Abstract
Poly(methyl acrylate)-poly(dimethyl siloxane)-poly(methyl acrylate) (PMA-PDMS-PMA) and poly(methyl methacrylate)-poly(dimethyl siloxane)-poly(methyl methacrylate) (PMMA-PDMS-PMMA) triblock copolymers were synthesized with atom transfer radical polymerization technique. Thermodynamic properties of block copolymer solutions were investigated. Solubility parameter differences and Flory-Huggins interaction parameters of block copolymer-solvent systems were evaluated for the membrane application. Morphology study indicated cylindrical micelles of PDMS block copolymers. X-Ray analysis confirmed phase separated morphology of PDMS block copolymers in bulk. The effect of polyvinyl acetate (PVAc) on the morphology and its effect on the gas permeation behavior of PMA-PDMS-PMA triblock copolymer was studied. PMA-PDMS-PMA/PVAc blend membranes were shown a new fibrillar morphology. The gas permeation properties and selectivity of the blend membranes were also reported.
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T. Nakagawa, T. Nishimura, and A. Higuchi, J. Membr. Sci., 206, 149 (2002).
M. Rutnakornpituk and P. Ngamdee, Polymer, 47, 7909 (2006).
K. Berean, J. Z. Ou, M. Nour, K. Latham, C. McSweeney, D. Paull, A. Halim, S. Kentish, C. M. Doherty, A. J. Hill, and K. Kalantar-zadeh, Sep. Purif. Technol., 122, 96 (2014).
S. S. Madaeni, E. Enayati, and V. Vatanpour, J. Appl. Polym. Sci., 122, 827 (2011).
T. C. Merkel, V. I. Bondar, K. Nagai, B. D. Freeman and I. Pinnau, J. Polym. Sci., Part B: Polym. Phys., 38, 415 (2000).
S. R. Reijerkerk, M. H. Knoef, K. Nijmeijer, and M. Wessling, J. Memb. Sci., 352, 126 (2010).
H. B. Park, C. H. Jung, Y. K. Kim, S. Y. Nam, S. Y. Lee, and Y. M. Lee, J. Membr. Sci., 235, 87 (2004).
Y. Tsujita, K. Yoshimura, H. Yoshimizu, A. Takizawa, T. Kinoshita, M. Furukawa, Y. Yamada, and K. Wada, Polymer, 34, 2597 (1993).
K. Madhavan and B. S. R. Reddy, J. Membr. Sci., 283, 357 (2006).
M. Srividhya and B. S. R. Reddy, J. Membr. Sci., 296, 65 (2007).
H. B. Park, C. K. Kim, and Y. M. Lee, J. Membr. Sci., 204, 257 (2002).
D. P. Queiroz and M. N. de Pinho, Polymer, 46, 2346 (2005).
D. Gomes, K. V. Peinemann, S. P. Nunes, W. Kujawski, and J. Kozakiewicz, J. Membr. Sci., 281, 747 (2006).
M. A. Semsarzadeh and E. Vakili, Iran. J. Polym. Sci. Technol., 4, 337 (2013).
S. R. Reijerkerk, M. Wessling, and K. Nijmeijer, J. Membr. Sci., 378, 479 (2011).
T. Hu, G. Dong, H. Li, and V. Chen, J. Membr. Sci., 432, 13 (2013).
T. Hu, G. Dong, H. Li, and V. Chen, J. Membr. Sci., 468, 107 (2014).
Z. H. Luo, H. J. Yu, and T. Y. He, J. Appl. Polym. Sci., 108, 1201 (2008).
D. Pavlovic, J. G. Linhardt, J. F. Künzler, and D. A. Shipp, Macromol. Chem. Phys., 211, 1482 (2010).
E. Martinelli, M. Suffredini, G. Galli, A. Glisenti, M. E. Pettitt, M. E. Callow, J. A. Callow, W. David, and L. Graeme, Biofouling, 27, 529 (2011).
K. Huan, L. Bes, D. M. Haddleton, and E. Khoshdel, J. Polym. Sci., Part A: Polym. Chem., 39, 1833 (2001).
Z.-H. Luo and T.-Y. He, React. Funct. Polym., 68, 931 (2008).
Y. Jiang, H. Shi, M. Cai, Y. Liang, B. Li, H. Zhang, and R. Song, J. Appl. Polym. Sci., 129, 247 (2013).
W. A. Braunecker and K. Matyjaszewski, Prog. Polym. Sci., 32, 93 (2007).
K. Matyjaszewski, Macromolecules, 45, 4015 (2012).
M. K. Barillas, R. M. Enick, M. O’Brien, R. Perry, D. R. Luebke and B. D. Morreale, J. Membr. Sci., 372, 29 (2011).
M. A. Semsarzadeh and B. Ghalei, J. Membr. Sci., 401-402, 97 (2012).
D. B. G. Williams and M. Lawton, J. Org. Chem., 75, 8351 (2010).
E. Duquesne, J. Habimana, P. Degée, and P. Dubois, Macromol. Chem. Phys., 207, 1116 (2006).
M. A. Semsarzadeh and M. Abdollahi, J. Appl. Polym. Sci., 123, 2423 (2012).
Y. Sun and W. Liu, Polym. Bull., 68, 1815(2012).
Y. Kim and H. J. Harwood, Polymer, 43, 3229 (2002).
S. S. Vadhavkar, Polymerization of Methyl Acrylate and as Comonomer with Ethylene Using Single-Site Catalysts, Thesis, Rochester Institute of Technology, 2008.
G. R. Guillen, Y. Pan, M. Li, and E. M. Hoek, Ind. Eng. Chem. Res., 50, 3798 (2011).
C. M. Hansen, Hansen Solubility Parameters: A User’s Handbook, CRC Press, Boca Raton, 2012.
R. Guan, H. Dai, C. Li, J. Liu, and J. Xu, J. Membr. Sci., 277, 148 (2006).
Z. Shi and X. Wang, Polym. Adv. Technol., 20, 1017 (2009).
X. Ren, J. Ren, H. Li, Sh. Feng, and M. Deng, Int. J. Greenh., Gas Control, 8, 111 (2012).
S. Gopakumar and M. R. G. Nair, Eur. Polym. J., 41, 2002 (2005).
D. W. Van Krevelen and K. Te Nijenhuis, Properties of Polymers: Their Correlation with Chemical Structure; Their Numerical Estimation and Prediction from Additive Group Contributions, Elsevier, Amsterdam, 2009.
A. Guner, Eur. Polym. J., 40, 1587 (2004).
T. Lindvig, M. L. Michelsen, and G. M. Kontogeorgis, Fluid Phase Equilib., 203, 247 (2002).
D. Rana, B. M. Mondal, and S. N. Bhattacharyya, Polymer, 34, 1454 (1993).
K. Shi, Ch. Lian, Zh. Bai, Sh. Zhao, and H. Liu, Chem. Eng. Sci.,122, 185 (2015).
P. A. Albouy, Polymer, 41, 3083 (2002).
G. L. Jadav, V. K. Aswal, H. Bhatt, J. C. Chaudhari, and P. S. Singh, J. Membr. Sci., 415-416, 624 (2012).
J. Zhang, J. Gao, X. Sun, Z. Peng, and J. Diao, Iran. Polym. J., 16, 39 (2007).
J. J. H. Lancastre, N. Fernandes, F. M. A. Margaça, I. M. Miranda Salvado, L. M. Ferreira, A. N. Falcão, and M. H. Casimiro, Radiat. Phys. Chem., 81, 1336 (2012).
H. A. Klok and S. Lecommandoux, Adv. Mater., 13, 1217 (2001).
T. Smart, H. Lomas, M. Massignani, M. V. Flores-Merino, L. R. Perez, and G. Battaglia, Nano Today, 3, 38 (2008).
J. Pyun, S. Jia, T. Kowalewski, and K. Matyjaszewski, Macromol. Chem. Phys., 205, 411 (2004).
S. Aggarwal, Polymer, 17, 938 (1976).
I. W. Hamely and V. Castelletto, Prog. Polym. Sci., 29, 909 (2004).
M. L. Wadley, I.-F. Haseieh, K. A. Cavicchi, and S. Z. D. Cheng, Macromolecules, 45, 5538 (2012).
R. F. Storey and D. W. Baugh, Polymer, 41, 3205 (2000).
I. W. Hamely, Developments in Block Copolymer Science and Technology, Wiley, Chichester, 2004.
J. Zhu, S. Zhang, K. Zhang, X. Wang, J. W. Mays, K. L. Wooley, and D. J. Pochan, Nat. Commun., 4, 1 (2013).
P.-C. Li, Y.-C. Lin, M. Chen, and S.-W. Kuo, Soft Matter, 9, 11257 (2013).
W. Work, K. Horie, M. Hess, and R. Stepto, Pure Appl. Chem., 76, 1985 (2004).
E. Princi, S. Vicin, and E. Pedemonte, Polym. Int., 58, 656 (2009).
P. Casarino, A. Brunacci, and E. Pedemonte, Macromol. Chem. Phys., 197, 3773 (1996).
Y. Yampolskii, Macromolecules, 10, 3298 (2012).
K.-I. Okamoto, M. Fujii, S. Okamyo, H. Suzuki, K. Tanaka, and H. Kita, Macromolecules, 28, 6950 (1995).
M. Yoshino, K. Ito, H. Kita, and K.-I. Okamoto, J. Polym. Sci., Part B: Polym. Phys., 38, 1707 (2000).
D. Husken, T. Visser, M. Wessling, and R. J. Gaymans, J. Membr. Sci., 346, 194 (2010).
H. B. Park, S. Y. Ha, and Y. M. Lee, J. Membr. Sci., 177, 143 (2000).
Z. Mogri and D. R. Paul, Polymer, 42, 7765 (2001).
S. R. Reijerkerk, M. H. Knoef, K. Nijmeijer, and M. Wessling, J. Membr. Sci., 352, 126 (2010).
J. M. Mark, Polymer Data Handbook, Oxford University Press, New York, 2009.
L. M. Robson, Ind. Eng. Chem. Res., 49, 11859 (2010).
H. Savoji, D. Rana, T. Matsuura, M. Soltanieh, and Sh. Tabe, J. Appl. Polym. Sci., 124, 2287 (2012).
L. M. Robeson, Polymer Characterization Techniques and Their Application to Blends, G. P. Simon, Ed., Oxford University Press, New York, 2003.
H. Savoji, D. Rana, T. Matsuura, M. Soltanieh, and Sh. Tabe, J. Appl. Polym. Sci., 124, 2300 (2012).
L. M. Robson, J. Membr. Sci., 320, 390 (2008).
M. E. Vanegas, R. Quijada, S. P. Nunes, and W. Yave, J. Membr. Sci., 348, 34 (2010).
M. Sadeghi, M. A. Semsarzadeh, M. Barikani, and B. Ghalei, J. Membr. Sci., 354, 40 (2010).
W. Yave, A. Car, K.-V. Peinemann, M. Q. Shaikh, K. Rätzke, and F. Faupel, J. Membr. Sci., 339, 177 (2009).
V. A. Kusuma, B. D. Freeman, M. A. Borns, and D. S. Kalika, J. Membr. Sci., 327, 195 (2009).
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Semsarzadeh, M.A., Ghahramani, M. Synthesis and morphology of polyacrylate-poly(dimethyl siloxane) block copolymers for membrane application. Macromol. Res. 23, 898–908 (2015). https://doi.org/10.1007/s13233-015-3112-3
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DOI: https://doi.org/10.1007/s13233-015-3112-3