Integrated geophysics and soil gas profiles as a tool to characterize active faults: the Amer fault example (Pyrenees, NE Spain)

The combined use of geophysical and soil gas composition exploration methods allows to rapidly obtain at relative low cost information that might be related to seismic activity conditions. In this study, we carried out geochemical soil gas sampling (²²²Rn, ²²⁰Rn and CO₂), electrical resistivity tomography and seismic refraction profiles in two selected zones near the town of Amer in the Spanish Pyrenees, where the presence of recent fractures is evident in the field. Data analysis clearly reveals anomalous values for each gas at specific positions along the electrical imaging transects. Geomorphologic and hydrogeologic data and the integration of geophysical data and soil gas measurements indicate that: (1) endogene gases radon (²²²Rn) and carbon dioxide (CO₂) are released from the meta-sedimentary basement rocks across the main fractured zones with higher permeability values, while lower Cenozoic detrital sedimentary formations act as an impervious boundary; (2) sites with highest radon concentrations (52 kBq m⁻³) coincide with the zones in the Amer fault showing more recent geomorphic evidence of activity, and more specifically with those areas covered by thinner surficial formations; (3) the lowest ²²²Rn values (0.2–0.4 kBq m⁻³) were recorded just on the master active fault plane. This pattern could be explained by a dilution effect resulting from high rates of soil CO₂ efflux (267 g m⁻² day⁻¹); (4) soil thoron (²²⁰Rn) activity is maximum (143 kBq m⁻³) in areas with high surficial fracturing; (5) groundwater pumping may cause important distortions in the natural flow dynamics and in the measured concentrations of gases. The agreement between the different data (geochemical, geophysical, and hydrogeological) and field observations (geology and geomorphology) leads us to propose a preliminary tectonic-gravitational model for the study area.