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Viscosity of the oil-in-water Pickering emulsion stabilized by surfactant-polymer and nanoparticle-surfactant-polymer system

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Abstract

Information on the viscosity of Pickering emulsion is required for their successful application in upstream oil and gas industry to understand their stability at extreme environment. In this work, a novel formulation of oil-in-water (o/w) Pickering emulsion stabilized using nanoparticle-surfactant-polymer (polyacrylamide) system as formulated in our earlier work (Sharma et al., Journal of Industrial and Engineering Chemistry, 2014) is investigated for rheological stability at high pressure and high temperature (HPHT) conditions using a controlled-strain rheometer. The nanoparticle (SiO2 and clay) concentration is varied from 1.0 to 5.0 wt%. The results are compared with the rheological behavior of simple o/w emulsion stabilized by surfactant-polymer system. Both the emulsions exhibit non-Newtonian shear thinning behavior. A positive shift in this behavior is observed for surfactant-polymer stabilized emulsion at high pressure conditions. Yield stress is observed to increase with pressure for surfactant-polymer emulsion. In addition, increase in temperature has an adverse effect on the viscosity of emulsion stabilized by surfactant-polymer system. In case of nanoparticle-surfactant-polymer stabilized o/w emulsion system, the viscosity and yield stress are predominantly constant for varying pressure and temperature conditions. The viscosity data for both o/w emulsion systems are fitted by the Herschel-Bulkley model and found to be satisfactory. In general, the study indicates that the Pickering emulsion stabilized by nanoparticle-surfactant-polymer system shows improved and stable rheological properties as compared to conventional emulsion stabilized by surfactant-polymer system indicating their successful application for HPHT environment in upstream oil and gas industry.

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References

  • Alderman, N.J., 1988, High-temperature, high-pressure rheology of water-based muds, Proceedings of the Annual Technical Conference and Exhibition of the Society of Petroleum Engineers (SPE), Houston.

    Google Scholar 

  • Binks, B.P., J.H. Clint, and C.P. Whitby, 2005, Rheological behavior of water-in-oil emulsions stabilized by hydrophobic bentonite particles, Langmuir 21, 5307–5316.

    Article  Google Scholar 

  • Binks, B.P. and A. Rocher, 2009, Effects of temperature on water-in-oil emulsions stabilised solely by wax microparticles, J. Colloid Interf. Sci. 335, 94–104.

    Article  Google Scholar 

  • Dickinson, E. and K. Pawlowsky, 1996, Effect of high-pressure treatment of protein on the rheology of flocculated emulsions containing protein and polysaccharide, J. Agr. Food Chem. 44, 2992–3000.

    Article  Google Scholar 

  • Dickinson, E. and J.D. James, 1999, Influence of competitive adsorption on flocculation and rheology of high-pressure-treated milk protein-stabilized emulsions, J. Agr. Food Chem. 47, 25–30.

    Article  Google Scholar 

  • English, R.J., J.H. Laurer, R.J. Spontak, and S.A. Khan, 2002, Hydrophobically modified associative polymer solutions: rheology and microstructure in the presence of nonionic surfactants, Ind. Eng. Chem. Res. 41, 6425–6435.

    Article  Google Scholar 

  • Erni, P., E.J. Windhab, R. Gunde, M. Graber, B. Pfisetr, A. Parker, and P. Fischer, 2007, Interfacial rheology of surfaceactive biopolymers: acacia senegal gum versus hydrophobically modifed starch, Biomacromolecules 8, 3458–3466.

    Article  Google Scholar 

  • Frith, W.J., R. Pichot, M. Kirkland, and B. Wolf, 2008, Formation, stability, and rheology of particle stabilized emulsions: influence of multivalent cations, Ind. Eng. Chem. Res. 47, 6434–6444.

    Article  Google Scholar 

  • Hermes, M. and P.S. Clegg, 2013, Yielding and flow of concentrated Pickering emulsions, Soft Matter 9, 7568–7575.

    Article  Google Scholar 

  • Houwen, O.H., 1986, Rheology of oil base muds, Proceedings of the Annual Technical Conference and Exhibition of the Society of Petroleum Engineers (SPE), New Orleans.

    Google Scholar 

  • Jung, J., K. Zhang, B. Chon, and H. Choi, 2013, Rheology and polymer flooding characteristics of partially hydrolyzed polyacrylamide for oil recovery, J. Appl. Polym. Sci. 127, 4833–4839.

    Article  Google Scholar 

  • Kim, S. and C. Kim, 2012, The effects of particle concentration, ionic strength and shearing on the microstructure of alumina nanorod suspensions, Korea-Aust. Rheol. J. 24, 65–71.

    Article  Google Scholar 

  • Kundu, P., A. Agrawal, H. Mateen, and I.M. Mishra, 2013, Stability of oil-in-water macro-emulsion with anionic surfactant: effect of electrolytes and temperature, Chem. Eng. Sci. 102, 176–185.

    Article  Google Scholar 

  • Lan, Q., F. Yang, S. Zhang, S. Liu, J. Xu, and D. Sun, 2007, Synergistic effect of silica nanoparticle and cetyltrimethyl ammonium bromide on the stabilization of o/w emulsions, Colloids Surface A 302, 126–135.

    Article  Google Scholar 

  • Lequeux, F.P., 1998, Emulsion rheology, Curr. Opin. Colloid In. 3, 408–411.

    Article  Google Scholar 

  • Meister, M.J., G.K. Kettenbrink, and A.G. Collins, 1976, Enhanced oil recovery using improved aqueous fluid-injection methods: an annotated bibliography, Energy Research and Development Administration, Technical Information Center, Bartlesville, Oklahoma.

    Google Scholar 

  • Ozel, B.G., A. Orum, M. Yildiz, and Y.Z. Menceloglu, 2014, Experimental study on the rheology of anisotropic, flocculated and low volume fraction colloids, Korea-Aust. Rheol. J. 26, 105–116.

    Article  Google Scholar 

  • Pal, R., 1992, Rheology of polymer-thickened emulsions, J. Rheol. 36, 1245–1259.

    Article  Google Scholar 

  • Pal, R., 1993, Rheological behavior of surfactant-flocculated water-in-oil emulsions, Colloids Surface A 71, 173–185.

    Article  Google Scholar 

  • Pal, R., 1999, Rheology of blends of suspensions and emulsions, Ind. Eng. Chem. Res. 38, 5005–5010.

    Article  Google Scholar 

  • Pei, H., G. Zhang, J. Ge, M. Tang, and Y. Zheng, 2012, Comparative effectiveness of alkaline flooding and alkaline-surfactant flooding for improved heavy-oil recovery, Energ. Fuel. 26, 2911–2919.

    Article  Google Scholar 

  • Perino, A., C. Noik, and C. Dalmazzone, 2013, Effect of fumed silica particles on water-in-crude oil emulsion: emulsion stability, interfacial properties, and contribution of crude oil fractions, Energ. Fuel. 27, 2399–2412.

    Article  Google Scholar 

  • Ponmani, S., J.K.M. William, R. Samuel, R. Nagarajan, and J.S. Sangwai, 2014, Formation and characterization of thermal and electrical properties of CuO and ZnO nanofluids in xanthan gum, Colloids Surface A 443, 37–43.

    Article  Google Scholar 

  • Pons, R., C. Solans, and ThF. Tadros, 1995, Rheological behavior of highly concentrated oil-in-water (o/w) emulsions, Langmuir 11, 1966–1971.

    Article  Google Scholar 

  • Saha, R.K., A. Biswas, and U.C. Goswami, 2011, A simple method for scanning electron microscopy (SEM) study of cladocera: bosmina (bosmina) tripurae, World J. Fish Marine Sci. 3, 71–78.

    Google Scholar 

  • Sangwai, J.S., D.N. Saraf, and S.K. Gupta, 2006, Viscosity of bulk free radical polymerizing systems under near-isothermal and non-isothermal conditions, Polymer 47, 3028–3035.

    Article  Google Scholar 

  • Sangwai, J.S., D.N. Saraf, and S.K. Gupta, 2007, Dynamic viscoelastic properties of free radical bulk polymerizing systems under near-isothermal and non-isothermal conditions, Rheol. Acta 46, 455–468.

    Article  Google Scholar 

  • Sani, A.M. and S.N. Shah, 2001, Experimental investigation of xanthan foam rheology, Proceedings of the Society of Petroleum Engineers (SPE) Production and Operations Symposium, Oklahoma.

    Google Scholar 

  • Sharma, T., G.S. Kumar, B.H. Chon, and J.S. Sangwai, 2014, Thermal stability of oil-in-water Pickering emulsion in the presence of nanoparticle, surfactant and polymer, J. Ind. Eng. Chem., DOI: http://dx.doi.org/10.1016/j.jiec.2014.07.026.

    Google Scholar 

  • Steinborn, R. and D.L. Flock, 1983, The rheology of heavy crude oils and their emulsions, J. Can. Petrol. Technol. 22, 37–52.

    Article  Google Scholar 

  • Thijssen, J.H.J., A.B. Schofield, and P.S. Clegg, 2011, How do (fluorescent) surfactants affect particle-stabilized emulsions?, Soft Matter 7, 7965–7968.

    Article  Google Scholar 

  • Thomas, A., N. Gaillard, and C. Favero, 2012, Some key features to consider when studying acrylamide-based polymers for chemical enhanced oil recovery, Oil Gas Sci. Technol. 67, 887–902.

    Article  Google Scholar 

  • William, J.K.M., S. Ponmani, R. Samuel, R. Nagarajan, and J.S. Sangwai, 2014, Effect of CuO and ZnO nanofluids in xanthan gum on thermal, electrical and high pressure rheology of water based drilling fluids, J. Petrol. Sci. Eng. 117, 15–27.

    Article  Google Scholar 

  • Wolf, B., S. Lam, M. Kirkland, and W.J. Frith, 2007, Shear thickening of an emulsion stabilized with hydrophilic silica particles, J. Rheol. 51, 465–478.

    Article  Google Scholar 

  • Wu, S., 2013, Shear and elongational rheology of partially hydrolyzed polyacrylamide used for EOR, Appl. Rheol. 23, 53800–53807.

    Google Scholar 

  • Zhang, T., A. Davidson, S.L. Bryant, and C. Huh, 2010, Nanoparticle-stabilized emulsions for applications in enhanced oil recovery, Proceedings of the Society of Petroleum Engineers (SPE) Improved Oil Recovery Symposium, Oklahoma.

    Google Scholar 

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Authors and Affiliations

  1. Petroleum Engineering Program, Department of Ocean Engineering, Indian Institute of Technology Madras, Chennai, 600036, India

    Tushar Sharma, G. Suresh Kumar & Jitendra S. Sangwai

  2. School of Petroleum Technology, Pandit Deendayal Petroleum University, Gandhinagar, 382007, India

    Tushar Sharma

  3. Department of Energy Resources Engineering, Inha University, Incheon, 402-751, Republic of Korea

    Bo Hyun Chon

Authors
  1. Tushar Sharma
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  2. G. Suresh Kumar
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  3. Bo Hyun Chon
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  4. Jitendra S. Sangwai
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Correspondence to Jitendra S. Sangwai.

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Sharma, T., Kumar, G.S., Chon, B.H. et al. Viscosity of the oil-in-water Pickering emulsion stabilized by surfactant-polymer and nanoparticle-surfactant-polymer system. Korea-Aust. Rheol. J. 26, 377–387 (2014). https://doi.org/10.1007/s13367-014-0043-z

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  • DOI: https://doi.org/10.1007/s13367-014-0043-z

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