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Effect of Ni Doping on the Structural and Optical Properties of TiO2 Nanoparticles at Various Concentration and Temperature

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Abstract

TiO2 nanopowders doped by Ni were prepared by sol–gel method. The effects of Ni ion (transition metal ion) doping on the physical structural and optical properties of TiO2 have been investigated by X-ray diffraction (XRD), scanning electron microscopy and UV–Vis absorption spectroscopy. XRD results suggest that adding impurities has a significant effect on anatase phase stability, crystallinity, and particle size of TiO2. The phase transformation from anatase to rutile was inhibited by Ni ion doped TiO2 at temperatures 675 °C. The lowest band gap value (2.83 eV) was obtained for TiO2-4%Ni sample calcined at 675 °C.

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References

  1. Gopal M, Moberly Chan WJ, De Jonghe LC (1997) Room temperature synthesis of crystalline metal oxides. J Mater Sci 32(22):6001–6008

    Article  CAS  Google Scholar 

  2. Najibi Ilkhechi N, Koozegar Kaleji BS https://doi.org/10.1007/s12633-015-9363-y

    Article  Google Scholar 

  3. Weast RC (1984) Handbook of chemistry and physics. CRC Press, Boca Raton. B–154-155

    Google Scholar 

  4. Kostov I (1973) Minerology, 3rd edn. Nauka, Izkustia, Sofia

    Google Scholar 

  5. Fujishima A, Honda K (1972) Electrochemical photolysis of water at a semiconductor electrode. Nature 238(5358):37

    Article  CAS  Google Scholar 

  6. Wang CY, Liu CY, Shen T (1997) The photocatalytic oxidation of phenylmercaptotetrazole in TiO2 dispersions. J Photochem Photobiol A Chem 109(1):65–70

    Article  CAS  Google Scholar 

  7. Palmer FL, Eggins BR, Coleman HM (2002) The effect of operational parameters on the photocatalytic degradation of humic acid. J Photochem Photobiol A Chem 148(1–3):137–143

    Article  CAS  Google Scholar 

  8. Ilkhechi NN, Ghobadi N (2016) Comparison of structural, optical, photocatalytic behavior and hydrophilic properties of pure and Sn/La co-doped TiO2 thin films. J Mater Sci Mater Electron 27(11):12050–12059

    Article  CAS  Google Scholar 

  9. Ilkhechi NN, Kaleji BK (2016) Effect of Cu2+, Si4+ and Zr4+ dopant on structural, optical and photocatalytic properties of titania nanopowders. Opt Quant Electron 48(7):347

    Article  Google Scholar 

  10. Hermann J. (1999) Heterogeneous photocatalysis: Catal Today 53:115–129

    Google Scholar 

  11. Hwang KS, Jeong JH, Ahn JH, Kim BH (2006) Hydrophilic/hydrophobic conversion of Ni-doped TiO2 thin films on glass substrates. Ceram Int 32(8):935–937

    Article  CAS  Google Scholar 

  12. Kaleji BK, Alijani M, Aghaei A (2016) Sn/Ce co-doping of TiO2 nanoparticles: influence of dopants concentration on optical and structural characteristics. J Mater Sci Mater Electron 27(8):8524–8531

    Article  CAS  Google Scholar 

  13. Alijani M, Kaleji BK, Rezaee S (2017) Improved visible light photocatalytic activity of TiO2 nano powders with metal ions doping for glazed ceramic tiles. Opt Quant Electron 49(6):225

    Article  Google Scholar 

  14. Supha C, Boonto Y, Jindakaraked M, Ananpattarachai J, Kajitvichyanukul P (2015) Long-term exposure of bacterial and protozoan communities to TiO2 nanoparticles in an aerobic-sequencing batch reactor. Sci Technol Adv Mater 16(3):034609

    Article  Google Scholar 

  15. Alijani M, Kaleji BK, Rezaee S (2017) Highly visible-light active with Co/Sn co-doping of TiO2 nanoparticles for degradation of methylene blue. J Mater Sci Mater Electron 28(20):15345–15353

    Article  CAS  Google Scholar 

  16. Ilkhechi NN, Alijani M, Kaleji BK (2016) Optical and structural properties of TiO2 nanopowders with Co/Ce doping at various temperature. Opt Quant Electron 48(2):148

    Article  Google Scholar 

  17. Linsebigler AL, Lu G, Yates Jr. JT (1995) Photocatalysis on TiO2 surfaces: principles, mechanisms, and selected results. Chem Rev 95(3):735–758

    Article  CAS  Google Scholar 

  18. Lim Y-M, Jeong JH, An JH, Jeon YS, Jeon KO, Hwang KS, Kim BH (2005) Nickel-doped titanium oxide films prepared by chemical solution deposition. J Ceram Process Res 6(4):302

    Google Scholar 

  19. Kim Y-S, Chung Y-C, Lee KS (2006) The electronic structure of Ni doped rutile TiO2. J Electroceram 17(2–4):951–953

    Article  CAS  Google Scholar 

  20. Carp O, Huisman CL, Reller A (2004) Carbon-Inorganic hybrid materials: the carbon nanotube/TiO2 interface. Solid Prog State Chem 32:42

    Article  Google Scholar 

  21. Nakai I, Sasano M, Inui K, Korekawa T, Ishijima H, Katoh H, Li YJ, Kurisu M (2013) Oxygen vacancy and magnetism of a room temperature ferromagnet Co-doped TiO2. J Korean Phys Soc 63(3):532–537

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Materials Engineering, Malayer University, Malayer, Iran

    Mahnaz Alijani

  2. Faculty of Material Engineering, Sahand Univercity of Technology, Tabriz, Iran

    Nasrollah Najibi Ilkhechi

Authors
  1. Mahnaz Alijani
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  2. Nasrollah Najibi Ilkhechi
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Correspondence to Mahnaz Alijani.

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Alijani, M., Ilkhechi, N.N. Effect of Ni Doping on the Structural and Optical Properties of TiO2 Nanoparticles at Various Concentration and Temperature. Silicon 10, 2569–2575 (2018). https://doi.org/10.1007/s12633-018-9792-5

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  • DOI: https://doi.org/10.1007/s12633-018-9792-5

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