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Pigment-cellulose nanofibril composite and its application as a separator-substrate in printed supercapacitors

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Abstract

Pigment-cellulose nanofibril (PCN) composites were manufactured in a pilot line and used as a separator-substrate in printed graphene and carbon nanotube supercapacitors. The composites consisted typically of 80% pigment and 20% cellulose nanofibrils (CNF). This composition makes them a cost-effective alternative as a substrate for printed electronics at high temperatures that only very special plastic films can nowadays stand. The properties of these substrates can be varied within a relatively large range by the selection of raw materials and their relative proportions. A semi-industrial scale pilot line was successfully used to produce smooth, flexible, and nanoporous composites, and their performance was tested in a double functional separator-substrate element in supercapacitors. The nanostructural carbon films printed on the composite worked simultaneously as high surface area active electrodes and current collectors. Low-cost supercapacitors made from environmentally friendly materials have significant potential for use in flexible, wearable, and disposable low-end products.

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References

  1. K. Torvinen, J. Sievänen, T. Hjelt, and E. Hellén, Cellulose 19, 821 (2012).

    Article  Google Scholar 

  2. A. Penttilä, J. Sievänen, K. Torvinen, K. Ojanperä, and J. A. Ketoja, Cellulose 20, 1413 (2013).

    Article  Google Scholar 

  3. C. Liu, F. Li, L. P. Ma, and H. M. Cheng, Adv. Mater. 22, E28 (2010).

    Article  Google Scholar 

  4. V. L. Pushparaj, M. M. Shaijumon, A. Kumar, S. Murugesan, L. Ci, R. Vajtai, R. J. Linhardt, O. Nalamasu, and P. M. Ajayan, Proc. Natl. Acad Sci. USA 104, 13574 (2007).

    Article  Google Scholar 

  5. T. Kousksou, P. Bruel, A. Jamil, T. El Rhafiki, and Y. Zeraouli, Sol Energ Mat. Sol C 120, 59 (2014).

    Article  Google Scholar 

  6. A. Somov, C. C. Ho, R. Passerone, J. W. Evans, and P. K. Wright, Wireless Sensor Networks, Lecture Notes in Computer Science 7158, 212 (2012).

    Article  Google Scholar 

  7. X. Li and B. Wei, Nano Energy 2, 159 (2013).

    Article  Google Scholar 

  8. H. B. Radousky and H. Liang, Nanotechnology 23, 502001 (2012).

    Article  Google Scholar 

  9. D.-Y. Lee and H. J. Kim, Nanotechnology 24, 175402 (2013).

    Article  Google Scholar 

  10. S. Lehtimäki, M. Li, J. Salomaa, J. Pörhönen, A. Kalanti, S. Tuukkanen, P. Heljo, K. Halonen, and D. Lupo, Int. J. Elec. Power 58, 42 (2014).

    Article  Google Scholar 

  11. J. Pörhönen, S. Rajala, S. Lehtimäki, and S. Tuukkanen, IEEE T Electron. Dev. 61, 3303 (2014).

    Article  Google Scholar 

  12. H. S. Kim, J.-H. Kim, and J. Kim, International Journal of Precision Engineering and Manufacturing 12, 1129 (2011).

    Article  Google Scholar 

  13. F. Simjee and P. H. Chou, ISLPED’06, Proceedings of the 2006 International Symposium on Low Power Electronics and Design (IEEE) 197 (2006).

    Google Scholar 

  14. S. Lehtimäki, J. Pörhönen, S. Tuukkanen, P. Moilanen, J. Virtanen, and D. Lupo, Mater. Res. Soc. Symp. Proc. 1659 (2014).

    Google Scholar 

  15. S. Lehtimäki, S. Tuukkanen, J. Pörhönen, P. Moilanen, J. Virtanen, M. Honkanen, and D. Lupo, Appl. Phys. A. 117, 1329 (2014).

    Article  Google Scholar 

  16. J. Li, X. Cheng, A. Shashurin, and M. Keidar, Graphene 1, 1 (2012).

    Article  Google Scholar 

  17. T. Chen and L. Dai, Materials Today 16, 272 (2013).

    Article  Google Scholar 

  18. H. J. Choi, S. M. Jung, J. M. Seo, D. W. Chang, L. Dai, and J. B. Baek, Nano Energy 1, 534 (2012).

    Article  Google Scholar 

  19. S. Tuukkanen, S. Lehtimäki, F. Jahangir, A. P. Eskelinen, D. Lupo, and S. Franssila, Proceedings of 5th Electronics System-Integration Technology Conference (ESTC) (2014).

    Google Scholar 

  20. J. C. Roberts, Paper Chemistry. Springer, New York (1996).

    Google Scholar 

  21. L. Hu, J. W. Choi, Y. Yang, S. Jeong, F. La Mantia, L.-F. Cui, and Y. Cui, Proc. Natl. Acad Sci. USA 106, 21490 (2009).

    Article  Google Scholar 

  22. L. Hu, H. Wu, and Y. Cui, Appl. Phys. Lett. 96, 183502 (2010).

    Article  Google Scholar 

  23. S. Hu, R. Rajamani, and X. Yu, Appl. Phys. Lett. 100, 104103 (2012).

    Article  Google Scholar 

  24. P. Mostafalu and S. Sonkusale, Sensors, 2013 IEEE proceedings 1-4, 3-6 Nov. 2013, Baltimore, (2013).

    Google Scholar 

  25. J. Li, X. Cheng, J. Sun, C. Brand, A. Shashurin, M. Reeves, and M. Keidar, J. Appl. Phys. 115, 164301 (2014).

    Article  Google Scholar 

  26. H. Kangas, P. Lahtinen, A. Sneck, A. M. Saariaho, O. Laitinen, and E Hellén, Nordic Pulp Pap. Res. J. 29, 129 (2014).

    Article  Google Scholar 

  27. J. Vartiainen, T. Kaljunen, V. Kunnari, P. Lahtinen, A. Salminen, J. Seppala, and T. Tammelin, Proceedings of 26th IAPRI Symposium on Packaging 197 (2013).

    Google Scholar 

  28. O. Timofeev, K. Torvinen, J. Sievänen, T. Kaljunen, J. Kouko, and J. A. Ketoja, Materials 7, 6893 (2014).

    Article  Google Scholar 

  29. T. Tammelin, A. Salminen, and U. Hippi, Patent Application FI20116048 (2011).

    Google Scholar 

  30. B. E. Conway, J. Electrochem. Soc. 138, 1539 (1991).

    Article  Google Scholar 

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Correspondence to Katariina Torvinen.

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Torvinen, K., Lehtimäki, S., Keränen, J.T. et al. Pigment-cellulose nanofibril composite and its application as a separator-substrate in printed supercapacitors. Electron. Mater. Lett. 11, 1040–1047 (2015). https://doi.org/10.1007/s13391-015-5195-6

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  • DOI: https://doi.org/10.1007/s13391-015-5195-6

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