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Effect of Nitrogen-Functional Groups on the ORR Activity of Activated Carbon Fiber-Polypyrrole-Based Electrodes

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Abstract

Polypyrrole (PPy) coatings inside the microporosity of an activated carbon fiber (ACF) were synthesized by chemical polymerization obtaining ACF-PPy composites. N-doped ACFs were prepared by carbonization of the ACF-PPy composites at two temperatures (500 and 800 °C). All the samples were characterized using different techniques (XPS, SEM, elemental analysis, physical adsorption of N2, cyclic voltammetry, etc.). The electrochemical characterization in alkaline medium shows that the N-doped ACFs have a similar specific capacitance than the pristine ACF, in spite of the lower specific surface area. The materials were used as electrodes in the oxygen reduction reaction (ORR) in alkaline medium using the rotating ring-disk electrode (RRDE) and linear sweep voltammetry (LSV) tests. It was found that the N-doped ACF material carbonized at 800 °C has higher catalytic activity than the pristine ACF. The investigation also indicates that the ORR process on the N-doped ACF materials proceeds through an indirect two-electron pathway.

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Funding

The authors thank MINECO, GV, and FEDER for financial support (projects MAT2016-76595-R, CTQ2015-66080-R (MINECO/FEDER)). ACRP thanks GV for a Santiago Grisolía fellowship (GRISOLIA/2012/009).

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Authors and Affiliations

  1. Departamento de Química Física and Instituto Universitario de Materiales, Universidad de Alicante, Apartado 99, 03080, Alicante, Spain

    Ana Cristina Ramírez-Pérez & Emilia Morallón

  2. Departamento de Química Inorgánica and Instituto Universitario de Materiales, Universidad de Alicante, Apartado 99, 03080, Alicante, Spain

    Javier Quílez-Bermejo & Diego Cazorla-Amorós

  3. Instituto de Ingeniería Electroquímica y Corrosión and CONICET, Universidad Nacional del Sur, Av. Alem 1253, B8000CPB, Bahía Blanca, Argentina

    Juan Manuel Sieben

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  1. Ana Cristina Ramírez-Pérez
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  2. Javier Quílez-Bermejo
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  3. Juan Manuel Sieben
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  5. Diego Cazorla-Amorós
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Correspondence to Emilia Morallón.

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Ramírez-Pérez, A.C., Quílez-Bermejo, J., Sieben, J.M. et al. Effect of Nitrogen-Functional Groups on the ORR Activity of Activated Carbon Fiber-Polypyrrole-Based Electrodes. Electrocatalysis 9, 697–705 (2018). https://doi.org/10.1007/s12678-018-0478-y

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