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22.05.2018

Organosilicon-group-derived silica-ionogel electrolyte for lithium ion batteries

verfasst von: Yue-Jiao Li, Cui Guo, Lu-Shan Yue, Wen-Jie Qu, Nan Chen, Yu-Juan Dai, Ren-Jie Chen, Feng Wu

Erschienen in: Rare Metals | Ausgabe 6/2018

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Abstract

In order to avoid leakage problem caused by liquid electrolyte, a new ionogel electrolyte was developed by in situ immobilizing organosilicon-functionalized ionic liquid within a nanoporous silica matrix. The ionic liquid evenly coats on the surface of porous silica and fills in the silica framework pores with no strong chemical interaction. The ionogel electrolyte has the dual advantages of a silica solid support and a wide electrochemical stability window of ionic liquid (4.87 V vs. Li⁺/Li). The half-cells assembled with this electrolyte and LiFePO₄ electrode have excellent performance at room temperature and 60 °C. The Li/SiO₂-IGE/LiFePO₄ cell displays a discharge capacity of 129.1 mAh·g⁻¹ after 200 charge/discharge cycles at room temperature.

Vorheriger Artikel Rotational motion of polyanion versus volume effect associated with ionic conductivity of several solid electrolytes

Nächster Artikel Ultrathin Al2O3-coated reduced graphene oxide membrane for stable lithium metal anode

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Titel: Organosilicon-group-derived silica-ionogel electrolyte for lithium ion batteries
verfasst von: Yue-Jiao Li
Cui Guo
Lu-Shan Yue
Wen-Jie Qu
Nan Chen
Yu-Juan Dai
Ren-Jie Chen
Feng Wu
Publikationsdatum: 22.05.2018
Verlag: Nonferrous Metals Society of China
Erschienen in: Rare Metals / Ausgabe 6/2018
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI: https://doi.org/10.1007/s12598-018-1056-4

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