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Characterization and Study of Properties in a Polar Solvent of a Functionalized and Quaternized Poly(dimethylsiloxane-co-methyl-hydridosiloxane)

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Abstract

Poly(dimethylsiloxane- c o-methyl-hydridosiloxane) (PDMSMHS) with a OSi(CH 3) 2/OSi(HCH 3) molar ratio of 21:1 was functionalized with dimethylallylamine (DMAA) via catalytic hydrosilylation using Karstedt’s catalyst and then quaternized with 1-iodooctane. The functionalized and quaternized co-polysiloxanes (PDMSMHS-1 and PDMSMHS-QAS) were characterized using 1H, 13C and 29Si NMR. The physicochemical properties of the polymeric systems (the differential refractive index increment (dn/dc), the square root of the mean square radius of gyration \((< RMS_{\text {radius}}^{2}>^{1/2})\), the average molecular weight (M), and the second virial coefficient (A 2)) were measured in ethanol using gel permeation chromatography/light scattering (GPC/LS). The low percentage (3–4 %) of amino side groups has an unexpected effect on the co-polymers physicochemical properties because the A 2 experimental value for PDMSMHS-1 and PDMSMHS-QAS (8.87×10−3and 1.51×10−2molmLg −2, respectively) indicates that ethanol is a good solvent.

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Authors and Affiliations

  1. Departamento de Química, División de Ciencias Naturales y Exactas, Universidad de Guanajuato, Campus Guanajuato, Col. Noria Alta s/n, 36050, Guanajuato, Gto, México

    Antonio Guerra-Contreras, Antonio Villegas, Eulalia Ramírez-Oliva & Jorge Cervantes

  2. Departamento de Química, División de Ciencias Naturales y Exactas, Universidad de Guanajuato, Campus Guanajuato, 36050, Guanajuato, Gto, México

    Antonio Villegas

Authors
  1. Antonio Guerra-Contreras
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  2. Antonio Villegas
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  3. Eulalia Ramírez-Oliva
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  4. Jorge Cervantes
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Correspondence to Antonio Villegas.

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Guerra-Contreras, A., Villegas, A., Ramírez-Oliva, E. et al. Characterization and Study of Properties in a Polar Solvent of a Functionalized and Quaternized Poly(dimethylsiloxane-co-methyl-hydridosiloxane). Silicon 9, 525–533 (2017). https://doi.org/10.1007/s12633-015-9286-7

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  • DOI: https://doi.org/10.1007/s12633-015-9286-7

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