. Beresnev, G. Abadias, O. Bondar, L. Rebouta, J. Araujo, A. Pogrebnjak, J. Alloys Compd. 725, 1188–1198 (2017)

    Article  Google Scholar 

  47. A. Pogrebnjak, O. Bondar, B. Zhollybekov, S. Konstantinov, P. Konarski, V. Beresnev, A. Kupchishin, Phys. Solid State 59, 1798–1802 (2017)

    Article  Google Scholar 

  48. A. Pélisson-Schecker, H.J. Hug, J. Patscheider, Surf. Coat. Technol. 257, 114–120 (2014)

    Article  Google Scholar 

  49. Y.-Y. Chang, S.-M. Yang, Thin Solid Films 518, S34–S37 (2010)

    Article  Google Scholar 

  50. C.-L. Chang, J.-W. Lee, M.-D. Tseng, Thin Solid Films 517, 5231–5236 (2009)

    Article  Google Scholar 

  51. V.A. Belous, V.V. Vasyliev, V.S. Goltvyanytsya, S.K. Goltvyanytsya, A.A. Luchaninov, E.N. Reshetnyak, V.E. Strel’nitskij, G.N. Tolmacheva, O. Danylina, Surf. Coat. Technol. 206, 1720–1726 (2011)

    Article  Google Scholar 

  52. C.-L. Chang, C.-S. Huang, Thin Solid Films 519, 4923–4927 (2011)

    Article  Google Scholar 

  53. S. Carvalho, L. Rebouta, E. Ribeiro, F. Vaz, C.J. Tavares, E. Alves, N.P. Barradas, J.P. Riviere, Vacuum 83, 1206–1212 (2009)

    Article  Google Scholar 

  54. X.D. Zhang, W.J. Meng, W. Wang, L.E. Rehn, P.M. Baldo, R.D. Evans, Surf. Coat. Technol. 177–178, 325–333 (2004)

    Article  Google Scholar 

  55. A.V. Naumkin, A. Kraut-Vass, S.W. Gaarenstroom, C.J. Powell, NIST Standard Reference Database 20 (2012)

  56. S. Veprek, M.G.J. Veprek-Heijman, P. Karvankova, J. Prochazka, Thin Solid Films 476, 1–29 (2005)

    Article  Google Scholar 

  57. I.-W. Park, S.R. Choi, J.H. Suh, C.-G. Park, K.H. Kim, Thin Solid Films 447–448, 443–448 (2004)

    Article  Google Scholar 

  58. M.S. Kabir, P. Munroe, Z. Zhou, Z. Xie, Wear 380–381, 163–175 (2017)

    Article  Google Scholar 

  59. M.G. Kovaleva, A.Y. Kolpakov, A.I. Poplavskii, I.Y. Goncharov, M.Y. Arseenko, Russ. Metall. 2013, 746–750 (2013)

    Article  Google Scholar 

  60. O.V. Bondar, B.O. Postolnyi, Y.A. Kravchenko, A.P. Shypylenko, O.V. Sobol, V.M. Beresnev, A.P. Kuzmenko, P. Zukowski, Acta Phys. Pol. A 128, 867–870 (2015)

    Article  Google Scholar 

  61. A. Anders, Surf. Coat. Technol. 257, 308–325 (2014)

    Article  Google Scholar 

  62. A.D. Pogrebnyak, A.P. Shpak, N.A. Azarenkov, V.M. Beresnev, Phys.-Usp. 52, 29–54 (2009)

    Article  Google Scholar 

  63. N.K. Mehta, Metal Cutting and Design of Cutting Tools, Jigs & Fixtures, vol. 452 (McGraw Hill Education Private Limited, New Delhi, 2014)

    Google Scholar 

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Acknowledgements

The authors are grateful to V.M. Rogoz (Sumy State University) for the help in interpreting the results of X-ray diffraction analysis. This work was done under the aegis of Ukrainian state budget programs: “Development of material science fundamentals of structure engineering of vacuum-plasma superhard coatings with given functional properties” (Registration Number 0115U000682); “Physical basics of forming of composition and properties of transition metals boride, nitride and boride-nitride films to be used in machine-building” (Registration Number 0116U002621); “Development of perspective nanostructured multilayered coatings with enhanced physical–mechanical and tribological properties” (Registration Number 0116U006816).

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Authors and Affiliations

  1. Sumy State University, Sumy, 40007, Ukraine

    K. V. Smyrnova, A. D. Pogrebnjak, S. O. Borba-Pogrebnjak, Ya. O. Kravchenko & O. V. Bondar

  2. V.N. Karazin, Kharkiv National University, Kharkiv, 61022, Ukraine

    V. M. Beresnev & S. V. Litovchenko

  3. V.Bakul Institute for Superhard Materials NASU Ukraine, Kiev, 04074, Ukraine

    A. S. Manokhin & S. A. Klimenko

  4. Karakalpak State University named after Berdakh, Nukus, 742012, Uzbekistan

    B. Zhollybekov

  5. Abai Kazakh National Pedagogical University, Almaty, 050010, Kazakhstan

    A. I. Kupchishin

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  1. K. V. Smyrnova
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  2. A. D. Pogrebnjak
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Smyrnova, K.V., Pogrebnjak, A.D., Beresnev, V.M. et al. Microstructure and Physical–Mechanical Properties of (TiAlSiY)N Nanostructured Coatings Under Different Energy Conditions. Met. Mater. Int. 24, 1024–1035 (2018). https://doi.org/10.1007/s12540-018-0110-y

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