Abstract
Novel chemiresistive gas sensors based on graphene/Al2O3 quantum dots composites were fabricated and examined for carbon dioxide sensing. Composite samples with different wt% of graphene (20–80 wt%) mixing in constant 1 g Al2O3 were prepared and characterized by X-ray diffraction, transmission electron microscopy along with selected area electron diffraction, ultraviolet–visible spectroscopy, fluorescence spectroscopy and thermo gravimetric-differential thermal analysis. The experimental results showed that the graphene/Al2O3-based chemiresistor exhibited much higher sensing response and it enhanced linearly with addition of graphene. The gas sensing mechanism was discussed on the basis of defect chemistry through fluorescence measurements. 80 wt% graphene/Al2O3 composite exhibited good sensing response (10.84) at room temperature, low operating temperature (398 K), fast response time (14 s) and recovery time (22 s) along with good stability.
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C Booth, D McDonald and P Walsh Marine Biol. Lett. 5 347 (1984)
R Desai, D Lakshminarayana, P Patel and C J Panchal Sens. Actuators B 107 523 (2005)
J Herran, G G Mandayo and E Castano Sens. Actuators B 129 705 (2008)
C Bai, J Wang, G Yang and Y Yang Indian J. Phys. 87 133 (2013); Z Wu et al. Sens. Actuators B 178 485 (2013)
A K Geim Science 324 1530 (2009)
H E Romero et al. Nanotechnology 20 245501 (2009)
F Schedin et al. Nat. Mater. 6 652 (2007)
Y Li et al. J. Am. Chem. Soc. 134 15 (2012)
M. Mahdizadeh-Rokhi Indian J. Phys. 87 517 (2013); S A Waghuley Indian J. Pure Appl. Phys. 49 816 (2011)
G Y Chai et al. Sens. Actuators A 176 64 (2012)
G Telipan, M Ignat, C Tablet and V Parvulescu Adv. Mater. 10 2138 (2008)
G Jimenez-Cadena, J Riu and F X Rius Analyst 132 1083 (2007)
P K Panda, V A Jaleel and G Lefebvre Mater. Sci. Engineering A 485 558 (2008)
N P Damayanti J Sol-Gel Sci. Technol. 56 47 (2010)
P Konttinen and P D Lund Sol. Ener. Mater. Solar Cell 82 361 (2004)
A S Chellappa, C M Fischer and W J Thomson Appl. Catal. A 227 231 (2002)
Y Fan et al. Carbon 48 1743 (2010)
Z Jiang, J Wang, L Meng, Y Huang and L Liu Chem. Commun. 47 6350 (2011)
B M Venkatesan et al. ACS Nano 24 441 (2012)
O Lupan et al. Sens. Actuators B 144 56 (2010)
S Pati, S B Majumder and P Banerji J. Alloys Comp. 541 376 (2012)
K R Nemade and S A Waghuley J. Electron. Mater. 42 2857 (2013)
H J Yoon, D H Jun, J H Yang, Z Zhou, S S Yang and M M Cheng Sens. Actuators B 157 310 (2011)
K R Nemade and S A Waghuley Int. J. Modern Phys.: Conf. Series 22 380 (2013)
J Liu, H Bai, Y Wang, Z Liu, X Zhang and D D Sun Adv. Funct. Mater. 20 4175 (2010)
M Feng, H B Zhan and Y Chen Nanotech. 21 075601 (2010)
S A Waghuley, S M Yenorkar, S S Yawale and S P Yawale Sens. Actuators B 128 366 (2008)
T Kuila, S Bose, A K Mishra, P Khanra, N H Kim and J H Lee Prog. Mat. Sci. 57 1061 (2012)
K R Nemade and S A Waghuley Results in Phys. 3 52 (2013)
S S Nath, M Choudhury, G Gope and R K Nath Nanotrends 8 1 (2010)
H Ke-long, Y Liang-guo, L Su-qin and L Chao-jian Trans. Nonferrous Met. Soc. 17 633 (2007)
L K Bangal, J Y Patil, I S Mulla and S S Suryavanshi Ceramics Int. 38 4835 (2012)
M W Ahn et al. Appl. Phys. Lett. 93 263103 (2008)
K R Nemade and S A Waghuley Solid State Sciences 22 27 (2013)
J Wang, Y Kwak, I Lee, S Maeng and G Kim Carbon 50 4060 (2012)
K Fan, H Qin, L Wang, L Ju and J Hu Sens. Actuators B 177 265 (2013)
K R Nemade and S A Waghuley J. Chinese Adv. Mater. Soc. 1 219 (2013)
M Morio, T Hyodo, Y Shimizu and M Egashira Sens. Actuators B 139 563 (2009)
Acknowledgments
Authors are very much thankful to Head, Department of Physics Sant Gadge Baba Amravati University, Amravati for providing necessary facilities. Nemade is thankful to Sant Gadge Baba Amravati University, Amravati for financial support through the Late M N Kale scholarship (2012).
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Nemade, K.R., Waghuley, S.A. Highly responsive carbon dioxide sensing by graphene/Al2O3 quantum dots composites at low operable temperature. Indian J Phys 88, 577–583 (2014). https://doi.org/10.1007/s12648-014-0454-1
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DOI: https://doi.org/10.1007/s12648-014-0454-1