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Characterisation of groundwater chemistry in an eastern coastal area of Cuddalore district, Tamil Nadu

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Journal of the Geological Society of India

Abstract

The groundwater quality detoriation due to various geochemical processes like saline water intrusion, evaporation and interaction of groundwater with brines is a serious problem in coastal environments. Understanding the geochemical evolution is important for sustainable development of water resources. A detailed investigation was carried out to evaluate the geochemical processes regulating groundwater quality in Cuddalore district of Tamilnadu, India. The area is entirely underlined by sedimentary formations, which include sandstone, clay, alluvium, and small patches of laterite soils of tertiary and quaternary age. Groundwater samples were collected from the study area and analyzed for major ions. The electrical conductivity (EC) value ranged from 962 to 11,824 μS/cm, with a mean of 2802 μS/cm. The hydrogeochemical evolution of groundwater in the study area starts from Mg-HCO3 type to Na-Cl type indicating the cation exchange reaction along with seawater intrusion. The Br/Cl ratio indicates the evaporation source for the ion. The Na/Cl ratios indicate groundwater is probably controlled by water-rock interaction, most likely by derived from the weathering of calcium-magnesium silicates. The plot of (Ca+Mg) versus HCO3 suggests ions derived from sediment weathering. The plot of Na+K over Cl reflects silicate weathering along with precipitation. Gibbs plot indicates the dominant control of rock weathering. Factor analysis indicates dominance of salt water intrusion, cation-exchange and anthropogenic phenomenon in the study.

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References

  • APHA (1995) Standard methods for the examination of water and wastewater. 19th ed. American Public Association, Washington, DC.

    Google Scholar 

  • Chidambaram, S., Senthil Kumar, G., Prasanna, M.V., John Peter, A., Ramanthan, A.L. and Srinivasamoorthy, K. (2009) A study on the hydrogeology and Hydrogeochemistry of groundwater from different depths in a coastal aquifer: Annamalai Nagar, Tamilnadu, India. Environ. Geol. v.57.pp.59–73, DOI 10.1007/s00254-008-1282-4.

    Article  Google Scholar 

  • Davis, J.C. (2002) Statistics and data analysis in geology. Wiley, (ASIA) Pvt. Ltd., Singapore, New York, pp.526–540.

    Google Scholar 

  • Demirel, Z. (2004) The history and evaluation of saltwater intrusion into a coastal aquifer in Mersin, Turkey. Jour. Environ. Man., v.70, pp.275–282.

    Article  Google Scholar 

  • Dixon, W. and Chiswell, B. (1992) The use of hydrochemical sections to identify recharge areas and saline intrusions in alluvial aquifers, southeast Queensland, Australia. Jour. Hydrol., v.130, pp.299–338.

    Article  Google Scholar 

  • Elango, L. and Ramachandran, S. (1991) Salt balance model for an alluvial aquifer. In: Modeling groundwater flow and pollution. Nanjing University Press, Nanjing, v.1, pp.479–486.

    Google Scholar 

  • Garrels, R.M. and Mackenzie, F.T. (1967) Origin of the chemical compositions of some springs and lakes. In: W. Stumm (Ed.), Equilibrium concepts in natural water systems. Amer., Chem. Soc, pp.222–242

  • Ghabayen, S.M.S., Mckee, M. and Kemblowski, M. (2006) Ionic and isotopic ratios for identification of salinity sources and missing data in the Gaza aquifer. Jour. Hydrol., v.318, pp.360–373.

    Article  Google Scholar 

  • Gibbs, R.J. (1970) Mechanisms controlling world water chemistry. Science, v.17, pp.1088–1090.

    Article  Google Scholar 

  • Jeen, S.K., Kim, J.M., Ko K.S, Yum, B. and Chang, H.W. (2001) Hydrogeochemical characteristics of groundwater in a midwestern coastal aquifer system, Korea. Geosci. Jour., v.5 pp.339–348.

    Article  Google Scholar 

  • Jeevanandam, M., Kannan, R., Srinivasalu, S. and Rammohan, V. (2006) Hydrogeochemistry and groundwater quality assessment of lower part of the Ponnaiyar River Basin, Cuddalore district, South India. Enviro. Monit. Assess., v.132, no.1, pp.263–274. doi:10.1007/s10661-006-9532-y.

    Article  Google Scholar 

  • Kim, K.Y., Park, Y.S., Kim, G.P. and Park, K.I. (2008) Dynamic freshwater-saline water interaction in the coastal zone of Jeju Island, South Korea. Hydrol. Jour., v.17, No3, pp.617–629. DOI: 10.1007/s10040-008-0372-4

    Google Scholar 

  • Krishna Kumar, S., Rammohan, V., Dajkumar Sahayam, J. and Jeevanandam, M. (2009) Assessment of groundwater quality and Hydrogeochemistry of Manimuktha River basin, Tamil Nadu, India. Environ. Monit. Assess., v.159. pp.341–351 DOI 10.1007/s10661-008-0633-7.

    Article  Google Scholar 

  • Liu, C.W., Lin, K.H. and Kuo, Y.M. (2003) Application of factor analysis in the assessment of groundwater quality in a blackfoot disease area in Taiwan. Sci. Total Environ., v.313, pp.77–99.

    Article  Google Scholar 

  • Magaritz, M., Nadler, A., Koyumdjisky, H. and Dan, N. (1981) The use of Na/Cl ratio to trace solute sources in a semiarid zone. Wat. Resour. Res., v.17, pp.602–608.

    Article  Google Scholar 

  • Melloul, A.J. and Goldenberg, L.C. (1997) Monitoring of seawater intrusion in coastal aquifers: basics and local concerns. Jour. Environ. Manage. v.51, no.1, pp.73–86.

    Article  Google Scholar 

  • Mercado, A. (1985) The use of hydrogeochemical patterns in carbonate sand and sandstone aquifers to identify intrusion and flushing of saline waters. Ground Water., v.23, pp.635–645

    Article  Google Scholar 

  • Mondal, N.C., Singh, V.P., Singh, V.S. and Saxena, V.K. (2010) Determining the interaction between groundwater and saline water through groundwater major ions chemistry. Jour. Hydrol., v.25, pp.100–111.

    Article  Google Scholar 

  • Mondal, N.C., Singh, V.P., Singh, S. and Singh, V.S. (2011) Hydrochemical characteristic of coastal aquifer from Tuticorin, Tamil Nadu, India. Environ. Monit. Assess., v.175, pp.531–550. DOI 10.1007/s10661-010-1549-6.

    Article  Google Scholar 

  • Murad, A.A. and Krishnamurthy, R.V. (2004) Factors controlling groundwater quality in Eastern United Arab Emirates: a chemical and isotopic approach. Jour. Hydrol., v.286, pp.227–235.

    Article  Google Scholar 

  • Nadler, A., Magaritz, M. and Mazar, E. (1981) Chemical reactions of seawater with rocks and freshwater-experimental and field observations on brackish waters in Israel. Geochim. Cosmochim. Act., v.44, pp.879–886.

    Article  Google Scholar 

  • Pacheco Fal, Szocs, T. (2006) Dedolomitization reactions driven by anthropogenic activity on loessy sediments, SW Hungary. Appl., Geochem., v.21, pp.614–631.

    Article  Google Scholar 

  • Piper, A.M. (1944) A graphic procedure in the geochemical interpretation of wateranalysis. Trans. Am. Geophys., Union, v.25, pp.914–923.

    Google Scholar 

  • Polemio, M., Dragone, V. and Limoni, P.P. (2006) Salt contamination in Apulian aquifer: spatial and time trend. Proceedings of 1st SWIM-SWICA (19th salt water intrusion meeting-3rd salt water intrusion in coastal aquifers), Cagliari. pp.119–125.

  • Pulido-Leboeuf, P. (2004) Seawater intrusion and associated processes in a small coastal complex aquifer (Castell de Ferro, Spain). Appl. Geochem. v.19, pp.1517–1527.

    Article  Google Scholar 

  • Rajmohan, N., Al-Futaisi, A. and Jamrah, A. (2007) Evaluation of long-term groundwater level data in regular monitoring wells, Barka, Sultanate of Oman. Hydrol. Process., v.2z, pp.3367–3379.

    Article  Google Scholar 

  • Re, V., Faye, S.C., Faye, A., Faye, S., Gaye, C.B., Sacchi, E., Zuppi, G.M. (2011) Water quality decline in coastal aquifers under anthropic pressure: the case of a suburban area of Dakar (Senegal), Environ Monit Assess., v.172. pp.605–622. DOI 10.1007/s10661-010-1359-x.

    Article  Google Scholar 

  • Richter, B.C., Kreitler, C.W. and Bledsoe, B.E. (1993) Geochemical techniques for identifying sources of groundwater salinization. CRC, New York, 272p.

    Google Scholar 

  • Sami, K. (1992) Recharge mechanisms and geochemical processes in a semi-arid sedimentary basin, Eastern Cape, South Africa. Jour. Hydrol., v.139, pp.27–48.

    Article  Google Scholar 

  • Shaji, E., Vinayachandran, N. and Thambi, D.S. (2009) Hydrogeochemical Characteristics of Groundwater in Coastal Phreatic Aquifers of Alleppey District, Kerala. Jour. Geol. Soc. India., v.74, pp.585–590.

    Article  Google Scholar 

  • Spears, D.A. (1986) Mineralogical control of the chemical evolution of groundwater. In: S.T. Trudgill (Ed.), Solute processes. Wiley, Chichester UK, 512p.

    Google Scholar 

  • Stallard, R.F. and Edmond, J.M. (1983) Geochemistry of the Amazon river. The influence of the geology and weathering environment on dissolved load. Jour. Geophys. Res., v.88, pp.9671–9688.

    Article  Google Scholar 

  • Subba Rao, N., Saroja Nirmala, I. and Suryanarayana, K. (2005) Groundwater quality in a coastal area: a case study from Andhra Pradesh, India. Environ. Geol. v.48. pp.543–550, DOI 10.1007/s00254-005-1306-2.

    Google Scholar 

  • Tijani, M.N. (2004) Evolution of saline waters and brines in the Benue-Trough, Nigeria. Applied Geochem., v.19, pp.1355–1365.

    Article  Google Scholar 

  • Vengosh, A., Starinsky, A., Melloul, A., Fink, M. and Erlich, S. (1991) Salinization of the coastal aquifer water by Ca-chloride solutions at the interface zone, along the Coastal Plain of Israel. Hydrological Service, Jerusalem.

    Google Scholar 

  • Zhu, G.F., Li, Z.Z., Su, Y.H., Ma, J.Z. and Zhang, Y.Y. (2007) Hydrogeochemical and isotope evidence of groundwater evolution and recharge in Minqin Basin, Northwest China. Jour. Hydrol., v.333, pp.239–251.

    Article  Google Scholar 

Download references

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Srinivasamoorthy, K., Vasanthavigar, M., Chidambaram, S. et al. Characterisation of groundwater chemistry in an eastern coastal area of Cuddalore district, Tamil Nadu. J Geol Soc India 78, 549–558 (2011). https://doi.org/10.1007/s12594-011-0122-4

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  • DOI: https://doi.org/10.1007/s12594-011-0122-4

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