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Effect of Cu and Zr Co-doped SiO2 Nanoparticles on the Stability of Phases (Quartz-Tridymite-Cristobalite) and Degradation of Methyl Orange at High Temperature

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Abstract

SiO2 nanoparticles doped by 10 mol% Zr and 10 mol% Cu were prepared via the sol-gel method in a controled process. The effects of doping and calcination temperature on the structural and photo-catalytic properties of SiO2 nanopowders were studied by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and UV-Vis absorption spectroscopy. The phases of cristobalite, quartz and tridymite were found at a calcinations temperature range of 800 to 1000 °C and only cristobalite phase was formed at a temperature of 1200 °C. The degradation of methyl orange was examined under visible light radiation indicating that the effect of doped elements (Zr, Cu) on SiO2 reduces the band gap effectively.

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Authors and Affiliations

  1. Department of Materials Engineering, Sahand University of Technology, P.O. Box 51335-1996, Tabriz, Iran

    Nasrollah Najibi Ilkhechi & Mahdi Mozammel

  2. Department of Materials Engineering, Faculty of Engineering, Malayer University, Malayer, Iran

    Behzad Koozegar Kaleji

  3. Department of Physics, Faculty of Science, Malayer University, Malayer, Iran

    Nader Ghobadi

Authors
  1. Nasrollah Najibi Ilkhechi
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  2. Behzad Koozegar Kaleji
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  3. Mahdi Mozammel
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  4. Nader Ghobadi
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Correspondence to Nasrollah Najibi Ilkhechi or Behzad Koozegar Kaleji.

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Ilkhechi, N.N., Kaleji, B.K., Mozammel, M. et al. Effect of Cu and Zr Co-doped SiO2 Nanoparticles on the Stability of Phases (Quartz-Tridymite-Cristobalite) and Degradation of Methyl Orange at High Temperature. Silicon 9, 293–299 (2017). https://doi.org/10.1007/s12633-016-9416-x

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  • DOI: https://doi.org/10.1007/s12633-016-9416-x

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