Abstract
This study aims to improve the lubrication performance of grease by letting Tin (Sn) nanoparticles dispersed in lithium grease, and tests the tribological properties of nanogrease. We use the chemical reduction method to prepare Sn nanoparticles of different particle sizes. After applying Sn nanogrease on the self-made pin-on-disk tribology tester that meets ASTM G99 standards, this study explores the properties of wear resistance and friction decreases of nanogrease with nanparticles of different particle sizes, concentrations and loads. Experimental results show that adding Sn nanoparticles to lithium grease can enhance wear resistance and reduce the coefficient of friction. Under the condition that Sn nanoparticles are in smaller particle size and at a concentration of 1.0 wt.%, friction and wear can both be reduced significantly. Compared to pure lithium base grease, when the grease has loads of 39.2 N and 49 N respectively, the friction coefficients reduce from 0.05434 to 0.01985 and from 0.05635 to 0.02155, with reduction rates at around 63.5% and 61.8%, respectively. Moreover, wear scar diameters decrease from 0.7651 mm to 0.3145 mm and from 0.8263 mm to 0.3658 mm, with reduction rates at around 58.9% and 55.7%, respectively. Additionally, through SEM photographs, this study proves that Sn nanoparticles produce filling and sedimentary effects on wear surfaces.
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Picas, J. A., Forn, A., Igartua, A., and Mendoza, G., “Mechanical and Tribological Properties of High Velocity Oxy-Fuel Thermal Sprayed Nanocrystalline Crc-Nicr Coatings,” Surface and Coatings Technology, Vol. 174–175, pp. 1095–1100, 2003.
Spikes, H., “Tribology Research in the Twenty-First Century,” Tribology International, vol. 34, no. 12, pp. 789–799, 2001.
Tarassov, S. Y. and Kolubaev, A. V., “Effect of Friction on Subsurface Layer Microstructure in Austenitic and Martensitic Steels,” Wear, vol. 231, no. 2, pp. 228–234, 1999.
Zhang, Z., Xue, Q., and Zhang, J., “Synthesis, Structure and Lubricating Properties of Dialkyldithiophosphate-Modified MoS Compound Nanoclusters,” Wear, vol. 209, no. 1, pp. 8–12, 1997.
Hu, Z. S., Lai, R., Lou, F., Wang, L. G., Chen, Z. L., et al., “Preparation and Tribological Properties of Nanometer Magnesium Borate as Lubricating Oil Additive,” Wear, vol. 252, no. 5–6, pp. 370–374, 2002.
Tarasov, S., Kolubaev, A., Belyaev, S., Lerner, M., and Tepper, F., “Study of Friction Reduction by Nanocopper Additives to Motor Oil,” Wear, vol. 252, no. 1–2, pp. 63–69, 2002.
Xu, T., Zhao, J., Xu, K., and Xue, Q., “Study on the Tribological Properties of Ultradispersed Diamond Containing Soot as an Oil Additive©,” Tribology Transactions, vol. 40, no. 1, pp. 178–182, 1997.
Higgs, C. F. and Wornyoh, E. Y. A., “An in Situ Mechanism for Self-Replenishing Powder Transfer Films: Experiments and Modeling,” Wear, vol. 264, no. 1–2, pp. 131–138, 2008.
Bartz, W. J., “Some Investigations on the Influence of Particle Size on the Lubricating Effectiveness of Molybdenum Disulfide,” A S L E Transactions, vol. 15, no. 3, pp. 207–215, 1972.
Zhang, S., Hu, L., Feng, D., and Wang, H., “Anti-Wear and Friction-Reduction Mechanism of Sn and Fe Nanoparticles as Additives of Multialkylated Cyclopentanes under Vacuum Condition,” Vacuum, vol. 87, pp. 75–80, 2013.
Liu, G., Li, X., Lu, N., and Fan, R., “Enhancing Aw/Ep Property of Lubricant Oil by Adding Nano Al/Sn Particles,” Tribology Letters, vol. 18, no. 1, pp. 85–90, 2005.
Zhao, Y., Zhang, Z., and Dang, H., “Preparation of Tin Nanoparticles by Solution Dispersion,” Materials Science and Engineering: A, vol. 359, no. 1–2, pp. 405–407, 2003.
Liu, X., Zeng, M. Q., Ma, Y., and Zhu, M., “Wear Behavior of Al-Sn Alloys with Different Distribution of Sn Dispersoids Manipulated by Mechanical Alloying and Sintering,” Wear, vol. 265, no. 11–12, pp. 1857–1863, 2008.
Mohamed, A., Osman, T. A., Khattab, A., and Zaki, M., “Tribological Behavior of Carbon Nanotubes as an Additive on Lithium Grease,” Journal of Tribology, Vol.137, No. 1, Paper No. 011801, 2015.
Zhao, B. Y., Zhang, Z. J., Wu Z. S., and Dang, H. X., “Tribological Properties of Tin Nanoparticle,” Chinese Journal of Applied Chemistry, vol. 20, no. 12, pp. 1156–1160, 2003.
Zou, C. D., Gao, Y. L., Yang, B., and Zhai, Q. J., “Size-Dependent Melting Properties of Sn Nanoparticles by Chemical Reduction Synthesis,” Transactions of Nonferrous Metals Society of China, vol. 20, no. 2, pp. 248–253, 2010.
Srivatsan, T. S., Ravi, B., Naruka, A. S., Riester, L., Yoo, S., et al., “A Study of Microstructure and Hardness of Bulk Copper Sample Obtained by Consolidating Nanocrystalline Powders using Plasma Pressure Compaction,” Materials Science and Engineering: A, vol. 311, no. 1–2, pp. 22–27, 2001.
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Chang, H., Kao, MJ., Luo, JD. et al. Synthesis and effect of nanogrease on tribological properties. Int. J. Precis. Eng. Manuf. 16, 1311–1316 (2015). https://doi.org/10.1007/s12541-015-0171-5
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DOI: https://doi.org/10.1007/s12541-015-0171-5