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Agglomeration effects of thin metal catalyst on graphene film synthesized by chemical vapor deposition

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Abstract

The agglomeration effect of thin metal catalyst on graphene film grown via CVD was investigated. Among Ni and Co catalysts with 200 nm to 400 nm thickness, 200 nm-Ni exhibits the highest agglomeration and the worst non-uniformity of the synthesized graphene film. Agglomeration induces roughness of catalysts and in turn degrades thickness uniformity of graphene film due to non-uniform dissolution and precipitation of carbon across the catalyst film. Increasing catalyst thickness suppresses the agglomeration and improves uniformity of graphene film. Co shows higher resistant to agglomeration than Ni and improves uniformity of the synthesized graphene film.

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References

  1. K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Dubonos, I. V. Grigorieva and A. A. Firsov, Science 306, 666 (2004).

    Article  CAS  Google Scholar 

  2. A. K. Geim and K. S. Novoselov, Nature Mater. 6, 183 (2007).

    Article  CAS  Google Scholar 

  3. A. K. Geim, Science 324, 1530 (2009).

    Article  CAS  Google Scholar 

  4. C. Lee, X. D. Wei, J. W. Kysar, and J. Hone, Science 321, 385 (2008).

    Article  CAS  Google Scholar 

  5. A. A. Balandin, S. Ghosh, W. Z. Bao, I. Calizo, D. Teweldebrhan, F. Miao, and C. N. Lau, Nano Lett. 8, 902 (2008).

    Article  CAS  Google Scholar 

  6. K. Kim, Y. Zhao, H. Jang, S. Lee, J. Kim, K. Kim, J. Ahn, P. Kim, J. Choi, and B. Hong, Nature 457, 706 (2009).

    Article  CAS  Google Scholar 

  7. B. J. Lee, H. Y. Yu, and G. H. Jeong, Nanoscale. Res. Lett. 5, 1768 (2010).

    Article  CAS  Google Scholar 

  8. S. W. Lee, S. J. Park, E. E. B. Campbell, and Y. W. Park, Nat. Comm. 2, 1 (2011).

    Google Scholar 

  9. C. Berger, Z. Song, T. Li, X. Li, A. Y. Ogbazghi, R. Feng, Z. Dai, A. N. Marchenkov, E. H. Conrad, P. N. First, and W. A. de Heer, J. Phys. Chem. B 108, 19912 (2004).

    Article  CAS  Google Scholar 

  10. C. Berger, Z. Song, X. Li, X. Wu, N. Brown C., C. Naud, D. Mayou, T. Li, J. Hass, A. N. Marchenkov, E. H. Conrad, P. N. First and W. A. de Heer, Science 312, 1191 (2006).

    Article  CAS  Google Scholar 

  11. H. C. Schniepp, J-L Li, M. J. McAllister, H. Sai, M. Herrera-Alonso, D. H. Adamson, R. K. Prud’homme, R. Car, D. A. Saville, and I. A. Aksay, J. Phys. Chem. B 110, 8535 (2006).

    Article  CAS  Google Scholar 

  12. X. Li, X. Wang, L. Zhang, S. Lee, and H. Dai, Science 319, 1229 (2008).

    Article  CAS  Google Scholar 

  13. A. Reina, X. Jia, J. Ho, D. Nezich, H. Son, V. Bulovic, M. S. Dresselhaus, and J. Kong, Nano Lett. 9, 30 (2009).

    Article  CAS  Google Scholar 

  14. S. Bae, H. Kim, Y. Lee, X. Xu, J. Park, Y. Zheng, J. Balakrishnan, T. Lei, H. Kim, Y. Song, Y. Kim, K. Kim, B. Özyilmaz, J. Ahn, B. Hong, and S. Iijima, Nature Nanotech. 5, 574 (2010).

    Article  CAS  Google Scholar 

  15. A. Reina, S. Thiele, X. Jia, S. Bhaviripudi, M. S. Dresselhaus, J. A. Schaefer, and J. Kong, Nano Res. 2, 509 (2009).

    Article  CAS  Google Scholar 

  16. S. Chae, F. Günes, K. Kim, E. Kim, G. Han, S. Kim, H. Shin, S. Yoon, J. Choi, M. Park, C. Yang, D. Pribat, and Y. Lee, Adv. Mater. 21, 2328 (2009).

    Article  CAS  Google Scholar 

  17. E. Kim, H. An, H, Jang, W. Cho, N. Lee, W. Lee, and J. Jung, Chem. Vap. Deposition. 17, 9 (2011).

    Article  CAS  Google Scholar 

  18. E. Jiran and C. V. Thompson, J. Electron. Mater. 19, 1153 (1990).

    Article  CAS  Google Scholar 

  19. J. J. Rha and J. K. Park, J. Appl. Phys. 82, 1608 (1997).

    Article  CAS  Google Scholar 

  20. D. J. Srolovitz and S. A. Safran, J. Appl. Phys. 60, 247 (1986).

    Article  CAS  Google Scholar 

  21. M. Castriota, E. Cazzanelli, D. Pacilè, L. Papagno, Ç. O. Girit, J. C. Meyer, A. Zettl, M. Giarola, and G. Mariotto, Diam. Relat. Mater. 19, 608 (2010).

    Article  CAS  Google Scholar 

  22. A. C. Ferrari, J. C. Meyer, V. Scardaci, C. Casiraghi, M. Lazzeri, F. Mauri, S. Piscanec, D. Jiang, K. S. Novoselov, S. Roth, and A. K. Geim, Phys. Rev. Lett. 97, 187401 (2006).

    Article  CAS  Google Scholar 

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Correspondence to Jongwan Jung.

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Kim, E., Lee, WG. & Jung, J. Agglomeration effects of thin metal catalyst on graphene film synthesized by chemical vapor deposition. Electron. Mater. Lett. 7, 261–264 (2011). https://doi.org/10.1007/s13391-011-0915-z

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  • DOI: https://doi.org/10.1007/s13391-011-0915-z

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