Abstract
In this study, the characterization of solid waste and the effect of the leachate from an open dumping site in Ariyamangalam, Tiruchirappalli District, Tamil Nadu, on groundwater is investigated. A total of 14 groundwater samples and 20 leachate samples were collected for monitoring purpose. All the samples were analyzed for various physical and chemical parameters according to standard methods: this includes pH, electrical conductivity, total dissolved solids (TDS), total hardness, and total alkalinity, major cations such as Ca2+, Mg2+, and Fe2+, major anions such as NO3−, Cl−, and SO42− and heavy metals such as Cd, Cu, Mn, Pb, and Zn. The results indicated that, very few parameters such as pH, sulfates and nitrates concentration in the groundwater samples are within the recommended maximum admissible limits approved by WHO (World Health Organization 940–949, 2002) and Bureau of Indian standards (IS 10500:1991). The TDS (range between 740 and 14,200 mg/L) in groundwater reveal the saline behavior of water and was found to be very high according to standards. The range of chlorides in all the locations under investigation is 215.15–4,098.73 mg/L. The contour plots also indicated that the groundwater was rigorously contaminated with various heavy metals. The presence of high concentration of Pb (0.59 mg/L) in groundwater samples nearby dumping site implies that groundwater samples were contaminated by leachate migration from an open dumping site.
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Introduction
The generation of solid waste has become an increasing environmental and public health problem everywhere in the world, particularly in developing countries. The fast expansion of urban, agricultural and industrial activities spurred by rapid population growth and the change in consumer habits has produced vast amounts of solid wastes (Akoteyon et al. 2011). Open dumps are the oldest and the most common way of disposing of solid waste. In recent years thousands have been closed, while many still are being used. In many cases, they are located wherever land is available, without regard to safety, health hazard and esthetic degradation. The waste is often piled as high as equipment allows. In some instances, the refuse is ignited and allowed to burn. In others, the refuse is periodically leveled and compacted (Sabahi et al. 2009). The dumping of solid waste in uncontrolled landfills can cause significant impacts on the environment and human health (Dong et al. 2008). The most commonly reported danger to the human health from these landfills is from the use of groundwater that has been contaminated by leachate (Jhamnani and Singh 2009).
Leachate is produced when moisture enters the refuse in a landfill, extracts contaminants into the liquid phase, and produces moisture content sufficiently high to initiate liquid flow. Leachate is generated in a landfill as a consequence of the contact of water with solid waste (Lo 1996). Leachate from a solid waste disposal site is generally found to contain major elements like calcium, magnesium, potassium, nitrogen and ammonia, trace metals like iron, copper, manganese, chromium, nickel, lead and organic compounds like phenols, polyaromatic hydrocarbons, acetone, benzene, toluene, chloroform, etc. (Freeze and Cherry 1979). The concentration of these in the leachate and water depends on the composition of wastes (Alker et al. 1995). The rate and characteristics of leachate produced depends on many factors such as solid waste composition, particle size, degree of compaction, hydrology of site, age of landfill, moisture and temperature conditions, and available oxygen. Leachate tended to migrate in surrounding soil may result in contamination of underlying soil and groundwater (Jhamnani and Singh 2009). Leachate migrations from waste sites or landfills and the release of pollutants from sediment (under certain conditions) pose a high risk to groundwater resource if not adequately managed. Their impact on groundwater continues to raise concern and have become the subject of recent and past investigations (Ahmed and Sulaiman 2001; Fatta et al. 1999; Kjelsen et al. 1998; Bjerg et al. 1995; Robinson and Gronow 1992; Cariera and Masciopinto 1998; Loizidou and Kapetanios 1993; Gallorini et al. 1993; Khan et al. 1990; Kunkle and Shade 1976). Empirical investigations as well as modeling techniques (McCreanor and Reinhart 2000; Lee et al. 1997; Syriopoulou and Koussis 1987; Koussis et al. 1989; Ostendorf et al. 1984) have been used to assess the pollution of groundwater by leachate from a landfill.
Groundwater is an important source of drinking water for humankind. It contains over 90 % of the fresh water resources and is an important reserve of good quality water. Groundwater, like any other water resource, is not just of public health and economic value; it also has an important ecological function (Armon and Kitty 1994). The chemical composition of groundwater is a measure of its suitability as a source of water for human and animal consumption, irrigation, and for industrial and other purposes (Babiker et al. 2007). Therefore, monitoring the quality of water is important because clean water is necessary for human health and the reliability of aquatic ecosystems.
This study aims to develop an understanding of the natural groundwater quality in the Ariyamangalam open dumping site and the adjacent areas through the dug wells and bore wells that have been selected for this purpose. To estimate how far groundwater quality has been affected by the downward movement of leachate from the Ariyamangalam open dumping site, the surrounding groundwater samples were collected and analyzed for various physicochemical parameters. The heavy metals distribution profile in the groundwater system at the waste disposal site was also studied.
Study area
Tiruchirappalli, better called as Trichy, is the fourth largest municipal corporation in Tamil Nadu and also the fourth largest urban agglomeration in the state. Kaveri River flows through the length of the district and is the principal source of irrigation and water supply. The district has an area of 4,404 km2. The district has an approximate population of 27 lakhs and the population density of 602 inhabitants per square kilometer. The maximum temperature experienced in this district is 37.7 °C and the minimum temperature is 18.9 °C. The normal annual rainfall is 842.60 mm. The Trichy district is served by an open dumping yard namely Ariyamangalam garbage ground located 12 km from the city on the Trichy–Thanjavur highway. The dumping site is located at 10°48′ N and 78°43′ E. The ground elevation of the dumping site is 75.875 m above mean sea level. The Ariyamangalam dumping site has been in operation since 1967, covering a total surface area of 47.7 acres where the geological formation consists of mainly alluvium (based on the data collected from Public Works Department, Tamilnadu). The Tiruchirappalli municipal corporation consists of four zones namely Srirangam, Ponmalai, Ariyamangalam, and Abishegapuram. The dump site receives approximately 400–470 tonnes of MSW per day, which are collected from four zones. The height of dump is around 3–4 m above ground level. The waste is disposed here without segregation and compaction. The deposited waste is not provided by any daily or intermediate covers. No lining is provided at the bottom of the dump yard to prevent leachate migration. Access to the site is freely available to all and the site is regularly utilized by rag pickers, scavenging for recyclable materials, and by a variety of animals including water buffaloes, cattle, pigs, and dogs scavenging food waste. Unhygienic drinking water and garbage-induced diseases, like dysentery, cholera and hepatitis, are frequently reported in the surrounding villages. The layout of the study area is shown in Fig. 1.
Methodology
Solid waste composition
To appraise the fresh solid waste composition, a total of 60 fresh solid waste samples (three samples from each zone per day) from four different zones of Trichy city were collected for 5 days from the truck discharge point to the dumping site. The collected fresh solid waste were segregated into different categories viz. paper, plastics, metals, glass, debris, vegetables, textiles, etc. The segregated samples were weighed individually (Mohan and Gandhimathi 2009). The mean of the solid waste composition was calculated using the results of the composition of each of the sorting samples (Gidarakos et al. 2005).
Sampling of leachate and groundwater
Leachate samples from the actual leachate streams in the solid waste dumping site were collected in 5 L polypropylene carboys that were rinsed out thrice prior to sample collection, transported to the laboratory, stored at 4 °C and analyzed within 2 days. A total of 20 leachate samples were collected for monitoring purpose, out of which 11 samples were collected from the old dumping area (greater than 3 years old) referred to as “stabilized leachate” whereas the remaining nine samples of leachate called as “fresh leachate” were collected near the new dumping area (less than or equal to 2 years old). The physicochemical analyses were carried out according to the standard methods (APHA 1998). A random sampling method was employed to collect the groundwater samples with due consideration to represent land-use patterns, topography, and areas close to dumping site (Kale et al. 2010). Groundwater samples of totally 14 numbers (4 hand pumps, 7 bore wells and 3 open wells) were collected within 1.7 km from the dumping site. The details of groundwater sampling locations are given in Table 1. The spatial data was obtained from the data recorded by a Garmin Global Positioning System. The groundwater sampling locations with the study area is shown in Fig. 1. Water was collected from open wells using drawing buckets tied with ropes, while bore wells and tube wells were pumped for 5–15 min before sampling (Andrew et al. 2011). These samples were collected in pre-cleaned polypropylene containers of 2 L capacity after rinsing with the sample and preserved airtight to avoid evaporation, stored at 4 °C and analyzed within 2 days.
The pH and electrical conductivity (EC) were recorded on site at the time of sampling with digital pH meter and digital EC meter, respectively. For heavy metal analyses, samples were separately collected in pre-washed polypropylene containers of 100 ml capacity and acidified onsite to avoid precipitation of metals.
Analytical methods
The parameters were selected based on their relative importance in municipal landfill leachates composition, and their pollution potential on groundwater resource in particular (Bagchi 2004). The physicochemical parameters such as total dissolved solids (TDS), total alkalinity (TA), total hardness (TH), major cations such as calcium (Ca2+) and magnesium (Mg2+), major anion such as chlorides (Cl−) of the leachate and groundwater samples were analyzed by titrimetric methods. Chloride was included in the water quality assessment because of its measure of extent of dispersion of leachates in groundwater body (Chapman 1992). Sulfates (SO42−) in the groundwater samples were analyzed by nephelometric turbidity method (APHA 1998). Nitrates (NO3−) and total organic carbon (TOC) determination in the groundwater samples were carried out by DR 2700 spectrometer. Estimation of chemical oxygen demand (COD) was done by closed reflux titrimetry method, while biochemical oxygen demand (BOD) was calculated by oxygen determination by Winkler titration for the preserved leachate sample. All the analyses in this study were repeated two or three times until concordant values were obtained, and all the tests were carried out according to the standard methods (APHA 1998). The data was statistically analyzed by setting up and calculating a correlation matrix for the various parameters using Statistical Package for Social Sciences (SPSS) software package (Norusis 1997).
The heavy metals such as Cd, Cu, Mn, Pb and Zn concentrations in the leachate and ground water samples were analyzed using atomic absorption spectrophotometer (AAS) supplied by Thermo Fisher Scientific, USA with D2 background correction lamp. Standard solutions of heavy metals viz. copper (Cu), cadmium (Cd), manganese (Mn), lead (Pb) and zinc (Zn) were prepared with distilled water using copper sulfate (CuSO4·5H2O), cadmium sulfate (CdSO4·8H2O), manganese sulfate (MnSO4·7H2O), lead nitrate [Pb(NO3)2], and zinc nitrate [Zn(NO3)2·6H2O].
Results and discussion
Composition of municipal solid waste
The results from the composition studies (Fig. 2) show that samples from Ariyamangalam dumping site contained about 90–95 % combustible materials such as paper, textiles, plastic, debris, metals, glass, and vegetable waste. The non-combustible fraction such as metals and glass is about 1–5 %. The results were compared with solid waste composition reported by other researchers. Mohan and Gandhimathi (2009) reported that the MSW composition from Perungudi dumping site (Chennai City, Tamil Nadu) contained about 60–70 % combustible materials such as textile, leaves, plastics, food waste, etc., with an average of 65 %. The non-combustible fraction such as metals and glass was about 30–40 % with an average of 35 %. The solid waste composition in most Asian countries is highly biodegradable, mainly composed of an organic fraction with high moisture content (Visvanathan et al. 2004). Joseph et al. (2012) revealed that the biodegradable waste was high when compared to non-biodegradable waste in MSW composition at Chennai city. The findings from other studies indicated that the composition of MSW is site-specific and based on the nature of waste and source location.
Leachate
The physicochemical characteristics and the heavy metal contamination in the collected leachate sample depend primarily upon the waste composition and water content of the municipal solid waste (MSW) (Denutsui et al. 2012). The physicochemical characteristics and heavy metal concentrations were analyzed for the collected leachate sample from Ariyamangalam open dumping site and are presented in Table 2.
From the Table 2, it can be observed that the fresh leachate sample possesses very high concentration of chemical parameters except pH, when compared to stabilized leachate samples. The pH value of the fresh samples was observed in the range of 6.96–7.77, but the older samples were amber colored and alkaline with pH range from 7.68 to 8.33. This may be attributed to the decrease in the concentration of free volatile acids due to anaerobic decomposition, as fatty acids can be partially ionized and contribute to higher pH values. Alkaline pH is normally encountered at landfills, 10 years after disposal (El-Fadel et al. 2002). The relatively high value of electrical conductivity (57,000 μ mho/cm) indicates the presence of dissolved inorganic materials in the samples. The concentration of TDS (60,970 mg/L) also fluctuates widely. Other inorganic contaminants also follow the trend of decreasing concentrations with increasing leachate age and stability. In general, leachate generated from young acidogenic landfills are characterized by high concentrations of organic and inorganic pollutants (Calli et al. 2005). The presence of Magnesium in the leachate is due to the disposal of construction waste along with MSW (Al-Yaqout 2003). The calcium and magnesium concentrations exhibited typical trends of constituents affected by the biological activity in the dumping site. A reduction with time is attributed to the depletion of these compounds and to the increase in pH, thus reducing their solubility in leachate, and enhancing precipitation. The initial concentrations of these parameters are on the higher side (1,200–3,000 mg/L, 250–1,500 mg/L). A decrease in concentration was observed in stabilized leachate samples. The chloride concentration in the leachate varied from 1,000 to 8,000 mg/L for young leachate samples and 1,000–6,500 mg/L for stabilized samples. The possible anthropogenic sources of chloride are kitchen wastes from households, restaurants, and hotels. TA varies between 4,500 and 26,000 mg/L. The presence of high BOD (43,328 mg/L) and COD (75,840 mg/L) indicates the high organic strength. This indicates that majority of the organic compounds is biodegradable (Fatta et al. 1999). The presence of Fe (400 mg/L) in the leachate sample indicates that steel scraps are also dumped in the landfill. The dark brown color of the leachate is mainly attributed to the oxidation of ferrous to ferric form and the formation of ferric hydroxide colloids and complexes with fulvic/humic substance (Chu et al. 1994).
The concentration range of trace elements such as Cd, Cu, Fe, Mn, Pb, and Zn were found in the collected leachate samples and are also reported in Table 2. Fresh leachate samples showed a higher degree of metal solubilization, due to lower pH values caused by the biological production of organic fatty acids. As the dumping site age increased, the consequent increase in pH values caused a certain decrease in metal solubility (Mohan and Gandhimathi 2009). The stabilized leachate samples have less concentration when compared to fresh leachate samples. The concentration of Zn (4.80 mg/L) in the leachate shows that the dumping site receives waste from batteries and fluorescent lamps. The presence of Pb in the leachate samples are in the range 1.85–5.15 mg/L. The possible source of lead may be batteries, chemicals for photograph processing, older lead-based paints and lead pipes disposed at the landfill, which indicates toxicity to all forms of life at this level. Acidity in the leachate causes lead to be released from refuse (Al-Yaqout 2003). Cd (1.4 mg/L) and Cu (1.92 mg/L) are also present in the leachate samples whereas high Mn (8.18 mg/L) concentrations suggest a strong reducing environment. A variety of waste is dumped at Ariyamangalam open dump site, which likely indicate the origin of Mn, Pb, Cu, Cd, and Fe in leachate.
Groundwater assessment
The collected groundwater samples in and around the dumping site were free from color and odor excluding the locations W3 and W12. The groundwater of the studied area is used for drinking and domestic purposes. Table 3 shows the desirable and maximum permissible limit of individual species for drinking water recommended by Bureau of Indian Standards (BIS 1991) and World Health Organization (2002). The physicochemical concentrations of collected groundwater samples for the various parameters are shown in Figs. 3, 4, 5. The pH values of all groundwater samples are within the range of BIS and WHO standards. EC is the indicator of dissolved inorganic ions in groundwater. The presence of EC in the studied area ranges between 802 (W8) and 12,680 (W2) μ mho/cm and was found to be high, especially at locations W1, W2, W3, and W9. These high conductivity values measured in the underground water near the dumping site are an indication of its effect on groundwater. The TDS in groundwater reveal the saline behavior of water. According to classification by Rabinove et al. (1958), two samples were non saline (TDS value less than 1,000 mg/L); nine samples were in the slightly saline category (TDS value range between 1,000 and 3,000 mg/L) and two samples were in moderately saline category (TDS value range between 3,000 and 10,000 mg/L). Only one sample was very saline in nature (W2) with the value exceeding 10,000 mg/L. This high value of TDS may be due to the leaching of various pollutants into the groundwater.
Hardness is normally expressed as the total concentration of calcium and magnesium in mg/L, equivalent of CaCO3. According to Durfor and Becker’s (1964) classification of TH, only one groundwater sample (W7) was moderately hard among the 14 sampling locations. The remaining groundwater samples were very hard (greater than 180 mg/L as CaCO3) in nature. Multivalent cations, particularly magnesium and calcium, are often present at a significant concentration in natural water. These ions are easily precipitated and in particular react with soap to make it difficult to remove scum. The calcium concentration in groundwater samples were beyond acceptable limit in two locations (W1 and W9). In most of the locations, magnesium content plays a major role and ranges between 7.2 and 81.6 mg/L. The TA was higher than the acceptable limit of 200 mg/L as CaCO3 in all sampling locations. The high alkalinity imparts an unpleasant taste and may be deleterious to human health along with the high pH, TDS, and TH. Enhanced rock water interaction during post-monsoon could also contribute (to a limited extent) toward the increased values in bicarbonate (Pawar 1993).
The range of chlorides in all the locations under investigation is 215.15 (W8) to 4,098.73 (W2) mg/L. The concentration of chlorides in all locations except W8 exceeds the permissible level described by IS 10500-1991. Chloride in reasonable concentration is not harmful, but it causes corrosion in concentrations above 250 mg/L, while at about 400 mg/L, it causes a salty taste in water. An excess of chloride in water is usually taken as an index of pollution and considered as tracer for groundwater contamination (Loizidou and Kapetanios 1993).The chloride values in the water samples maybe due to the dissolution of rocks surrounding the aquifer and probably due to the leakage of sewage and anthropogenic pollution (agricultural activities). High concentration of chloride gives salty taste to water and may result in hypertension, osteoporosis, renal stones, and asthma (McCarthy 2004). The high chloride content in groundwater is from pollution sources such as domestic effluents, fertilizers, septic tanks, and leachates (Mor et al. 2006). Agricultural fertilizers and leachate are the main sources of sulfate in groundwater. The sulfate concentration in groundwater is within BIS and WHO standards for all the collected samples. Similarly, the nitrate concentration was also within the permissible limit (45 mg/L) in all the sampling locations except location 1 (W1). In general, the major sources for nitrate in groundwater include domestic sewage, runoff from agricultural fields, and leachate from landfill sites (Pawar and Shaikh 1995; Jawad et al. 1998; Lee et al. 2003; Jalali 2005). Higher concentration of NO3− in water causes a disease called “Methaemoglobinaemia” also known as “Blue-baby Syndrome”. This disease particularly affects infants that are up to 6 months old (Kapil et al. 2009). The presence of TOC values ranges from 2.7 to 49 mg/L indicates that the groundwater contains organic impurities. The concentration of Fe in the groundwater samples varies from below detectable limit (BDL) to 5.102 mg/L (Fig. 5) and was found to be well above the WHO permissible limit (0.3 mg/L) in all the samples. Presence of Fe in water can lead to change of color of groundwater (Rowe et al. 1995).
The contour diagrams show (Figs. 6, 7, 8, 9, 10) the concentration profile of heavy metals at several water sample locations near the study area. The contour diagrams were drawn by surfer software. The collected groundwater samples were analyzed for heavy metals such as Cd, Cu, Mn, Pb, and Zn. Cadmium concentrations in the collected groundwater samples are lower than that of the leachate. The presence of cadmium concentration (Fig. 6) exceeds the permissible limit of 0.01 mg/L in all the collected samples. From the Fig. 6, it was observed that the contaminant species from the waste disposal site had migrated and accumulated at the location W6. Figure 7 shows the contour diagram of Cu distribution contaminant species from the location W3, it was located near an open dumping site toward southwest of the study area. From the Fig. 9, it was found that the presence of high concentration of Pb (0.59 mg/L) in groundwater samples nearby dumping site implies that groundwater samples were contaminated by leachate migration from an open dumping site. The concentrations of Zn (Fig. 10) in the collected samples were within the permissible limit.
Based on the contour diagram (from Figs. 6, 7, 8, 9, 10), the heavy metals such as lead (Pb), manganese (Mn), copper (Cu), Cadmium (Cd) showed significantly high values, which exceeded the maximum permissible concentration (MPC) as specified by WHO and BIS Standards for drinking water. Meanwhile, the zinc (Zn) was detected below the (MPC) value. The results indicated that all the collected sample locations were rigorously affected by the migration of leachate. Hence, the water is not potable for drinking purpose.
Correlation analysis for different water quality parameters
Correlation is a method used to evaluate the degree of interrelation and association between two variables (Nair et al. 2005). A correlation of +1 indicates a perfect positive relationship between two variables. A correlation of −1 indicates that one variable changes inversely with relation to the other. A correlation of zero indicates that there is no relationship between the two variables (Kapil et al. 2009). Table 4 represents the correlation matrix among ten water quality parameters of groundwater of the study area.
Electrical conductivity and Cl− show good positive correlation with major water quality parameters. The correlation (r = 0.964, p ≤ 0.01) between these two parameters for the analyzed samples in this study show a linear correlation. Equally, TA and HCO3− (r = 0.989, p ≤ 0.01) indicate the good positive correlation. Some of the other highly significant and positive correlation were found between EC—NO3− (r = 0.844, p ≤ 0.01), EC—TDS (r = 0.748, p ≤ 0.01), TDS—HCO3− (r = 0.477, p < 0.01), TDS—Cl− (r = 0.704, p ≤ 0.01), TDS—NO3− (r = 0.770, p ≤ 0.01), which also shows linear correlation. This suggested that presence of bicarbonate; chloride and nitrate in the study area greatly influence the TDS and EC. TH was also positively and significantly correlated with TA (r = 0.425, p < 0.01), HCO3− (r = 0.432, p ≤ 0.01), SO42− (r = 0.155, p ≤ 0.01), Ca2+ (r = 0.838, p ≤ 0.01) and Mg2+ (r = 0.882, p ≤ 0.01). This result implies that there was great dependence of hardness on calcium, magnesium, chloride, sulfate, and bicarbonate. pH was negatively correlated with all the parameters except SO42−. Similarly few other parameters were also found to have negative correlation, viz TDS—SO42− (r = −0.238), Ca2+—SO42− (r = −0.032) and Mg2+ –Cl− (r = −0.012). EC is solely a function of the major ion concentrations (Ca2+, Mg2+, Cl−, SO42−, and NO3−) of water quality parameters. The result was compared with the study reported by Kapil et al. (2009) for Indian conditions. They revealed that the major positive linear correlation was found in EC with all the water quality parameters in their study area.
Conclusion
The indiscriminate disposal and crude dumping of MSW are considered as a dangerous practice in integrated waste management at the global level. The fresh solid waste composition study shows that samples from the open dump site contained about 90–95 % combustible materials and non-combustible fraction is about 1–5 %. The fresh leachate sample possesses very high concentration of chemical parameters except pH, when compared to stabilized leachate samples. The heavy metal concentration range of collected fresh leachate sample showed a higher degree of metal solubilization when compared to stabilized leachate samples. The pH values of all groundwater samples are within the range of BIS and WHO standards. The physicochemical analysis indicated that chlorides (range between 215.15 and 4,098.73 mg/L) and TDS (ranges from 740 to 14,200 mg/L) of the groundwater samples are higher than the permissible limits in all the sampling locations when compared to other parameters. The presence of heavy metals (Pb, Mn, Cu, Cd and Zn) in groundwater samples indicates that there is appreciable contamination by leachate migration from an open dumping site. Based on the average concentration, the heavy metal components in the groundwater samples were found in the following order: Pb > Mn > Cu > Cd > Zn. From the present study, it was found that the groundwater is non-potable because most of the physicochemical parameters and heavy metals examined exceed the permissible limits. Ultimately, all results presented show that the Ariyamangalam open dump site constitutes a serious threat to local aquifers. The details such as solid waste composition, leachate characteristics and characteristics of groundwater samples will be used to develop contaminant transport model using Visual MODFLOW and MT3DMS software for leachate migration into subsurface system from open dumping site.
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Acknowledgments
We sincerely thank the Department of Science and Technology, New Delhi for the financial support rendered to carry out the research work. We also thank the Corporation of Tiruchirappalli for the permission to carry out the studies at the open dump sites.
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Kanmani, S., Gandhimathi, R. Investigation of physicochemical characteristics and heavy metal distribution profile in groundwater system around the open dump site. Appl Water Sci 3, 387–399 (2013). https://doi.org/10.1007/s13201-013-0089-y
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DOI: https://doi.org/10.1007/s13201-013-0089-y